Urea formaldehyde resin adhesive for moisture-proof environment-friendly medium density fiberboard and production method as well as composite additives thereof
A technology of urea-formaldehyde resin and composite additives, which is applied in adhesives, aldehyde/ketone condensation polymer adhesives, adhesive types, etc., can solve the problems of high cost, high price, and poor market acceptance, and achieve low cost , low price, and the effect of reducing the amount of raw materials
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Embodiment 1
[0023] 1. Recipe composition
[0024] The molar ratio of formaldehyde to urea was F / U=1.156, 550 parts of formaldehyde (37% concentration), 354 parts of urea (98% purity), and 60 parts of compounding aids.
[0025] Percentage composition of compound auxiliary: sodium chloride 24%, esterified starch 16%, melamine 57%, dicyandiamide 3%.
[0026] 2. Glue making process
[0027] Put 480 parts of formaldehyde aqueous solution into the reaction kettle, start the stirrer, start heating and heating, stop heating when the temperature is raised to 40 ° C, and adjust the pH value with 25-30% sodium hydroxide aqueous solution to 7.5-8.0;
[0028] Add 170 parts of the first batch of urea, stop heating when the temperature rises to 70°C, then naturally heat up to 90°C, check pH (guaranteed pH=6.5~7.0), add 12 parts of compound additives after holding for 10 minutes, stir for 15 minutes minute;
[0029] Adjust pH=4.8-5.2 with 25-30% formic acid aqueous solution, and carry out polyconden...
Embodiment 2
[0044] 1. Recipe composition
[0045] The molar ratio of formaldehyde to urea was F / U=1.2, 550 parts of formaldehyde (37% concentration), 346 parts of urea (98% purity), and 67 parts of compounding auxiliary.
[0046] Percentage composition of compound auxiliary: sodium chloride 24%, oxidized starch 16%, melamine 57%, dicyandiamide 2%, hexamethylenetetramine 1%.
[0047] 2. Glue making process
[0048] Put 480 parts of formaldehyde aqueous solution into the reaction kettle, start the stirrer, start heating and heating, stop heating when the temperature is raised to 40 ° C, and adjust the pH value with 25-30% sodium hydroxide aqueous solution to 7.5-8.0;
[0049] Add 165 parts of the first batch of urea, stop heating when the temperature rises to 70°C, then naturally heat up to 90°C, check the pH (guaranteed pH=6.5~7.0), add 13 parts of compound additives after holding for 10 minutes, stir for 15 minutes minute;
[0050] Adjust the pH between 5.0 and 5.2 with 25-30% formi...
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