The invention relates to a care composite for hair, in particular to a dandruff-removal and itching-stopping care essence and a production process thereof. The dandruff-removal and itching-stopping care essence is prepared from the following raw materials: fructus chebulae, paeonol, fructus cnidii, herba portulacae, citral, eugenol, glycerinum, a seaweed extract, EDTA-2 natrium, 130 w sodium hyaluronate, polyglutamic acid, trehalose, glycereth-26, fucogel-1, aminomethyl propanol, DSBC silanol salicylate, 1,3-butanediol and a preservative. The dandruff-removal and itching-stopping care essencehas the following characteristics of clearing heat and removing toxicity, inhibiting bacteria, inhibiting growing of pathogenic bacteria and funguses causing dandruff on the surface of the scalp, nourishing blood and promoting blood circulation, dispelling wind and stopping itching, relieving the itching sensation of the scalp, enhancing the autoimmunity of the scalp skin, repairing the scalp barrier, adjusting microbial floras, and preventing the hairline from receding.