Method for optimizing steel structure by adding nano particles into steel liquid

A technology of nanoparticles and molten steel, applied in the field of adding nanoparticles to molten steel to optimize the steel structure, can solve the problems of loss of nano powder, inability to disperse, low bulk density, etc., to ensure the original size, optimize the steel structure, To achieve the effect of diffuse distribution

Inactive Publication Date: 2013-08-14
ANHUI UNIVERSITY OF TECHNOLOGY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This application adopts the method of deep deoxidation of aluminum in the smelting process, so that the deep deoxidation and deep desulfurization of molten steel are easy to realize, but its disadvantages are: on the one hand, the specific surface area of ​​nano-scale MgO and CaO powder is large, easy to agglomerate, The bulk density is small, so if you directly spray pure MgO and CaO powder (one or two) into molten steel without dispersion, it is very easy to agglomerate and cannot be dispersed evenly
However, since the preparation of additives is simply isostatic pressing, without sintering and other methods to make it into a completely dense state, its density is lower than that of molten steel, so it will float up soon and cannot be dispersed in molten steel.
[0012] To sum u

Method used

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  • Method for optimizing steel structure by adding nano particles into steel liquid
  • Method for optimizing steel structure by adding nano particles into steel liquid

Examples

Experimental program
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Effect test

Embodiment 1

[0037] A method of adding nanoparticles to molten steel in this embodiment to optimize the steel structure, the steps are:

[0038] (1) Mixing and dispersing

[0039] Take magnesium oxide powder with a particle size of 100nm and pure iron powder with a particle size of 5 microns, the mass percentages are 25% and 75% respectively, and they are ground for 60 minutes by mechanical ball milling for mixing and dispersing;

[0040] (2) Preparation of nano powder rods

[0041] The mixture obtained in step (1) is sintered into a nano-powder rod by hot pressing technology under an inert gas atmosphere. The core material of the nano-powder rod is a steel rod, and the outer layer of the nano-powder rod is a mixture. The diameter of the powder rod is 150mm, the diameter of the steel rod is 100mm, the thickness of the mixture is 25mm, the pressure of hot pressing sintering is 20MPa, the sintering temperature is 1350°C, and the holding time is 10 minutes;

[0042] (3) Nano powder rod inse...

Embodiment 2

[0046] A method of adding nanoparticles to molten steel in this embodiment to optimize the steel structure, the steps are:

[0047] (1) Mixing and dispersing

[0048] Take calcium oxide powder with a particle size of 50nm and pure iron powder with a particle size of 2 microns, the mass percentages are 20% and 80% respectively, and they are ground by mechanical ball milling for 50 minutes for mixing and dispersing;

[0049] (2) Preparation of nano powder rods

[0050] The mixture obtained in step (1) is sintered into a nano-powder rod by hot pressing technology under an inert gas atmosphere. The core material of the nano-powder rod is a steel rod, and the outer layer of the nano-powder rod is a mixture. The diameter of the powder rod is 160mm, the diameter of the steel rod is 80mm, and the thickness of the mixture is 40mm. The pressure of hot pressing sintering is 30MPa, the sintering temperature is 1200°C, and the holding time is 15 minutes;

[0051] (3) Nano powder rod ins...

Embodiment 3

[0055] The basic processing steps of this embodiment are the same as those of Example 1, the difference being that in the process of mixing and dispersing, the nanopowder with a particle size of 10nm is taken (the nanopowder includes titanium nitride and silicon carbide, each of which accounts for 50% of the mass percentage) and pure iron powder with a particle size of 1 micron, the mass percentages are 40% and 60% respectively, and are ground for 90 minutes by manual grinding for mixing and dispersing; during the preparation of nano powder rods, The pressure of hot pressing sintering is 5MPa, the sintering temperature is 1350°C, and the holding time is 15min. After the nano-powder rods are completely melted, the steel clamping rods can be moved out of the molten steel using a mechanical hydraulic device. After the smelting is completed, the molten steel is sampled at high temperature. The quenched structure is similar to that of Example 1. There are a lot of acicular ferrite ...

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Abstract

The invention discloses a method for optimizing a steel structure by adding nano particles into steel liquid, which belongs to the field of ferrous metallurgy. The method comprises the following steps of: mixing and dispersing nano-powder and pure iron powder, wherein the mass percentage of the nano-powder is 1-40 percent, the mass percentage of the pure iron powder is 60-99 percent, and the average particle size of the nano-powder is 10-5,000 nm; under inert gas, sintering the mixture into a nano-powder stick by a hot-pressing technology, wherein a core material of the nano-powder stick is a steel stick, the outer layer of the nano-powder stick is provided with the mixture, the hot-pressing sintering pressure is 5-40 MPa, the sintering temperature is 1,000-1,400 DEG C, and the heat preservation time is 5-15 minutes; and inserting the nano-powder stick into the steel liquid of a steel ladle or a tundish, wherein the insertion depth of the nano-powder stick is 1/2-2/3 of the total depth of the steel liquid, and the nano-powder stick is driven by a mechanical hydraulic device to vibrate up and down or left and right. By the method, the nano particles can be effectively and uniformly dispersed and distributed in the steel liquid.

Description

technical field [0001] The invention belongs to the field of iron and steel metallurgy, and more specifically relates to a method for adding nanoparticles to molten steel to optimize steel structure. Background technique [0002] There are usually a large number of nano-second phase particles in steel. According to Yong Qilong's definition in the book "Second Phase in Iron and Steel Materials", the second phase in steel refers to the phase that is distributed in the matrix phase in a discontinuous state and cannot surround other phases in it. These nano-second phase particles have complex effects on the mechanical properties of steel due to their different types, sizes, shapes, distributions and volume fractions. [0003] The control and utilization of the second phase particles in steel has always been one of the hot issues concerned by metallurgists. The traditional idea is that the second phase particles in steel are often the cause of surface and internal defects of st...

Claims

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Application Information

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IPC IPC(8): B22F7/04B22D1/00B22F1/00B22F3/14C21C7/00
Inventor 范鼎东孔辉
Owner ANHUI UNIVERSITY OF TECHNOLOGY
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