Method for surface metallization of resin-based composite material compressed by mold

A composite material and compression molding technology, which is applied in metal material coating process, liquid chemical plating, coating, etc., can solve the problems of not being able to use resin-based composite materials, not applicable to resin-based composite materials, and endangering human health. Achieve the effects of enhanced oxidation, less environmental pollution, and increased hydrophilicity

Active Publication Date: 2012-04-18
SHENZHEN XINTIAN TECH
View PDF6 Cites 21 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0016] Chinese invention patent application CN201010297892.8 discloses a method for preparing metallized coatings on the surface of epoxy resin-based composite materials. Although this method has a good effect on the surface metallization of epoxy resin-based composite materials, there are still Certain problems, the existing problem is that the coarsening process still adopts the chromic anhydride-concentrated sulfuric acid system. As mentioned above, chromium ions are one of the harmful heavy ion metals that cause environmental pollution and endanger human health. At the same time, the epoxy resin-based composite material is a non-molding molding material, and its composition is relatively simple compared with the resin-based composite material that can be molded. The method disclosed in CN201010297892.8 is not applicable. Metallization of Compression Molded Resin Matrix Composites
[0017] Chinese invention patent ZL200710150743.7 discloses a new surface metallization method for carbon fiber reinforced epoxy resin-based composite materials. Compared with the standard process of surface metallization of resin-based composite materials, it is directly sensitized after degreasing, and then electroless plating , this surface metallization method has a good effect on specific epoxy resin-based composites with a carbon fiber content of more than 30%, but it cannot be generally used for resin-based composites, especially for those containing a large amount of structural fillers. Compression-moldable resin-based composites

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0043] Embodiment 1: A method for preparing the surface metallization of a moldable resin-based composite material provided by this preferred embodiment, the moldable resin-based composite material contains thermosetting resin, filler and fiber, the described The thermosetting resin is unsaturated polyester resin, the fiber is glass fiber, and the preparation method includes oil removal, coarsening, neutralization, sensitization, activation, and electroless plating, the filler is silicon dioxide, and the Surface metallization of moldable resin matrix composites is accomplished through the following steps:

[0044] The first step is to degrease, the resin-based composite material that can be molded is placed in a chemical degreasing tank containing a degreasing liquid, and the oil is removed by alkali washing to remove the oil stain on the surface of the resin-based composite material that can be molded. The content of sodium hydroxide is 20g / L, the content of sodium phosphate ...

Embodiment 2

[0050] Embodiment 2: This preferred embodiment provides a method for preparing the surface metallization of a moldable resin-based composite material. The moldable resin-based composite material contains thermosetting resins, fillers and fibers. The described The thermosetting resin is phenolic resin, the fiber is quartz fiber, and the preparation method includes oil removal, coarsening, neutralization, sensitization, activation, and electroless plating, and the filler is carbonate and silicon dioxide. The mesh number of salt and silica is 1000 mesh, and the surface metallization of the moldable resin matrix composite material is accomplished by the following steps:

[0051] The first step degreasing, with embodiment one;

[0052] In the second step of roughening, the moldable resin-based composite material that has been deoiled is placed in an ultrasonic roughening tank, and the roughening solution in the roughening tank adopts a mixed system of potassium permanganate-sulfuri...

Embodiment 3

[0057] Embodiment 3: A method for preparing the surface metallization of a moldable resin-based composite material provided by this preferred embodiment. The moldable resin-based composite material contains thermosetting resin, filler and fiber. The said The thermosetting resin is phenolic resin, the fiber is carbon fiber, and the preparation method includes degreasing, coarsening, neutralization, sensitization, activation, and electroless plating. The filler is carbonate, and the purpose of the carbonate is The number is 1000 mesh, and the surface metallization of the moldable resin-based composite material is accomplished by the following steps:

[0058] The first step degreasing, with embodiment one;

[0059]In the second step of roughening, the moldable resin-based composite material that has been deoiled is placed in an ultrasonic roughening tank, and the roughening solution in the roughening tank is a potassium permanganate-sulfuric acid system roughening solution , whe...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

No PUM Login to view more

Abstract

The invention discloses a method for surface metallization of a resin-based composite material compressed by a mold. The resin-based composite material compressed by a mold comprises one or more thermosetting resins, one or more fibers and one or more filling materials. The method provided by the invention can realize surface metallization of the resin-based composite material compressed by a mold. The key point of surface metallization is effectiveness in resin-based composite material roughening. Through the technical measures which comprise utilization of supersonic waves in roughening andimprovement of a roughening solution and realize good effects of roughening the one or more fibers and the one or more filling materials in the resin-based composite material by the roughening solution, the method realizes the surface metallization of the resin-based composite material compressed by a mold. The method is suitable for surface metallization of the resin-based composite material compressed by a mold, and has high efficiency, environmentally friendly characteristics and good metalized layer adhesion.

Description

technical field [0001] The invention relates to a preparation method for surface metallization of a resin-based composite material which can be molded, and belongs to the class of chemical plating methods for surface metallization of non-metallic materials. Background technique [0002] Products with good electrical conductivity on the surface are often required in industry, such as selective light-transmitting devices, electromagnetic reflection devices, communication equipment, and medical equipment. These products realize their functions through the good electrical conductivity of their surfaces. The use of articles with good electrical conductivity on the surface is so widespread that the manufacture of such articles has become a hot topic. [0003] Metals with good electrical conductivity are usually noble metals (such as gold and silver, etc.) or non-ferrous metals (such as aluminum and copper), which are expensive, so such products with good electrical conductivity on...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Applications(China)
IPC IPC(8): C23C18/24C23C18/18C23C18/36C23C18/40C23C18/31C23C18/44
Inventor 薛枫井新利王勇
Owner SHENZHEN XINTIAN TECH
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products