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Anti-oxidative color masterbatch and preparation method and application thereof

An oxidation color and masterbatch technology, applied in the field of color masterbatch, can solve the problems of poor stability of antioxidant color masterbatch, poor processing performance, poor heat and weather resistance, etc., and achieves delaying fading time, good processability and uniformity good effect

Inactive Publication Date: 2013-09-11
SHANGHAI RONGXIN CHEM IND CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0008] The technical problem to be solved by the present invention is to overcome the defects of poor stability, poor heat and weather resistance and poor processability of existing anti-oxidation color masterbatches used for plastic products, and provide an anti-oxidation color masterbatch and its preparation method and application

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0038] Embodiment 1 prepares 100 kilograms of antioxidant white master batches

[0039]Raw material formula: 50 kg of titanium dioxide (titanium dioxide rutile type C.I.PW6), 5 kg of antioxidant 1076, 1.6 kg of antioxidant 168, 4 kg of light stabilizer UV-326, 10 kg of polyethylene wax and 1 kg of diethylene hard Fatty acid amide, 28.4 kg linear low density polyethylene.

[0040] Preparation method: add antioxidant 1076, antioxidant 168, light stabilizer UV-326, titanium dioxide, polyethylene wax and low-density polyethylene into a high-speed mixer and mix for 10-30 minutes, then add diethylene stearic acid Amide, stir for 5-10 minutes, add the mixture to the twin-screw extruder to extrude, cool with water, air-dry, and then cut into pellets; wherein, the temperature distribution of the twin-screw extruder is from the feed section to the machine head. 60°C, 100°C, 100°C, 110°C, 120°C, 120°C and 130°C, the head temperature is 130°C, the host speed is 1200rpm, and the feeding s...

Embodiment 2

[0045] Embodiment 2 prepares 100 kilograms of antioxidant red master batches

[0046] Raw material formula: 20 kg of pigment red (C.I.PR254), 3 kg of antioxidant 1010, 2 kg of antioxidant 1076, 2 kg of antioxidant DSTP, 3 kg of light stabilizer UV-327, 3 kg of diethylene stearic acid Amide, 10 kg polyethylene wax and 57 kg linear low density polyethylene.

[0047] Preparation method: add antioxidant 1010, antioxidant 1076, antioxidant DSTP, light stabilizer UV-327, pigment red, polyethylene wax and low-density polyethylene into a high-speed mixer and mix for 10-30 minutes, then add double Ethylene stearic acid amide, stirred for 5-10 minutes, put the mixture into the twin-screw extruder to extrude, after cooling and drying, it can be cut into pellets; wherein, the temperature distribution of the twin-screw extruder is controlled by the feeding section The temperature to the machine head is 90°C, 100°C, 100°C, 110°C, 120°C, 120°C and 130°C respectively, the temperature of the ...

Embodiment 3

[0052] Embodiment 3 prepares 100 kilograms of antioxidant ultramarine blue master batches

[0053] Raw material formula: 40 kg of ultramarine blue (C.I.PB29), 5 kg of antioxidant 1010, 2 kg of antioxidant 168, 15 kg of light stabilizer UV-531, 12 kg of polyethylene wax and 1 kg of diethylene stearic acid amide, 25 kg linear low density polyethylene.

[0054] Preparation method: add antioxidant 1010, antioxidant 168, light stabilizer UV-531, ultramarine blue, polyethylene wax and low-density polyethylene into a high-speed mixer and mix for 10-30 minutes, then add diethylene stearic acid amide , stirred for 5-10 minutes, added the mixture to the twin-screw extruder to extrude, cooled with water, air-dried, and cut into pellets to obtain; wherein, the temperature distribution of the twin-screw extruder was 60°C from the feed section to the machine head. °C, 100 °C, 100 °C, 110 °C, 120 °C, 120 °C and 130 °C, the head temperature is 130 °C, the host speed is 1200 rpm, and the feed...

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PUM

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Abstract

The invention discloses an anti-oxidative color masterbatch. The anti-oxidative color masterbatch comprises the following raw materials in percentage by weight: 10-70% of pigment, 1-22% of antioxidant composition, 5-30% of dispersion and lubrication agent, 20-60% of carrier resin and 0-15% of filler, wherein the antioxidant composition comprises a hindered phenolic antioxidant and one or more of a phosphite antioxidant, a thio antioxidant and a light stabilizer. The invention further discloses a preparation method and application of the anti-oxidative color masterbatch. The anti-oxidative color masterbatch disclosed by the invention has the advantages of good uniformity, good stability, good processability, good mobility and good heat and weather resistance; the preparation method of the anti-oxidative color masterbatch has the advantages of simplicity, no pollution to factory buildings and no pollution to operating personnel; and during use, the dispersion is easy, the adding dosage is small, the service lives of plastic products can be prolonged remarkably, the brightness of colors of the plastic products can be increased, and the fading time of the plastic products can be delayed.

Description

technical field [0001] The invention relates to the field of color masterbatches, in particular to an anti-oxidation color masterbatch and its preparation method and application. Background technique [0002] Plastics are synthesized from raw materials such as petroleum, natural gas or coal, and can be produced on a large scale. Plastic products are easy to form and process. Therefore, plastics can be made as smooth as silk, as strong as steel, as light as sponge, and as transparent as glass. Plastic products can replace traditional materials and fill every corner of the world. Plastic is an important material in daily life, and its application fields are constantly expanding. However, whether it is natural or synthetic, polymer materials are prone to oxidation reactions. The degradation of polymers due to the reaction with oxygen in the air during preparation, processing, storage and use is called thermo-oxidative degradation. The research on the thermal oxygen degradatio...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/12C08L23/06C08L23/08C08K13/02C08K5/13C08K5/524C08K5/36B29B9/06B29C47/92C08J3/22D01F6/46D01F1/04D01F1/10B29C48/92
Inventor 刘英
Owner SHANGHAI RONGXIN CHEM IND CO LTD
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