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Preparation process of foam metal carrier for post-treatment

A metal foam and system technology, applied in the electrolysis process, electroforming, etc., can solve the problems of high process cost, long production process, environmental pollution, etc., achieve high practical value, improve efficiency, and cancel the effect of polluting processes

Inactive Publication Date: 2012-01-18
CHINA FIRST AUTOMOBILE
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0009] The traditional pretreatment includes degreasing and hydrophilization treatment. The hydrophilization treatment makes the surface of the plastic substrate change from hydrophobic to hydrophilic. The hydrophilization treatment method includes mechanical and chemical methods. A strong oxidizing solution of a mixture of anhydride and sulfuric acid for treatment, which has potential environmental pollution problems; the next step is to use catalytic gold, silver, platinum or palladium and other precious metals for activation treatment process; after activation treatment , start the electroless plating of foamed plastics, so that the metal ions in the plating solution are reduced and deposited on the foamed plastics substrate. After electroless plating, a metal conductive film will be attached to the surface of the foamed plastics. The thickness of the film layer is generally very thin (0.05~0.8 μm), often cannot meet the use requirements of the product in terms of mechanical properties and strength
Therefore, after electroless plating, foam plastic electroplating can be carried out by using the usual electroplating process to deposit iron and nickel metal, increase the thickness of the metal layer, and complete the foam metal preparation. It can be seen that the production process of traditional foam metal is long, Low efficiency, high process cost and potential environmental pollution are the disadvantages of the current chemical pretreatment method

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] First select a commercially available polyurethane foam substrate with a porosity of 25ppi and cut it into a disc-shaped blank with a diameter of 320mm and a thickness of 25mm. Regardless of whether there is residual oil stain, use a degreasing agent to clean and remove the oil stain, and then rinse with tap water for 2 Rinse twice with deionized water, dry the water, dry indoors, weigh W1=61.8g, and set aside; weigh 3 parts of industrial thermosetting phenolic resin, weigh 4 parts of industrial alcohol, and weigh 5 parts of the average Nano-graphite powder with a particle size of 10 μm (corresponding to the industrial grade with a standard mesh number of 1340), mixed and stirred to form a conductive paste; dip the above-mentioned foam plastic blank into it, first dip for the first time, take out and squeeze out the excess Slurry, air purged, and then kept in a drying oven at 80°C for 40 minutes, repeated the first operation, dipping and drying for the second time, and p...

Embodiment 2

[0023] First select a commercially available polyurethane foam substrate with a porosity of 25ppi and cut it into a disc-shaped blank with a diameter of 320mm and a thickness of 25mm. Regardless of whether there is residual oil stain, use a degreasing agent to clean and remove the oil stain, and then rinse with tap water for 2 Rinse twice with deionized water, dry the water, dry indoors, weigh W1=61.8g, and set aside; weigh 6 parts of industrial thermosetting phenolic resin, weigh 10 parts of industrial alcohol, and weigh 8 parts of the average The particle size is 13 μm (corresponding to the industrial grade with a standard mesh number of 1000), and the nano-graphite powder is mixed and stirred to form a conductive paste; the foam plastic blank is immersed in it, firstly dipped for the first time, and the excess paste is taken out and squeezed out. Air purging, and then keep warm in a drying oven at 120°C for 60 minutes, repeat the first operation, carry out second dipping and...

Embodiment 3

[0026] With the thermosetting phenolic resin of 4 mass parts, the technical alcohol of 6 mass parts, the nano-graphite of 5 mass parts, mix and stir and reconcile into conductive paste,

[0027] The particle size of the nano-graphite is 11 μm (corresponding to the industrial-grade nano-graphite with a standard mesh number of 1200), and the thermosetting resin is phenolic resin. However, other thermosetting resins can be used, and the thermosetting resin is formed after drying. The affinity of the film to water is very good; the particle size of the added nano-graphite is 11 μm, mainly considering that the thickness of the film formed by the thermosetting resin after drying is below 11 μm, so as to form a single-layer arrangement of nano-graphite particles. The resin can be dissolved with alcohol, and the addition of alcohol is to ensure that the nano-graphite powder can also be wetted by the thermosetting resin, and the formed film is more continuous and dense; the foam plastic...

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Abstract

The invention relates to a preparation process of a foam metal carrier for post-treatment, which is characterized in that: blending thermosetting phenolic resin, alcohol, and nanometer graphite to form conductive slurry, soaking and coating foamed plastics, extruding redundant slurry, drying, electroplating the plastics with iron and nickel, after electroplating, performing deficiency sintering with a preserved temperature in a high temperature furnace so as to prepare the foam metal with a certain porosity. Starting with the optimization of the pre-treatment process flow of foamed plastics, the invention shortens the flow, eliminates pollution procedures, has obvious energy saving and environmental protection effect, is stable and controllable, and has very high practical value.

Description

technical field [0001] The invention relates to a preparation process of a metal foam carrier for aftertreatment, which can be applied to the aftertreatment industry of automobile exhaust. Background technique [0002] At present, the world is facing comprehensive challenges of energy and environment. In the selection of technical means to meet the emission standards of traditional vehicles, people still face many difficulties, for example, how to choose the carrier and catalyst for post-treatment. [0003] The post-processing carrier is the key factor to constitute the vehicle after-processing platform. Up to now, most of the post-processing carriers are imported ceramic carriers. Similarly, mature metal carriers are also monopolized by foreign technologies and patents, which has become a key factor restricting the development of China's post-processing industry. Therefore, how to obtain low-cost and high-performance post-processing carriers is the core content of promotin...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C25C5/02C25D1/08
Inventor 张克金杨彬许德超米新艳魏晓川应善强崔龙张喆
Owner CHINA FIRST AUTOMOBILE