High temperature-resistant and heat insulating sandwich structure composite material and preparation method thereof

A composite material, sandwich structure technology, applied in chemical instruments and methods, lamination, lamination devices, etc., can solve the problems of small single piece area of ​​rigid ceramic tiles, brittle failure, temperature resistance below 200 ° C, etc. The difficulty of the forming process is reduced, the strength and toughness are improved, and the high temperature resistance performance is good.

Active Publication Date: 2015-06-17
NAT UNIV OF DEFENSE TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Traditional polyurethane foam and other heat insulation materials have good heat insulation effect at room temperature, but the temperature resistance is generally lower than 200°C, and it is difficult to meet the temperature resistance requirements
[0004] The use of ceramic insulation tiles by the U.S. space shuttle played an important role, but it has inherent low toughness (generally 1-5MPa×m1 / 2), low strength (generally less than 5MPa), and high thermal conductivity (generally greater than 0.06W / m×k) and the small area of ​​a single piece (generally 200×200mm), it cannot well meet the high-reliability and high-efficiency requirements of large-area heat insulation for high-speed aircraft, and the price is very expensive
The low toughness of ceramic heat insulating tiles makes it easy to produce brittle damage during production, transportation, installation and flight, and there are great safety hazards; low strength is also one of the important factors for the damage of ceramic heat insulating tiles; brittleness increases the strength, and it is easy It leads to stress failure between the rigid ceramic tile and the bonding matrix, which is an important factor for the small area of ​​the rigid ceramic tile; the small area of ​​the single piece makes the installation more difficult, and leaves many difficult-to-handle gaps; Rigid ceramic tiles have high thermal conductivity, which will inevitably increase the thickness of ceramic tiles and reduce the effective volume and payload of the aircraft
[0005] The airgel composite material developed in recent years has a good heat insulation effect, and the temperature resistance is greater than 400°C, but the strength of the material is not high, and it is not resistant to erosion, so it cannot be directly used for external heat insulation

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] The high-temperature-resistant and heat-insulating sandwich structure composite material of this embodiment is composed of an upper surface layer, a core layer, and a lower surface layer. The core layer is a mullite short fiber reinforced silica airgel composite material. The upper surface Layer and lower surface layer are both quartz fiber cloth reinforced polyimide composite materials; the thickness of the core layer is 20mm, and the density of the core layer material is 0.32g / cm 3 , the thermal conductivity is 0.028W / m×K, the thickness of the upper surface layer is 0.8mm, and the thickness of the lower surface layer is 0.6mm.

[0025] The preparation method comprises the following steps:

[0026] (1) Mullite short fiber reinforced silica airgel composite material is selected as the core material, and the thickness of the core layer is 20mm;

[0027] The mullite short fiber-reinforced silica airgel composite material is prepared by supercritical drying method (refer ...

Embodiment 2

[0035] The high-temperature-resistant and heat-insulating sandwich structure composite material of this embodiment is composed of an upper surface layer, a core layer, and a lower surface layer. The core layer is a basalt short fiber reinforced silica airgel composite material. The upper surface layer, The lower surface layer is carbon fiber cloth reinforced polysilazane composite material; the thickness of the core layer is 25mm, and the density of the core layer material is 0.30g / cm 3 , the thermal conductivity is 0.022W / m×K, the thickness of the upper surface layer is 1.2mm, and the thickness of the lower surface layer is 0.8mm.

[0036] The preparation method comprises the following steps:

[0037] (1) Select basalt short fiber reinforced silica airgel composite material as the core material, and the thickness of the core layer is 25mm;

[0038] The basalt short fiber reinforced silica airgel composite material is prepared by supercritical drying method (refer to Chinese ...

Embodiment 3

[0046]The high-temperature-resistant heat-insulating sandwich structure composite material of this embodiment is composed of an upper surface layer, a core layer, and a lower surface layer. The core layer is a mullite short fiber reinforced alumina airgel composite material, and the upper surface layer , The lower surface layer is carbon fiber cloth reinforced polysilazane composite material; the thickness of the core layer is 20mm, and the density of the core layer material is 0.32g / cm 3 , the thermal conductivity is 0.029W / m×K, the thickness of the upper surface layer is 1.2mm, and the thickness of the lower surface layer is 0.8mm.

[0047] The preparation method comprises the following steps:

[0048] (1) Select basaltic mullite short fiber reinforced alumina airgel composite material as the core material, and the thickness of the core layer is 20mm;

[0049] The mullite short fiber-reinforced alumina airgel composite material is prepared by supercritical drying (refer to ...

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Abstract

The invention relates to a high temperature-resistant and heat insulating sandwich structure composite material and a preparation method thereof. The high temperature-resistant and heat insulating sandwich structure composite material is composed of an upper surface layer, a core layer, and a lower surface layer. The core layer is a high temperature-resistant fiber reinforced aerogel composite material, and the upper surface layer and the lower surface layer are both a high temperature-resistant fiber reinforced high temperature-resistant resin composite material. The thickness of the core layer is 3-200mm, and the thickness of the upper surface layer and the lower surface layer is 0.1-5.0mm respectively. The invention also includes a preparation method of the high temperature-resistant and heat insulating sandwich structure composite material. The high temperature-resistant and heat insulating sandwich structure composite material provided in the invention has the advantages of good high temperature resistance, low thermal conductivity, as well as good heat insulation effect. At the same time, with greatly improved strength and toughness and substantially reduced molding process difficulty, the high temperature-resistant and heat insulating sandwich structure composite material can be better suitable for aerospace and other fields.

Description

technical field [0001] The invention relates to a high-temperature-resistant heat-insulating sandwich structure composite material and a preparation method thereof. Background technique [0002] High-speed aircraft fly at high speed and for a long time in the atmosphere, and the external temperature of its fuselage exceeds 200°C, and some parts reach 400°C. In order to prevent high temperature damage to internal equipment, it must be made of high-efficiency heat-insulating materials. [0003] Traditional heat insulation materials such as polyurethane foam have good heat insulation effect at room temperature, but the temperature resistance is generally lower than 200°C, and it is difficult to meet the temperature resistance requirements. [0004] The use of ceramic insulation tiles by the U.S. space shuttle played an important role, but it has inherent low toughness (generally 1-5MPa×m1 / 2), low strength (generally less than 5MPa), and high thermal conductivity (generally gre...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B32B27/04B32B27/06B32B33/00B32B37/15
Inventor 曹峰冯坚张长瑞姜勇刚冯军宗
Owner NAT UNIV OF DEFENSE TECH
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