High-smoke suppression and high-oxygen index phenolic aldehyde fire-proof heat-preserving board and preparation method thereof

A technology of fireproof insulation board and high oxygen index, which is applied in the field of building fireproof materials, can solve the problems that the oxygen index and smoke suppression degree of phenolic insulation board cannot be satisfied, and achieve the effect of good isolation of flame retardancy and prevention of dark fire

Inactive Publication Date: 2013-10-02
TIANJIN CHENGJIAN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The oxygen index and smoke suppression degree of the phenolic insulation boards currently used cannot meet the current national requirements for thermal insulation materials for interior and exterior walls of buildings. This is the main problem restricting the application of phenolic insulation materials.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0040]A high smoke suppression, high oxygen index phenolic fireproof insulation board is a composite product composed of inorganic-organic components, including the parts by mass of each component: phenolic resin 100, intumescent flame retardant 15, liquid flame retardant Combustion agent 8; zinc borate 12, vitrified microbead 2, fly ash 6, silica fume 1, magnesium hydroxide 1; foaming agent 6, foam stabilizer 6, curing agent 25.

Embodiment 2

[0042] A method for preparing a high smoke suppression and high oxygen index phenolic fireproof insulation board. The product is an organic-inorganic composite high smoke suppression and high oxygen index fireproof insulation board. It is a composite product composed of inorganic-organic components. The insulation board is mainly made of flame-retardant phenolic resin, and the ratio is according to the following mass fraction: (all ratios are based on 100 parts of phenolic mass). The organic components are: phenolic resin 100, expansion type Flame 10-20%, liquid flame retardant 5-10%. Inorganic components: 10-15% zinc borate, 1-3% expanded vitrified beads, 5-8% hollow fly ash, 1-2% silica fume, 1-2% magnesium hydroxide. Other additives: foaming agent 5-7%, foam stabilizer 5-7%, curing agent 20-30%.

[0043] The preparation method of organic-inorganic composite phenolic insulation board involved in the present invention, concrete implementation steps are as follows:

[0044] ...

Embodiment 3

[0050] A kind of preparation method of organic-inorganic composite high smoke suppression, high oxygen index phenolic fire insulation board, carry out according to the following steps:

[0051] (1) Weigh 60g of phenolic aldehyde, 3g of liquid flame retardant, 6g of intumescent flame retardant, 6g of zinc borate, 1.8g of intumescent vitrified beads, 3g of hollow fly ash, 1.2g of silica fume, and 1.2g of magnesium hydroxide.

[0052] (2) Take 3g of foaming agent and 3g of foam stabilizer and pour them into (1) successively, put them under the electric stirrer and stir evenly at the speed of 1000r-2500r / min.

[0053] (3) Take 13g of curing agent and pour it into (2) and put it under the electric stirrer to stir rapidly at the speed of 2000-3500r / min;

[0054] (4) Pour the mixed ingredients stirred in (3) into the mold, and heat and cure at 70-80°C for 15-20min;

[0055] (5) Demould the cured phenolic fireproof insulation board.

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PUM

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Abstract

The invention relates to a high-smoke suppression and high-oxygen index phenolic aldehyde fire-proof heat-preserving board and a preparation method thereof and belongs to the technical field of a building fire-proof material. The high-smoke suppression and high-oxygen index phenolic aldehyde fire-proof heat-preserving board comprises the following components in parts by mass: 100 parts of phenolic resin, 10 to 20 parts of expansive fire retardant, 5 to 10 parts of liquid fire retardant, 5 to 8 parts of coal ash, 1 to 2 parts of tiny silicon powder, 1 to 2 parts of magnesium hydroxide, 5 to 7 parts of foaming agent, 5 to 7 parts of foam stabilizer and 20 to 30 parts of curing agent. The preparation method of the high-smoke suppression and high-oxygen index phenolic aldehyde fire-proof heat-preserving board comprises the following steps of 1) preparing a mixed slurry, i.e. (1) optionally selecting a formula, (2) mixing the phenolic resin and the liquid fire retardant, (3) mixing the expansive fire retardant, the hollow coal ash, the magnesium hydroxide and the tiny silicon powder, and adding the mixture into the mixed liquid, (4) adding the foaming agent and the foam stabilizer, and uniformly stirring the materials, and (5) adding the curing agent, stirring the materials, and filling the mixture into a die; and 2) molding and curing to obtain the fire-proof heat-preserving board. The fire-proof heat-preserving board has the advantages of convenience in construction, good fire resistance, low water absorption per volume, capability of meeting the requirements of high smoke suppression and high oxygen index of inner and outer wall heat-preserving boards, and the like.

Description

technical field [0001] The invention belongs to the technical field of building fireproof materials, and in particular relates to a phenolic fireproof heat preservation board with high smoke suppression and high oxygen index and a preparation method thereof. Background technique [0002] Currently, one of the major sources of energy consumption in buildings is the loss of energy through the materials that make up the building envelope. In order to prevent energy loss, the application of thermal insulation materials is the most direct and effective way to save energy in buildings. Building insulation materials are mainly divided into two categories: organic and inorganic. Organic and inorganic insulation materials can be used alone, in combination or with other materials after proper compounding, thus forming a variety of building insulation materials and building external insulation systems. Phenolic foam is an organic hard foam insulation material, which has the dual advan...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L61/06C08L63/00C08K13/02C08K3/32C08K5/053C08K5/3492C08K3/34C08K3/22C08J9/08
Inventor 刘洪丽李国遵李亚静扈世有韩立杨久俊曲烈
Owner TIANJIN CHENGJIAN UNIV
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