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A polishing slurry for polishing titanium-containing substrates

A polishing slurry and base material technology, which is applied in the fields of polishing compositions containing abrasives, electrical components, semiconductor/solid-state devices, etc., can solve problems such as titanium scratches, low titanium removal rate, and failure to achieve polishing effects, etc., to achieve Effect of high removal rate

Active Publication Date: 2016-01-20
ANJI MICROELECTRONICS TECH (SHANGHAI) CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The polishing performance of titanium is quite different from ordinary aluminum, copper, etc. Titanium generally does not undergo oxidation reaction, and the use of ordinary polishing liquid cannot achieve a good polishing effect
[0007] During the polishing process of titanium, Delaware Rodell Company of the United States uses a harder polishing pad, which can effectively remove titanium, but scratches appear on titanium after polishing. Substrate surface flatness is low
Chinese patent CN1194453C provides a polishing liquid with oxalic acid, water and alumina abrasive particles as main components; % of oxidizing agent, 0.1~5wt% of complexing agent, 0.1~5wt% of chelating agent and the balance of water, wherein the grinding agent is more than 90m 2 Fumed silicon oxide / g surface area and only being exposed to acidic pH is the main component; U.S. Patent US6001269 provides a kind of titanium metal polishing liquid comprising the known abrasive composition of iodate-based oxidizing agent, but adopts the above-mentioned patent Polishing fluid, grooves appear on the surface of titanium, and the surface flatness of the substrate is low, which affects the reliability and stability of integrated circuits, and the removal rate of titanium is low during the polishing process

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1~20

[0028] Table 1 lists the components of the present invention containing amino acid polishing liquid embodiment 1 ~ 20 and non-amino acid polishing liquid comparative examples 1 ~ 3, according to the formula given in the table, all components are mixed uniformly, and water is used to make up the weight percentage to 100%. with KOH or HNO 3 Adjust to desired pH.

[0029] The blank titanium / titanium nitride was polished by using comparative polishing solutions 1-3 and polishing solutions 1-20 of the present invention. The polishing rates are shown in Table 1.

[0030] Polishing conditions: titanium / titanium nitride wafer, down force 3psi, polishing disc and polishing head speed 70 / 80rpm, polishing pad Politex, polishing liquid flow rate 100ml / min, polishing machine is LogitechPM5Polisher.

[0031]

[0032] The data in the above examples show that the removal rate of titanium / titanium nitride in the examples 1 to 20 of the polishing slurry of the present invention is imp...

Embodiment 21~39

[0034] Table 2 lists the components of Examples 21-39 of the amino acid-containing polishing liquid of the present invention. According to the formula given in the table, all components are mixed evenly, and the weight percentage is made up to 100% with water. with KOH or HNO 3 Adjust to desired pH. The composition formula given in Table 2 can also effectively improve the removal rate of titanium / titanium nitride.

[0035]

Embodiment 40

[0037] The amino acid-containing polishing liquid of the present invention can also add other additives such as methyl cellulose, defoaming agent and the like. like:

[0038] 0.5wt%SiO 2 (average particle size 80nm), 1wt% proline, 0.01wt% methylcellulose, 0.01wt% polysilane defoamer, according to the method described in the above examples, was prepared into a polishing solution.

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Abstract

A polishing slurry for polishing a titanium-containing base material of the present invention includes one or more amino acids, deionized water and abrasive particles; the polishing slurry is used for polishing the titanium-containing base material. The removal rate of titanium / titanium nitride is relatively high when the polishing slurry for polishing titanium-containing substrates is used to polish the titanium-containing substrates.

Description

technical field [0001] The invention relates to a polishing agent, in particular to a polishing slurry for polishing a titanium-containing substrate. Background technique [0002] In modern semiconductor manufacturing processes, an integrated circuit often contains millions of electronic components, which are interconnected and mounted on a silicon substrate through multilayer interconnects, and are interconnected with each other through metal vias or contacts , to form a fully functional circuit. [0003] In current semiconductor manufacturing, titanium or titanium nitride is commonly used as a filler metal for metal vias or contacts. Since titanium or its alloys play an important role in the entire semiconductor manufacturing process, how to ensure the flatness of the titanium or its alloy surface after polishing is an important link in the semiconductor manufacturing process. [0004] In the polishing process of the entire semiconductor substrate, the chemical mechanica...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01L21/02C09G1/02
Inventor 张建荆建芬蔡鑫元
Owner ANJI MICROELECTRONICS TECH (SHANGHAI) CO LTD