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Bentonite modifier and application thereof

A technology of soil modifier and bentonite, which is applied in the field of bentonite modifier, can solve problems such as damage to excellent properties, no waterproof and anti-seepage modification or anti-seepage and anti-salt corrosion modification, and weakened cement hydrated mineral bonding ability, etc., to achieve Promotes the refinement of crystal minerals and the effect of increasing the strength of cement stone

Active Publication Date: 2014-01-08
长沙紫宸科技开发有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] However, although bentonite has excellent water absorption expansion, suspension dispersion, water retention, lubricity, and stability, the current unmodified bentonite and various modified bentonites are still not suitable for adding cement concrete as a waterproofing agent or Waterproof and anti-seepage agent or anti-seepage and anti-salt decoration additive. The reason is that montmorillonite, the main mineral of bentonite, is a kind of clay mineral, which still has the characteristics of clay mineral. In the environment, under the joint action of hydrated calcium silicate gel, ferric aluminate and calcium hydroxide crystal minerals and complex ion exchange in the cement hydration process, there is no relationship between bentonite or modified bentonite and cement hydrated minerals. Form an effective fusion zone or strengthen the transition zone, and secondly, bentonite or premature full expansion will cause separation and dry shrinkage channels with cement hydrated minerals, or the original excellent performance will be destroyed or inhibited, and the cementing ability of cement hydrated minerals will also increase. Simultaneously weakened by clay-type minerals
That is, there is still a lack of a modifier that allows bentonite to play an effective waterproof and anti-seepage effect in cement concrete at home and abroad, and a conditioner that can adjust and improve the performance of bentonite in the cement concrete medium environment, resulting in no suitable for cement. Bentonite modifier for concrete waterproof and anti-seepage modification or anti-permeability and salt corrosion modification

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0016] Lithium thiosulfate, ethylene glycol, triethanolamine and water are mixed evenly in the ratio of lithium thiosulfate: ethylene glycol: triethanolamine and water in a mass ratio of 1: 1: 1: 1, dissolved to make a liquid solution, That is, bentonite modifier.

[0017] In the bentonite purification process, the obtained bentonite modifier is added to the bentonite suspension, stirred evenly, the amount of the bentonite modifier added is 0.8% of the dry weight of the bentonite, aged for 2 hours, dried and powdered according to the conventional process, to obtain Modified bentonite that can be used in cement and concrete.

[0018] With this modified bentonite is mixed in 32.5 grade cement powder by 5% of cement gross weight, mixes evenly, test detects that cement compressive strength improves 7Mpa in 3 days, and 28 days intensity improves 6Mpa; This cement is used for toilet construction, through After 2 years of observation, no signs of leakage and salt corrosion were foun...

Embodiment 2

[0020] Sodium thiosulfate, ethylene glycol, isopropanolamine and water are uniformly mixed according to the mass ratio of sodium thiosulfate, ethylene glycol, isopropanolamine and water in a ratio of 0.85:1:1:1.1, dissolved, and prepared into a liquid solution to obtain the bentonite modifier.

[0021] In the bentonite grinding process, the obtained bentonite modifier is continuously and evenly added to the bulk granular dry bentonite, and the amount of the bentonite modifier added is 1.5% of the dry weight of bentonite, and they are ground together to form bentonite powder, namely It is a modified bentonite that can be used in cement and concrete.

[0022] In this way, the modified bentonite is blended into 32.5 grade cement powder according to 7% of the total weight of the cement, homogenized, and the test detects that the compressive strength of the cement increases by 5Mpa in 3 days, and the strength increases by 5Mpa in 28 days. When this cement is used in the constructi...

Embodiment 3

[0024] Potassium thiosulfate, ethylene glycol and isopropanol, triethanolamine and water are mixed uniformly and dissolved according to the mass ratio of potassium thiosulfate 1, ethylene glycol 0.5 and isopropanol 0.3, triethanolamine 1 and water 1.2, and the preparation into a liquid solution to obtain the bentonite modifier.

[0025] Add the obtained bentonite modifier into the bentonite powder, stir evenly, the amount of the bentonite modifier added is 1% of the weight of the bentonite powder, and age for 8 hours to obtain the modified bentonite powder that can be used for cement and concrete.

[0026] In this way, the modified bentonite is added into 42.5 grade cement powder according to 10% of the total weight of the cement, and homogenized; the compressive strength of the cement is increased by 5Mpa in 3 days, and the strength is increased by 5Mpa in 28 days. This cement was used for the construction of the kitchen utensil cleaning pool. After 2 years of observation, no...

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PUM

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Abstract

The invention relates to a bentonite modifier which comprises a water soluble inorganic matter thiosulfate, an organic matter alcohol compound and an amine compound. The modifier is formed by uniformly mixing and dissolving the water soluble inorganic matter thiosulfate, the organic matter alcohol compound and the amine compound with water at a mass ratio of (0.5-1):(0.5-1):(0.5-1):(0.5-1.5). The bentonite modifier provided by the invention is wide in source of raw materials, simple in preparation method, low in cost and good in economical efficiency. Bentonite modified by the bentonite modifier provided by the invention and used in cement can be used for effectively improving the cement strength and the impermeability and salt corrosion resistances of concrete.

Description

technical field [0001] The invention relates to a bentonite modifier, in particular to a bentonite modifier which can be used in cement concrete and an application method thereof. Background technique [0002] Bentonite, also known as bentonite or bentonite, is a clay rock mainly composed of montmorillonite. The chemical formula of montmorillonite is 4SiO 2 ·Al 2 o 3 ·H 2 O, the crystal structure of montmorillonite is a 2:1 layered silicate composed of two layers of silicon-oxygen tetrahedral sheets sandwiched by a layer of aluminum-oxygen octahedral sheets. It has water absorption, swelling, dispersion and suspension, and viscosity. It has a series of physical and chemical properties such as binding, adsorption of organic matter, catalytic activity, thixotropy, plasticity, lubricity and cation exchange, and has good thermal and chemical stability. [0003] Due to the many excellent properties of bentonite's unique mineral structure and crystallization chemical proper...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B24/12C04B22/14C04B22/08
Inventor 尹无忌
Owner 长沙紫宸科技开发有限公司
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