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Flame-retardant glass fiber reinforced polyethylene terephthalate (PET)/ polytrimethylene terephthalate (PTT)/ polybutylene terephthalate (PBT) alloy material and preparation method thereof

An alloy material, PTT10 technology, applied in the field of flame-retardant glass fiber reinforced PET/PTT/PBT alloy material and its preparation, to achieve the effects of increased thermal deformation temperature, fast crystallization speed, and good comprehensive physical and mechanical properties

Inactive Publication Date: 2012-02-15
SHANGHAI SUNNY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The research and development of glass fiber reinforced flame retardancy of PET / PTT / PBT alloy has not been reported in China

Method used

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  • Flame-retardant glass fiber reinforced polyethylene terephthalate (PET)/ polytrimethylene terephthalate (PTT)/ polybutylene terephthalate (PBT) alloy material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0036] This embodiment provides a flame-retardant glass fiber-reinforced PET / PTT / PBT alloy material, the raw materials and weight fractions of which are:

[0037] 15 copies of PET;

[0038] 15 copies of PTT;

[0039] 24 copies of PBT;

[0040] 3 parts of compatibilizer;

[0041] Composite flame retardant 12 parts;

[0042] 0.5 part of antioxidant;

[0043] Lubricant 0.5 parts;

[0044] 30 parts of glass fiber;

[0045] The specific preparation method is: put all the components in a high-efficiency mixer in proportion and mix them for 8 minutes. The composite flame retardant in the raw materials consists of four kinds of decabromodiphenylethane, brominated triazine, antimony trioxide and TYT999. Composition of raw materials; then melted, kneaded, extruded, cooled, dried, pelletized and packaged through a twin-screw extruder. The used twin-screw extruder screw barrel has a temperature of 215~235°C in each zone, and the screw speed is 200 rpm to obtain the product.

Embodiment 2

[0047] This embodiment provides a flame-retardant glass fiber-reinforced PET / PTT / PBT alloy material, the raw materials and weight fractions of which are:

[0048] 15 copies of PET;

[0049] 15 copies of PTT;

[0050] 23 copies of PBT;

[0051] 3 parts of compatibilizer;

[0052] Composite flame retardant 13 parts;

[0053] 0.5 part of antioxidant;

[0054] Lubricant 0.5 parts;

[0055] 30 parts of glass fiber;

[0056] The specific preparation method is: put all the components in a high-efficiency mixer in proportion and mix them for 8 minutes. The composite flame retardant in the raw materials consists of four kinds of decabromodiphenylethane, brominated triazine, antimony trioxide and TYT999. Composition of raw materials; then melted, kneaded, extruded, cooled, dried, pelletized and packaged through a twin-screw extruder. The used twin-screw extruder screw barrel has a temperature of 215~235°C in each zone, and the screw speed is 200 rpm to obtain the product.

Embodiment 3

[0058] This embodiment provides a flame-retardant glass fiber-reinforced PET / PTT / PBT alloy material, the raw materials and weight fractions of which are:

[0059] 15 copies of PET;

[0060] 15 copies of PTT;

[0061] 23 copies of PBT;

[0062] 3 parts of compatibilizer;

[0063] Composite flame retardant 13 parts;

[0064] 0.5 part of antioxidant;

[0065] Lubricant 0.5 parts;

[0066] 30 parts of glass fiber;

[0067]The specific preparation method is: put all the components in a high-efficiency mixer in proportion and mix them for 8 minutes. The composite flame retardant in the raw materials consists of four kinds of decabromodiphenylethane, brominated triazine, antimony trioxide and TYT999. Composition of raw materials; then melted, kneaded, extruded, cooled, dried, pelletized and packaged through a twin-screw extruder. The used twin-screw extruder screw barrel has a temperature of 215~235°C in each zone, and the screw speed is 200 rpm to obtain the product.

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Abstract

The invention relates to a flame-retardant glass fiber reinforced polyethylene terephthalate (PET) / polytrimethylene terephthalate (PTT) / polybutylene terephthalate (PBT) alloy material and a preparation method thereof. The alloy material comprises the following raw materials in part by weight: 10 to 30 parts of PET, 10 to 30 parts of PTT, 20 to 40 parts of PBT, 3 to 10 parts of compatilizer, 5 to 20 parts of composite flame retardant, 0.1 to 0.5 part of antioxidant, 0.1 to 0.5 part of lubricating agent, and 10 to 30 parts of glass fibers. The preparation method comprises the following steps of: putting all the raw materials into an efficient mixer, mixing the raw materials for 5 to 10 minutes, and then discharging the uniformly mixed raw materials; and putting the uniformly mixed raw materials into a screw extruder, and performing extrusion and water cooling granulation. The produced PET / PTT / PBT alloy has the characteristics of excellent flame-retardant performance, high crystallization speed, good comprehensive physical and mechanical performance, low shrinkage rate, stable size, low warping, high surface glossiness, excellent processing performance and the like, and can be used for replacing a flame-retardant reinforced PBT material or bakelite under certain occasions.

Description

technical field [0001] The invention relates to a polymer material, in particular to a flame-retardant glass fiber reinforced PET / PTT / PBT alloy material and a preparation method thereof. Background technique [0002] PET (polyethylene terephthalate) is a crystalline polymer with high melting temperature and glass transition temperature, which maintains excellent physical and mechanical properties in a certain temperature range, and its fatigue resistance , friction resistance, aging resistance, and electrical insulation are extremely prominent, relatively stable to most organic solvents and acids, and have low production energy consumption, so they are widely used in the fields of synthetic fibers, films, and engineering plastics; but because PET Strong rigidity leads to poor toughness of the material, slow crystallization speed, high mold temperature and long molding cycle, etc., which greatly limit its application range. [0003] PTT (polytrimethylene terephthalate) is a ...

Claims

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Application Information

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IPC IPC(8): C08L67/02C08K13/04C08K7/14B29B9/06B29C47/92B29C48/92
CPCB29C48/04
Inventor 段浩黄晓明范潇潇孟成铭
Owner SHANGHAI SUNNY
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