Anti-impact environment-friendly flame-retardant polybutylene terephthalate composite material

A polybutylene terephthalate and composite material technology, which is applied in the field of impact-resistant, environment-friendly, flame-retardant polybutylene terephthalate composite materials, and can solve the problem of halogen-containing flame retardants with large fumes and gaps. Low impact strength, non-compliance with environmental protection requirements, etc., to achieve the effects of low smoke environmental protection weather resistance, excellent comprehensive performance, and good weather resistance

Inactive Publication Date: 2014-01-22
QINGDAO XINZHAN PLASTIC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, due to the presence of benzene rings, ester groups and methylene groups in the PBT molecular structure, the PBT molecular chain is relatively rigid and has a high crystallization rate, resulting in low notched impact strength and poor flame retardancy of PBT materials.
With the development of society and human beings' emphasis on environmental protection, due to the large amount of smoke generated by halogen-containing flame retardants during combustion, and the release of toxic and corrosive gases that seriously endanger human health and do not meet environmental protection requirements, halogen-containing flame retardants PBT materials for fuel are restricted in many products

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] An impact-resistant, environmentally friendly, and flame-retardant polybutylene terephthalate composite material, the components of which are proportioned by mass percentage: 50% polybutylene terephthalate, hyposalate flame retardant CJ- 1002 18%, acrylic graft silicone type LP2085 impact modifier 1%, alkali-free glass fiber 25%, silane coupling agent 2.5%, phenolic antioxidant 1076 and phosphite antioxidant 168 Compound 0.4%, ethylene copolymer containing epoxy groups 2.5%, OP wax 0.6%.

[0019] Preparation method: (1) Weigh and batch the above-mentioned components in proportion; (2) Dry butylene phthalate at 120°C-130°C for 4-6 hours, and control the moisture content below 0.03%. (3) Combine the dried butylene phthalate with hyposalate flame retardant CJ-1002, acrylic grafted silicone type LP2085 impact modifier, and phenolic antioxidant 1076 Add the compound with phosphite antioxidant 168, ethylene copolymer containing epoxy groups and OP wax into the mixing tank, s...

Embodiment 2

[0021] An impact-resistant, environmentally friendly, and flame-retardant polybutylene terephthalate composite material, the components of which are proportioned by mass percentage: 45% polybutylene terephthalate, hyposalate flame retardant CJ- 1002 18%, acrylic graft silicone type LP2085 impact modifier 1%, alkali-free glass fiber 30%, silane coupling agent 3%, phenolic antioxidant 1076 and phosphite antioxidant 168 Compound 0.5%, ethylene copolymer containing epoxy groups 2%, TAF 0.5%.

[0022] Preparation method: (1) Weigh and batch the above-mentioned components in proportion; (2) Dry butylene phthalate at 120°C-130°C for 4-6 hours, and control the moisture content below 0.03%. (3) Combine the dried butylene phthalate with hyposalate flame retardant CJ-1002, acrylic grafted silicone type LP2085 impact modifier, and phenolic antioxidant 1076 Add the compound with phosphite antioxidant 168, ethylene copolymer containing epoxy groups and TAF into the mixing tank, stir to mak...

Embodiment 3

[0024] An impact-resistant, environmentally friendly, and flame-retardant polybutylene terephthalate composite material, the components of which are proportioned by mass percentage: polybutylene terephthalate 60%, hyposalate flame retardant CJ- 1002 18%, acrylic graft silicone type LP2085 impact modifier 1%, alkali-free glass fiber 18%, silane coupling agent 1.8%, phenolic antioxidant 1076 and phosphite antioxidant 168 Compound 0.3%, ethylene copolymer containing epoxy group 0.6%, calcium stearate 0.3%.

[0025] Preparation method: (1) Weigh and batch the above-mentioned components in proportion; (2) Dry butylene phthalate at 120°C-130°C for 4-6 hours, and control the moisture content below 0.03%. (3) Combine the dried butylene phthalate with hyposalate flame retardant CJ-1002, acrylic grafted silicone type LP2085 impact modifier, and phenolic antioxidant 1076 Add the compound with phosphite antioxidant 168, ethylene copolymer containing epoxy groups and calcium stearate into...

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PUM

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Abstract

The invention discloses an anti-impact environment-friendly flame-retardant polybutylene terephthalate composite material, comprising the following components by mass percent: 45-60% of polybutylene terephthalate, 18-25% of halogen-free flame retardant, 0.5-3% of anti-impact modifier, 5-40% of alkali-free glass fiber, 0.5-4% of silane coupling agent, 0.2-0.5% of antioxidant, 0.5-5% of flexibilizer, and 0.1-1% of lubricant. By adopting the anti-impact environment-friendly flame-retardant polybutylene terephthalate composite material, the impact resistance, the flame retardant property, the weatherability, the compatibility, the dispersing performance and the service life of polybutylene terephthalate are well balanced; the composite material is halogen-free and flame-retardant, free of poison, low in smoke and good in environmental protection property. Thus, the polybutylene terephthalate composite material with excellent overall performance is provided; the application field of polybutylene terephthalate is expanded.

Description

technical field [0001] The invention relates to a polybutylene terephthalate composite material, in particular to an impact-resistant, environment-friendly and flame-retardant polybutylene terephthalate composite material. Background technique [0002] Polybutylene terephthalate (PBT for short) is one of the five major engineering plastics and is widely used because of its excellent electrical properties and processing properties. However, due to the presence of benzene rings, ester groups and methylene groups in the PBT molecular structure, the PBT molecular chain is relatively rigid and has a high crystallization rate, resulting in low notched impact strength and poor flame retardancy of PBT materials. With the development of society and human beings' emphasis on environmental protection, due to the large amount of smoke generated by halogen-containing flame retardants during combustion, and the release of toxic and corrosive gases that seriously endanger human health and ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L67/02C08L51/08C08K13/04C08K7/14C08K5/5313B29C47/92B29C48/92
CPCB29C48/04B29C48/40B29C48/911B29C48/92B29C2948/926B29C2948/92885
Inventor 不公告发明人
Owner QINGDAO XINZHAN PLASTIC
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