Method and device for removing oxynitride in smoke by organic waste

A technology for organic waste and nitrogen oxides, applied in the field of environmental pollution control, can solve the problems of high comprehensive cost, difficult to fundamentally improve environmental performance and environmental quality, and high operating cost, so as to improve the enthusiasm for operation, reduce waste of ammonia resources, and improve the atmospheric environment. Effect

Inactive Publication Date: 2013-09-18
CHINESE RES ACAD OF ENVIRONMENTAL SCI
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AI Technical Summary

Problems solved by technology

If my country's cement kilns and coal-fired industrial boilers adopt the SNCR ammonia denitrification technology, about 2.5 million tons of ammonia will be consumed each year, accounting for 5% of the total ammonia production in the country, and its by-product is non-recyclable nitrogen, which will compete with farmers for food. , waste of ammonia resources
[0017] Second, a large waste of resources and energy
[0018] Third, the overall cost is high
The pollution control process is complex and lengthy, with large investment and high operating costs, and the construction of polluting facilities is more important than operation, which makes it difficult to fundamentally improve the environmental performance of enterprises and the environmental quality of the region

Method used

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  • Method and device for removing oxynitride in smoke by organic waste

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Embodiment 1

[0033] Taking the organic waste water from the production of acrylic acid in petrochemical industry as an example, its main organic component is sodium acrylate solution (C 3 h 3 o 2Na, COD concentration is 19.8%). The organic wastewater is pressurized to 0.5MPa by the mud pump and then transported to the organic waste surge tank. After being compressed, it enters the gas interface of the spray gun; after the organic waste water and compressed air are mixed in the spray gun, they are sprayed into the high temperature area of ​​the furnace. Through the thermal gravimetric spectrum of the temperature-programmed decomposition of sodium acrylate in air, and the infrared spectrum analysis of its decomposition products, the results show that the decomposition product of sodium acrylate organic wastewater at high temperature is Na 2 CO 3 +C 5 h 6 O, C 5 h 6 O undergoes a redox reaction with NO in the high temperature region, and the overall reaction equation is: 2C 3 h 3 o ...

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Abstract

The invention provides method and device for removing oxynitride in smoke by organic waste. The method comprises the following steps: spraying concentrated organic waste to a high temperature area of a boiler or a kiln hearth to be contacted and reacted with smoke, wherein the chemical oxygen demand of the organic waste is greater than 150g/L; and decomposing the organic waste into small molecular hydrocarbon which is reacted with oxynitride in smoke to generate nitrogen and water so as to remove oxynitride in smoke. The device comprises an organic waste storage tank, a slush pump, an organic waste pressure stabilizing tank, an air compressor, an air pressure stabilizing tank and a plurality of spray guns, wherein the spray guns are arranged in the high temperature area of the boiler or the kiln hearth by layers. Each spray gun is provided with a liquid connector and a gas connector. The liquid connector is sequentially connected with the organic waste pressure stabilizing tank, the slush pump and the organic waste storage tank, while the gas connector is sequentially connected with the organic waste pressure stabilizing tank and the air compressor. By means of treatment of wastes with processes of wastes against one another, the method and device provided by the invention are efficient, and the operating cost for treating waste and removing oxynitride in smoke is lowered.

Description

technical field [0001] The invention relates to a method and a device for removing nitrogen oxides in flue gas by using organic waste, and belongs to the technical field of environmental pollution control. Background technique [0002] Nitrogen oxides (mainly nitric oxide and nitrogen dioxide) are important causes of photochemical smog and acid rain. Nitrogen oxides and hydrocarbons react with ultraviolet radiation to form photochemical smog. Photochemical smog has a special smell, which can irritate human eyes, nose, trachea and lungs and other organs, resulting in symptoms such as red eyes, wheezing and coughing. Long-term damage can cause lung function decline , bronchial inflammation, and even develop into cancer; nitrogen oxides and ammonia produce nitrate fine particles, reducing atmospheric visibility; nitrogen oxides and water produce nitric acid and nitrous acid, forming acid rain and endangering the ecological environment. [0003] In 2011, my country's nitrogen o...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01D53/78B01D53/56
Inventor 张凡石应杰都基峻王红梅刘宇王凡田刚曹晴张辰王相凤
Owner CHINESE RES ACAD OF ENVIRONMENTAL SCI
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