Composition for anisotropic conductive adhesive film, anisotropic conductive adhesive film and semiconductor device
A conductive adhesion, anisotropic technology, applied in conductive adhesives, conductive materials dispersed in non-conductive inorganic materials, semiconductor devices, etc., can solve problems such as reduced dimensional stability and insufficient adhesion of glass substrates , to improve the filling rate, improve connection reliability and stability, and improve production efficiency.
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Embodiment 1
[0138] Example 1: Preparation of anisotropic conductive adhesive film
[0139] (1) Preparation of anisotropic conductive adhesive composition
[0140] By mixing 30 wt% epoxy-functional acrylate copolymer (solids content: 18%), 5 wt% carboxyl-modified acrylonitrile butadiene rubber dissolved in toluene and methyl ethyl ketone (MEK) (solid content: 25%, weight average molecular weight: 240,000g / mol, Nipol NBR, Zeon Co., Ltd.), 15wt% styrene-acrylonitrile resin dissolved in MEK (solid content: 50%, Tg: 120°C , weight average molecular weight: 100,000g / mol), 20wt% isocyanurate ethylene oxide modified diacrylate (DSC exothermic peak: 92°C to 95°C), 20wt% bisphenol fluorene diacrylate (weight-average molecular weight: 1,400g / mol), 1.5wt% acidified phosphoethyl methacrylate, 2.5wt% phosphate acrylate (weight-average molecular weight: 12,000g / mol), 1.0wt% as Organic peroxide lauroyl peroxide (solid content: 10%) dissolved in toluene and 2.0 wt% benzoyl peroxide (solid content: 10%) ...
Embodiment 2
[0145] In the same manner as in Example 1, except that the contents of acrylate copolymer, oxirane-isocyanurate-modified diacrylate and bisphenol fluorene diacrylate were changed to 35wt%, 15wt% and 25wt% respectively An anisotropic conductive film according to Example 2 was prepared.
Embodiment 3
[0147] An anisotropic conductive film of Example 3 was prepared in the same manner as in Example 1, except that the following urethane acrylate resin was used instead of the carboxy-modified acrylonitrile butadiene rubber.
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