Light hydrocarbon separation method used in methanol to olefin device

A technology of methanol to olefins and separation method, applied in the field of light hydrocarbon separation, can solve the problems of large equipment investment and high operating costs, and achieve the effects of low operating costs, improving recovery rate, and saving equipment investment and operating costs.

Active Publication Date: 2014-03-12
CHINA TIANCHEN ENG +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0013] The main purpose of the present invention is to overcome the problems of large equipment investment and high operating costs in the light hydrocarbon separation method in the methanol-to-olefins unit in the prior art, and provide a light hydrocarbon separation method in the methanol-to-olefins unit by optimizing the existing process flow. Separation method, which can effectively improve the recovery rate of ethylene and propylene

Method used

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  • Light hydrocarbon separation method used in methanol to olefin device
  • Light hydrocarbon separation method used in methanol to olefin device
  • Light hydrocarbon separation method used in methanol to olefin device

Examples

Experimental program
Comparison scheme
Effect test

specific Embodiment 1

[0073] The operating pressure at the top and bottom of the demethanizer and the operating temperature at the top and bottom of the tower are shown in the table below:

[0074] project

Embodiment 1

[0075] The flow process simulation calculation result of embodiment 1 sees the following table:

[0076]

[0077]

[0078] From the above results, it can be seen that if the operating parameters of the demethanizer are set according to the data in the table, the temperature of the demethanizer tower is 15°C, which can match a variety of low-grade heat sources and realize the comprehensive utilization of energy. At the same time, control the C3 mixture absorption liquid, propane absorption liquid and ethane absorption liquid according to the flow rate in the above table, that is, the flow rate of propane absorption liquid is 170kg / h, the temperature is -50℃, and the flow rate of ethane absorption liquid is 730kg / h , the temperature is -50°C, the flow rate of the absorbed carbon three liquid is 30000kg / h, and the temperature is -38°C, the ethylene concentration in the gas phase at the top of the demethanizer can be controlled below 300ppm, and the propylene concentration ca...

Embodiment 2

[0079] In embodiment 2, the operating pressure at the top and bottom of the demethanizer and the operating temperature at the top and bottom of the tower are shown in the table below:

[0080] project

unit

Demethanizer top / bottom temperature

-43 / 22

Demethanizer top / bottom pressure

MPaG

2.9 / 3.05

[0081] The flow process simulation calculation result of embodiment 2 sees the following table:

[0082]

[0083]

[0084] From the above results, it can be seen that if the operating parameters of the demethanizer are set according to the data in the table, the temperature of the demethanizer tower is 22°C, which can match a variety of low-grade heat sources and realize the comprehensive utilization of energy. At the same time, control the C3 mixture absorption liquid, propane absorption liquid and ethane absorption liquid according to the flow rate in the above table, that is, the flow rate of propane absorption liquid i...

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Abstract

The invention relates to a light hydrocarbon separation method used in a methanol to olefin device. According to the method, through the optimization for conventional technological processes, the recovery rate of ethylene and propylene can be effectively improved, meanwhile, other absorbents are not introduced, and materials such as ethane, propane and three-carbon mixture in a system are used to absorb; multi-section absrptions, namely, main absorption and auxiliary absorption are arranged, a main absorption liquid is short in circulation in the system, and can effectively reduce the system operation load and reduce the device running cost, the auxiliary absorption circulating process is relatively longer than that of the main absorption, but the circulation amount is small, and the influence on the system load is relatively small. Through the adoption of multi-stage absorption, the separation of gases of methane, hydrogen, nitrogen, oxygen, carbon monoxide, ethane and the like from ethylene, propene and propane can be realized without copious cooling. The loss of ethylene and propene in fuel gas is small, the separating efficiency is high, and fuel gas products with less propane can be obtained, propylene and ethylene products satisfying polymer grade requirements can be manufactured, and, meanwhile, propane products with high purity can be obtained.

Description

technical field [0001] The invention belongs to the field of coal chemical industry, in particular to a method for separating light hydrocarbons in a methanol-to-olefins device. Background technique [0002] In recent years, my country's methanol-to-olefins projects have made considerable progress, and companies such as Shenhua and China Coal have launched large-scale methanol-to-olefins projects. For the methanol-to-olefins project, on the one hand, the reaction device and catalyst system play a decisive role in the selectivity and conversion rate of the reaction; on the other hand, the separation of the light hydrocarbon mixture produced by the reaction is also a key factor affecting the investment in the device and the cost of the product. [0003] For the olefin mixture produced in the methanol-to-olefin project, its components are similar to petroleum cracking gas and refinery dry gas. Therefore, typical separation methods include conventional cryogenic process and oil ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C07C11/04C07C11/06C07C9/08C07C7/00C07C7/11C10L3/00
CPCY02P30/40
Inventor 杨光孔令海李强耿玉侠赵文文裴艳红王兵杨玉兰段天魁刘新伟陈宁
Owner CHINA TIANCHEN ENG
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