Special paper-plastic composite film for keeping freshness of fruits and vegetables at room temperature

A paper-plastic composite and film technology, which is applied in the direction of packaging paper, synthetic resin layered products, paper/cardboard layered products, etc., can solve the problems of accelerating fruits and vegetables, rotting, bacterial growth, etc., to improve the storage period and shelf life, The effect of preventing water loss and simple production process

Inactive Publication Date: 2013-06-12
沈阳中清新材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] 1 The existing fresh-keeping materials are mostly limited to plastic substrates, because the oxygen transmission rate (0TR) of general plastic substrates can only reach 10 4 ml / m 2 .day.atm cannot meet the metabolism requirements of fruits and vegetables at room temperature, and generally can only be used as fresh-keeping materials for fruits and vegetables at low temperatures, but the effect of keeping fruits and vegetables at room temperature is poor, and even at room temperature will cause anaerobic respiration of fruits and vegetables;
[0005] 2. The water vapor transmission rate (WVTR) of the existing plastic-based fresh-keeping materials is small, and the moisture generated by the metabolism of fruits and vegetables in the fresh-keeping bags is easy to form a high-humidity internal environment, causing bacteria to grow and accelerating the decay of fruits and vegetables;
[0006] 3 If the air permeability of plastic fresh-keeping packaging is increased, the thickness of the film needs to be reduced, which in turn brings about the problem of insufficient mechanical properties of the packaging, making it difficult to process the film and prepare fresh-keeping bags
[0007] In short, the respiration intensity of fruits and vegetables at room temperature is high, and the requirements for fresh-keeping packaging materials are high. The existing plastic-based fresh-keeping materials are generally only suitable for low temperature use, or only suitable for fruits and vegetables with low respiration intensity. For fruits and vegetables with high respiration intensity At room temperature, not only will it not play a role in preserving freshness, but it will accelerate the decay of fruits and vegetables

Method used

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  • Special paper-plastic composite film for keeping freshness of fruits and vegetables at room temperature

Examples

Experimental program
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Effect test

Embodiment 1

[0024] After melting and blending 50 mass parts of butyl methacrylate resin and 50 mass parts of EVA resin, as the resin raw material for coating, the blended resin is cast on 16.5 grams of paper on the casting machine, and the casting thickness is controlled. It is 5-7 micron, is prepared into inner layer paper base and is coated with EVA-acrylic ester film; After the polybutylmethacrylate of 20 mass parts and the PE (low density polyethylene) of 80 mass parts are melt-blended, as a shower The resin raw material of film, cast this resin on 16.5 gram heavy papers on tape-casting machine, control casting thickness to be 5-7 micron, be prepared into outer layer paper base coating acrylate-PE film; Dip 6 mass parts After the lactic acid of 4 mass parts is mixed with the calcium sulfite of 4 mass parts, join in the polyurethane (PU) binding agent of 90 mass parts, prepare bactericide-polyurethane binding agent, two raw material films (paper Base-coated EVA-acrylate film and outer ...

Embodiment 2-6

[0026] The preparation method is similar to that of Example 1, except that the grades of raw materials, the composition ratio, and the film thickness of the coating film are changed. The specific data are shown in Table 1.

[0027] The oxygen transmission rate of the plastic-based fresh-keeping bag prepared in comparative example 1 is lower than 10 4 ml / m 2 .day.atm, if this fresh-keeping bag (dimensions 300×400mm) contains 1 kg of fruits and vegetables, it can only meet the respiratory intensity of less than 10ml / hr.kg, and generally can only be used for low-temperature fresh-keeping fruits and vegetables. The respiration intensity is 20-50ml / hr.kg, and the respiration intensity of vegetables is greater. Therefore, plastic-based fresh-keeping bags will cause hypoxia in the storage environment of fruits and vegetables at room temperature, and they are more likely to age and rot; plastic-based fresh-keeping bags are resistant to water vapor. The rate is lower than 1g / m 2 .day...

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Abstract

The invention relates to a special environmentally-friendly fresh-keeping paper-plastic composite flexible packaging film for fruits and vegetables. The fresh-keeping packing film is made by adding a blocking layer, a germicide releasing layer and an adjusting layer between two paper-based layers; by changing the polarity and air permeability of the blocking layer and adjusting layer, the purpose of controllably releasing germicide is realized; and the film can release gas-phase germicide of 5-20 ppm for 30-90 days, has functions of water conservation, disinfection and ventilation, mainly plays the role of keeping freshness of the fruits and the vegetables at room temperature to extend the shelf lives of the fruits and the vegetables, and can be naturally degraded after being discarded, without any pollution to the environment.

Description

technical field [0001] The invention relates to a paper-plastic composite film for keeping fruits and vegetables fresh at normal temperature and a preparation method thereof. The paper-plastic composite film uses a paper base as a base film, and an adjustment layer, a bactericide release layer (adhesive layer), and a barrier layer are arranged between two layers of paper bases. It is prepared by a solvent-free composite method and has slow-release sterilization and water retention. , Breathable function, used for fresh-keeping of fruits and vegetables at room temperature. Background technique [0002] With the development of my country's urbanization process and the improvement of people's living standards, vegetables and fruits in big cities are increasingly dependent on external supply. From the place of origin to the hands of the people, they need to go through several stages of picking, gathering, long-distance transportation, wholesale, and supermarkets. Generally, it t...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B65D65/40B65D30/02B32B27/36B32B29/00B32B33/00
Inventor 李东立
Owner 沈阳中清新材料有限公司
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