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Preparation method of carissone

A technology of fake tiger ketone and magnesium oxide, which is applied in the field of natural medicinal chemistry to achieve the effects of fast separation speed, simple operation and large processing capacity

Inactive Publication Date: 2013-08-07
NANJING ZELANG AGRI DEV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] Through literature search, there is no domestic method for preparing false tiger thorn ketone from the root of Egyptian false tiger thorn

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] Grind the leaves of Akniga branchiae, take 1kg and put it into a supercritical extraction kettle, and feed it with liquid CO 2 , set the extraction pressure to 25MPa, and the temperature to 40°C. After reaching the above parameters, adjust the liquid CO 2 The flow rate is 4ml / g crude drug / min, 95% ethanol solution is used as entrainer, the amount of entrainer is 15% of the total extraction solvent, dynamic extraction is carried out for 50min, analysis is carried out at a pressure of 7.5MPa and a temperature of 40°C, and the obtained extract is dissolved in methanol , add a small amount of neutral magnesia to mix the sample, evaporate the solvent, put it on the magnesia column by dry method, gradient elution with petroleum ether-acetone 23:3, 15:3, 5:3, 2:3 mixed solvent, collect the eluate Concentrate under reduced pressure to obtain crude extract. Take petroleum ether, ethyl acetate, methanol, and water and mix according to 6:8:7:5. After mixing and layering, take the...

Embodiment 2

[0025] Grind the leaves of Aknegia chinensis, take 2kg and add it to a supercritical extraction kettle, and feed it with liquid CO 2 , set the extraction pressure to 35MPa, and the temperature to 50°C. After reaching the above parameters, adjust the liquid CO 2 The flow rate is 5ml / g crude drug / min, 99% ethanol solution is the entrainer, the entrainer dosage is 18% of the total extraction solvent, dynamic extraction is carried out for 70min, and the analysis is carried out at a pressure of 9MPa and a temperature of 32°C. After the obtained extract is dissolved in methanol, Add a small amount of neutral magnesia to mix the sample, evaporate the solvent, put it on the magnesia column by dry method, and elute with petroleum ether-acetone 21:3, 12:3, 5:3, 2:3 mixed solvent gradient elution, collect the eluate and reduce Concentrate under reduced pressure to obtain a crude extract. Take petroleum ether, ethyl acetate, methanol, and water and mix according to 7:5:6:4. After mixing ...

Embodiment 3

[0027] Grind the leaves of Aknegia chinensis, take 2kg and add it to a supercritical extraction kettle, and feed it with liquid CO 2 , set the extraction pressure to 30MPa and the temperature to 55°C. After reaching the above parameters, adjust the liquid CO 2 The flow rate is 2.5ml / g crude drug / min, 100% ethanol solution is used as entrainer, the entrainer dosage is 12% of the total extraction solvent, dynamic extraction is carried out for 90min, analysis is carried out at a pressure of 8MPa and a temperature of 35°C, and the obtained extract is dissolved in methanol , add a small amount of neutral magnesia to mix the sample, evaporate the solvent, put it on the magnesia column by dry method, gradient elution with petroleum ether-acetone 18:3, 9:3, 2:3 mixed solvent, collect the eluate and concentrate under reduced pressure to obtain crude extract. Take petroleum ether, ethyl acetate, methanol, and water and mix according to 5:7:8:7. After mixing and layering, take the upper...

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Abstract

The invention discloses a preparation method of carissone. The preparation method of the carissone comprises the following steps of: a, crushing acnistus arborescens leaves, adding the crushed acnistus arborescens leaves to a supercritical extraction kettle, and carrying out supercritical CO2 extraction by using alcohol as entrain; b, purifying the extract by adopting neutral magnesium oxide column chromatography, carrying out gradient elution by using a petroleum ether-acetone mixed solvent, collecting eluant and concentrating under reduced pressure to obtain crude extract; and c, carrying out high-speed counter-current chromatography separation on the crude extract, monitoring by an ultraviolet detector, collecting target components, refreezing and catalyzing to obtain carissone colorless crystals. The preparation method of the carissone is simple in process, high in efficiency, high in obtained product content and suitable for industrial production.

Description

technical field [0001] The invention belongs to the field of natural medicinal chemistry, and in particular relates to a preparation method of pseudohuxone. Background technique [0002] Carissone, CAS No. 473-10-9, mp.78-79℃, molecular formula C 15 h 24 o 2 , molecular weight 236.36, structural formula is [0003] . [0004] False tiger thorn ketone comes from Apocynaceae (Apocynaceae) Egyptian false tiger thorn Carissa edulis Roots of Vahl. Studies have shown that pseudohuxone has antifungal effects. After 42 days of culture on 1 mg / ml dose of agar, the inhibition rates to Aspergillus niger UA-172-1 and Aspergillus fumigatus ATCC were 60% and 100% respectively [0005] According to literature search, there is no method for preparing pseudotigerone from the root of Egyptian pseudotigerium in China. Contents of the invention [0006] The purpose of the present invention is to provide a preparation method of pseudohuxone, which has simple process, high extraction...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C07C49/733C07C45/78C07C45/79
CPCY02P20/54
Inventor 苏刘花万冬梅
Owner NANJING ZELANG AGRI DEV