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Poss-based hybrid fluorine-containing acrylate resin and its preparation method and application

A technology of fluorine-containing acrylate and acrylic acid, applied in the direction of polyurea/polyurethane coatings, coatings, etc., to achieve the effect of simple synthesis conditions, high-efficiency oil-water separation characteristics, and strong mechanical properties

Inactive Publication Date: 2016-01-20
SOUTH CHINA UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This application introduces POSS bases into traditional polymers to prepare hydrophobic, amphiphilic, and hydrophobic and oleophobic coatings respectively. However, there is no literature report on the application of POSS-based fluoropolymers to metal filters to construct micro-nano dual-scale composite rough structures. To achieve the effect of superhydrophobic and superoilophilic, so as to realize the efficient separation of oil and water and the efficient transportation of oil

Method used

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  • Poss-based hybrid fluorine-containing acrylate resin and its preparation method and application
  • Poss-based hybrid fluorine-containing acrylate resin and its preparation method and application

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0038] In the first step, when equipped with an electric mixer, N 2 Add 12g of butyl acetate as a solvent to the four-necked flask with the gas guide tube, condensing reflux tube and constant pressure funnel, heat up to 75°C and reflux for 30min, and feed N 2 , then mix 1.2g methyl methacrylate, 1.9g butyl acrylate, 2.1g lauryl acrylate, 1.5g-β-hydroxyethyl methacrylate, 0.135g azobisisobutyronitrile and 4g butyl acetate After uniformity, add it to the constant pressure funnel, stir at a speed of 350 rpm, and drop it continuously within 2.5 hours, and continue the insulation reaction for 3 hours after the dropwise addition;

[0039] In the second step, 1.0g of trifluorooctyl methacrylate, 0.019g of azobisisobutyronitrile and 2g of butyl acetate were mixed evenly and added to the constant pressure funnel, and then added dropwise to the reaction system of the first step at a constant speed , continuous dripping within 1.5h, and continue the insulation reaction for 3h after the ...

Embodiment 2

[0043] In the first step, when equipped with an electric mixer, N 2 Add 10 g of butyl acetate as a solvent to the four-neck flask with the gas guide tube, condensing reflux tube and constant pressure funnel, heat up to 90 ° C and reflux for 30 min, and feed N 2 , then mix 0.8g tert-butyl methacrylate, 1.2g isooctyl acrylate, 1.8g hexadecyl acrylate, 1.4g hydroxybutyl methacrylate, 0.104g benzoyl peroxide and 3g butyl acetate Add it to the constant pressure funnel, stir at 350 rpm, drop it continuously within 3 hours, and continue the insulation reaction for 3.5 hours after the dropwise addition;

[0044] In the second step, mix 0.8g hexafluorobutyl acrylate, 0.015g benzoyl peroxide and 2g butyl acetate evenly and add them to the constant pressure funnel, then drop them into the reaction system of the first step at a constant speed, within 0.5h After the continuous dripping, continue the insulation reaction for 2 hours after the dripping;

[0045] In the third step, 4g POSS-b...

Embodiment 3

[0048] In the first step, when equipped with an electric mixer, N 2 Add 11 g of butyl acetate as a solvent to the four-neck flask with air duct, condensing reflux tube and constant pressure funnel, raise the temperature to 80 ° C and reflux for 30 min, and feed N 2 , then mixed 1.8g methyl methacrylate, 2.7g isooctyl acrylate, 2.4g octadecyl methacrylate, 1.7g hydroxypropyl methacrylate, 0.184g azobisisobutyronitrile and 3g butyl acetate After uniformity, add it to the constant pressure funnel, stir at a speed of 350 rpm, and drop it continuously within 2.5 hours, and continue the heat preservation reaction for 4 hours after the dropwise addition;

[0049] In the second step, 1.2g of 2-(perfluorooctyl)ethyl methacrylate, 0.02g of azobisisobutyronitrile and 2g of butyl acetate were mixed evenly and added to the constant pressure funnel, and then added dropwise to the first In the reaction system of the first step, the continuous dripping is completed within 1.5h, and the insul...

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Abstract

The invention discloses a POSS (Polyhedral Oligomeric Silsesquioxane) based hybridized fluorinated acrylate resin, and a preparation method and an application thereof. The formula of the resin comprises the following components by weight percent: 0.9-14% of POSS based monomer, 1.5-10% of hard monomer, 2.5-14% of soft monomer, 4-10.5% of acrylic higher ester monomer, 1.8-6% of fluoridized acrylate monomer, 1.8-9% of cross-linked monomer, 0.4-1.5% of initiator and 50-80% of solvent. According to the invention, the acrylic higher ester monomer is introduced as an oleophilic monomer into a fluorinated acrylate copolymer and then a hydrophobic and oleophilic compound multi-scale structure is established on filter paper or a metal filter screen by virtue of aggregating self-assembly of the POSS base in the copolymer; therefore, a hydrophobic and oleophilic coating is prepared. The resin coating prepared from the resin provided by the invention is applicable to the oil-water separation field and capable of removing trace moisture in the fuel oil, and has great practical application significance.

Description

technical field [0001] The invention relates to an acrylate resin, in particular to a POSS-based hybrid fluorine-containing acrylate resin with superhydrophobic and superlipophilic properties, its preparation method and application; it belongs to organic / inorganic hybrid materials. Background technique [0002] With the development of aviation and automobile industries, people have higher and higher requirements for aircraft and automobile engines. As the "blood" of the engine - fuel and hydraulic oil, their quality directly affects the performance of the engine. Oil water content is an important indicator of oil quality and one of the main causes of engine failure. The filter in the engine uses coalescence separation to remove impurities such as particles and water in the oil. It is of great practical significance to select a filter screen (filter paper) with good hydrophilic and oleophobic properties to separate the water in the oil. [0003] In recent years, the research...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08F220/18C08F220/28C08F220/14C08F220/22C08F2/06C08F8/42C09D175/04
Inventor 皮丕辉廖达文秀芳蔡智奇徐守萍程江
Owner SOUTH CHINA UNIV OF TECH
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