Novel derusting material

A metal and aspect technology, applied in the field of rust removal compositions, can solve the problems of excessive corrosion of steel, easy formation of acid mist, and unusable devices

Inactive Publication Date: 2015-07-08
TIANDI SCI & TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The current commercially available liquid rust removers have the main disadvantage of unsatisfactory rust removal effect, and in the case of long-term use, they will corrode the metal, and the latter will instead cause more serious secondary rust and corrosion or even cause the device to be completely damaged. can not be used
[0003] Traditional chemical rust removal usually uses strong acid, which can chemically react with rust and metal oxides to generate soluble salts, so as to achieve the purpose of rust removal. At the same time of rust removal, acid can react with base metal to release hydrogen, hydrogen It can generate pressure on rust and insoluble scale, which is beneficial to their peeling and reduction of high-valent iron, and accelerates the pickling process, but the traditional acid treatment method also has obvious defects: that is, the large amount of hydrogen gas in the process The occurrence of hydrogen embrittlement will cause the steel to have hydrogen embrittlement, which will cause the mechanical properties of the metal to decline and affect the strength of the steel itself; at the same time, it is easy to form acid mist, which will affect the health of the operator and corrode the surrounding equipment and environment; the consumption of acid is also large. Increases disposal costs; these acids can over-corrode steel
In addition, the residues produced in large quantities need to be discharged frequently, which not only seriously corrodes industrial pipelines, but also pollutes the soil and the environment.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] Embodiment 1: Preparation of 2-(2-nitro-phenylthio)-benzoic acid:

[0028] In a 250 ml three-necked flask, weigh o-chloronitrobenzene (63.4mmol) and 2-mercaptobenzoic acid (62.9mmol), add 110 ml of absolute ethanol, stir, then add potassium hydroxide (138.8mmol), Heating to reflux gradually dissolved the solid. After the reaction (about 8 hours), the reaction solution was cooled to room temperature, and a large number of yellow solids were precipitated. Filter to collect the filter cake. After the filtrate was concentrated, 50 ml of ethyl acetate was added, and a yellow solid precipitated again, which was filtered again. The filter cakes were combined and washed with 100 ml of ethyl acetate. The obtained filter cake was transferred into a 500 ml beaker, 200 ml of water was added, stirred, and the pH value was adjusted to 3-4 with 6N hydrochloric acid, and a yellow solid was precipitated. After filtration, the filter cake was washed twice with water (2×100 ml) and dr...

Embodiment 2

[0030] Example 2: Preparation of (4-(2-(2-hydroxyethoxy)-ethyl))piperazinyl-(2-(2-nitro)phenylthio)-methanone:

[0031]In a 250 ml three-necked flask, weigh 2-(2-nitro-phenylthio)-benzoic acid (36.3 mmol), add 120 ml of toluene, stir, slowly add thionyl chloride (12 ml, 164.4mmol), after the addition was completed, the reaction was refluxed for 12 hours (TLC monitored the reaction). After the reaction was completed, it was cooled to room temperature, and toluene and excess thionyl chloride were distilled off under reduced pressure. Another 200 ml of toluene was added to obtain a toluene solution of the acid chloride. The toluene solution of the resulting acid chloride was transferred to another 500 ml three-necked flask, stirred, and under cooling in an ice-water bath, triethylamine (8 ml, 57.4 mmol) was added dropwise. 1-[2-(2-Hydroxyethyl)piperazine (36.3mmol) was added. After the reaction was incubated for 30 minutes, the reaction was stirred at room temperature for 8 hou...

Embodiment 3

[0033] Embodiment 3: the preparation of formula I compound crystal:

[0034] Accurately weigh the compound of formula I obtained above, put it into an agate grinding body and grind it thoroughly, and then put the sample into a platinum crucible. Put it into a box furnace at 90°C for pre-sintering and grinding. Finally, keep the temperature at 150°C for 6 hours, and slowly cool to room temperature in stages (first stage: drop to 100°C at a rate of 2°C / h; second stage: drop from 100°C to room temperature at a rate of 10°C / h ). Finally, white powdery crystals were obtained at the bottom of the crucible. Carry out single crystal X-ray diffraction crystallography to this crystal and analyze its crystal structure, and its crystallographic parameter is, described crystal belongs to monoclinic crystal system, and its space group is P21, β=91.2°,

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PUM

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Abstract

The invention relates to a novel derusting material and a composition containing the same. The derusting material has a chemical formula as shown in a formula I; the composition consists of the following components: 10-20 parts of a compound shown in formula I, 1-8 parts of a penetrating agent, 2-10 parts of a surfactant, 0.5-5 parts of corrosion inhibitor and the balance of water to 100 parts by weight.

Description

technical field [0001] This invention relates to rust removing compositions, and in particular, to metal-targeted rust removing compositions useful for cleaning metal devices for medical or commercial use. Background technique [0002] Ferrous metal (steel) is prone to rust when placed outdoors or in the open air, which not only affects the appearance quality, but also affects the normal progress of painting, bonding and other processes. Economic losses. Stainless steel medical devices in some special fields such as medical or commercial use tend to rust and corrode during use, mainly for the following three reasons. First, devices are often exposed to organic contaminants such as disinfectants, body secretions, body fluids or blood. Salts and iodides contained in organic pollutants are corrosive and destructive to the chromium layer of the device. In particular, dry organic contamination on the device is more damaging. Second, devices are often subjected to chemical or ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C07D295/192C23G1/04
Inventor 石荟琦
Owner TIANDI SCI & TECH CO LTD
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