Original form dechroming method for chrome leather fragment, and application of product thereof in fertilizer aspect
A technology of chromium leather scraps and morphology, applied in the direction of solid waste removal, etc., can solve problems such as a large amount of chromium leather scraps hydrolysis, and achieve the effects of low hydrolysis rate, low chromium content, and reduced production costs.
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Embodiment 1
[0022] Weigh 50g of chrome leather shavings, 5g of calcium oxide, and 500mL of distilled water. After fully stirring, soak at 30°C for 2 days. During this period, stir frequently to ensure that the chrome leather shavings are fully dispersed; wash and filter, and add 350mL of distilled water and 5g of sodium chloride to the filter residue. , 10g of oxalic acid and 15mL of concentrated sulfuric acid, stir well, dechrome at 25°C for 2h, wash and filter with water; continue to add 350mL of distilled water, 5g of sodium hydroxide alkali and 8g of sodium chloride to the filter residue, and dechrome at 25°C for 40min, Adjusting the pH to neutral, fully washing with water, and filtering; drying the filter residue to obtain the original form of chrome leather shavings dechromed product.
[0023] The drying process adopts a two-step drying method: first, dry at a low temperature at 60-70°C for 3 hours to make the moisture content below 20%; then perform high-temperature drying at a cont...
Embodiment 2
[0026] Weigh 50g of chrome leather shavings, 7g of calcium oxide, and 250mL of distilled water. After fully stirring, soak at 40°C for 1 day. Stir often during this period to ensure that the chrome leather shavings are fully dispersed; wash and filter with water, and add 300mL of distilled water and 6g of sodium chloride to the filter residue. , 15g of oxalic acid and 15mL of concentrated sulfuric acid, stir well, dechrome at 30°C for 3 hours, wash and filter with water; continue to add 250mL of distilled water, 7g of sodium hydroxide and 5g of sodium chloride to the filter residue, heat and dechrome at 20°C for 30min, adjust pH to neutral, fully washed with water, filtered; drying the filter residue to obtain the original form of chrome leather shavings dechromed product.
[0027] The drying process adopts a two-step drying method: first, dry at a low temperature at 60-70°C for 4 hours to make the moisture content below 20%; then perform high-temperature drying at a controlled...
Embodiment 3
[0030] Weigh 50g of chrome leather shavings, 10g of calcium oxide, and 400mL of distilled water. After fully stirring, soak at 20°C for 4 days. During this period, stir frequently to ensure that the chrome leather shavings are fully dispersed; wash and filter, and add 200mL of distilled water and 10g of sodium chloride to the filter residue. , 10g of oxalic acid and 20mL of concentrated sulfuric acid, stir well, dechrome at 20°C for 4 hours, wash and filter with water; continue to add 500mL of distilled water, 10g of magnesium oxide and 10g of sodium chloride to the filter residue, heat at 60°C for 60min after dechrome, adjust the pH to neutral, fully washed with water, and filtered; after drying the filter residue, the original form of chromium leather scraps is obtained.
[0031] The drying process adopts a two-step drying method: firstly, dry at a low temperature at 60-70°C for 5 hours to make the moisture content below 20%; then perform high-temperature drying at a controll...
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