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Porous polymer material and preparation method thereof

A porous polymer, aromatic compound technology, applied in the directions of alkali metal compounds, chemical instruments and methods, organic compounds/hydrides/coordination complex catalysts, etc., can solve the problem of limited styrene monomers, increase production costs, The problems of high energy consumption, etc., achieve the effects of wide applicability, mild reaction conditions, and simple synthesis methods.

Active Publication Date: 2011-06-15
武汉华科中英纳米科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

This method generally requires three steps in the preparation process, that is, polymerization-swelling (dissolution)-hypercrosslinking, the process is complicated, and the energy consumption is large.
Moreover, the styrenic monomers that can be used for industrial production are very limited. If you want to prepare functional styrenic hypercrosslinked porous polymers, you generally need to adopt a post-modification method, which further increases the production cost.

Method used

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  • Porous polymer material and preparation method thereof
  • Porous polymer material and preparation method thereof
  • Porous polymer material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] At room temperature, add 20ml of 1,2-dichloroethane, 1.56g of benzene and 4.56g of dimethoxymethane into a three-necked flask equipped with a reflux condenser and a thermometer, and stir magnetically for 0.2 hours. Then add 6.50 g of anhydrous ferric chloride, raise the temperature to 45° C., stir magnetically at this temperature for 5 hours, then raise the temperature to 80° C., and stir magnetically at this temperature for 18 hours. During the above process, magnetic stirring was maintained. The reaction product was filtered to obtain a brown solid crude product, which was washed three times with ether and methanol, and then extracted with methanol in a Soxhlet extractor for 24 hours. Finally dry under reduced pressure to obtain the porous polymer material, its infrared spectrum is shown in the attached figure 1 , at 1600cm -1 , 1500cm -1 and 1450cm -1 The infrared peaks prove that the porous polymer has an aromatic ring structure; 13 C solid NMR spectrum see att...

Embodiment 2

[0026] At room temperature, add 20ml of 1,2-dichloroethane, 3.08g of biphenyl and 3.04g of dimethoxymethane into a three-necked flask equipped with a reflux condenser and a thermometer, and stir magnetically for 0.5 hours. Then add 6.50 g of anhydrous ferric chloride, raise the temperature to 45° C., stir magnetically at this temperature for 5 hours, then raise the temperature to 80° C., and stir magnetically at this temperature for 18 hours. During the above process, magnetic stirring was maintained. The reaction product was filtered to obtain a brown solid crude product, which was washed three times with ether and methanol, and then extracted with methanol in a Soxhlet extractor for 24 hours. Finally dry under reduced pressure to obtain the porous polymer material, its infrared spectrum is shown in the attached image 3 , at 1600cm -1 , 1500cm -1 and 1450cm -1 The infrared peaks prove that the porous polymer has an aromatic ring structure;13 C solid NMR spectrum see atta...

Embodiment 3

[0028] At room temperature, add 20ml of 1,2-dichloroethane, 1.86g of toluene and 3.04g of chloromethyl methyl ether into a three-neck flask equipped with a reflux condenser and a thermometer, and stir magnetically for 0.5 hours. Then add 6.50 g of anhydrous ferric chloride, raise the temperature to 45° C., stir magnetically at this temperature for 5 hours, then raise the temperature to 80° C., and stir magnetically at this temperature for 18 hours. During the above process, magnetic stirring was maintained. The reaction product was filtered to obtain a brown solid crude product, which was washed three times with ether and methanol, and then extracted with methanol in a Soxhlet extractor for 24 hours. Finally dry under reduced pressure to obtain the porous polymer material, its infrared spectrum is shown in the attached Figure 5 , at 1600cm -1 , 1500cm -1 and 1450cm -1 The infrared peaks prove that the porous polymer has an aromatic ring structure; 13 C solid NMR spectrum...

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Abstract

The invention provides a porous polymer material and a preparation method thereof. The porous polymer provided by the invention is prepared by crosslinking aromatic compounds with a crosslinking agent; the specific area of the porous polymer material is up to 2000 m<2>g<-1>, and the controllable range of the pore size is 0.3-100nm; and the porous polymer material can be used as a catalyst carrier, separation membrane, gas storage material and ion adsorbent. The preparation method comprises the following step: by using dimethoxymethane or chloromethyl methyl ether as the crosslinking agent andusing Lewis acid as the catalyst, crosslinking various aromatic compounds to obtain the porous polymer material by a one step method. The method has the characteristics of cheap and accessible raw materials and simple preparation technology, and the varieties of the aromatic compounds can be flexibly selected according to different application demands.

Description

technical field [0001] The invention belongs to the technical field of new materials, in particular, the invention relates to a porous polymer material and a preparation method thereof. Background technique [0002] Porous polymer materials are widely used as catalyst supports, separation membranes, gas storage materials, and ion adsorbents. At present, porous polymer materials mainly include: (1) styrene-based hypercrosslinked porous polymers; (2) self-porous polymers; (3) polyaniline-based porous polymers; (4) conjugated porous polymers ; (5) Porous polymers based on aromatic ring coupling reactions. The preparation methods of the above porous polymer materials are relatively complicated or need to use expensive raw materials. At present, only styrene-based hypercrosslinked porous polymers have been industrialized. However, this method needs to first polymerize styrenic monomers, then dissolve or swell the styrenic polymer obtained after polymerization in a solvent, and ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J20/30C08G61/00B01J20/26B01D71/72B01J20/28B01J31/06C08J9/00B01J32/00
CPCY02C10/08Y02C20/40
Inventor 谭必恩李步怡龚瑞妮梁丽芸
Owner 武汉华科中英纳米科技有限公司
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