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Technology for extracting gold from superfine carbonaceous gold ore containing arsenic sulfide

A technology for fine-grained and gold ore, applied in the field of hydrometallurgy, can solve the problems of difficulty in separating gold leaching rich liquid and leaching slag, low recovery rate of flotation-enriched sulfide ore, loss of dissolved gold in leaching slag, etc. Investment, improve recovery rate, good effect

Inactive Publication Date: 2014-04-23
CHINA NONFERROUS METAL (GUILIN) GEOLOGY & MINING CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, due to problems such as large investment, easy pollution of the environment, and limited market for by-products (sulfuric acid and arsenic oxide), the application of roasting pre-oxidation sulfide ore (or concentrate) technology is greatly restricted; some mining companies use chemical oxidation and biological pre-oxidation. However, if the problem of arsenic is not effectively solved, it will cause potential environmental pollution, and the production cost of the former is relatively high, so it is currently unsustainable; the existence of high clay not only causes flotation The recovery rate of enriched sulfide ore (or gold) is low, and the solid-liquid separation of the cyanidation gold leaching slurry is very difficult, and part of the dissolved gold is lost in the leaching residue, resulting in difficulties in the separation of the gold-rich solution and the leaching residue.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] In the primary ore sample of fine-grained carbonaceous arsenic-containing gold sulfide ore used in this embodiment, the gold content is 3.0 g / t, sulfur 6.20%, arsenic 0.5%, and carbon 1.40%. First, the ore sample is crushed to -200 mesh 100%, and then direct cyanidation gold leaching and gold extraction are carried out by the method of the present invention respectively.

[0030] Direct cyanidation gold leaching of primary sulfide ores: Slurry with water, add lime milk to adjust the pH value and stabilize it at pH ~ 11.0, add sodium cyanide for leaching, the initial concentration of sodium cyanide is 4.0 g / L, and the leaching solid-liquid ratio is 1:3. The leaching rate of gold was only 1.40% by using roller bottle technology for leaching for 24 hours. The results of the leaching test show that the ore sample is very difficult to leach, mainly due to the physical wrapping of the gold particles by the sulfide and the "gold-robbing" nature of the carbonaceous material. ...

Embodiment 2

[0034] In the primary ore sample of fine-grained carbonaceous arsenic-containing gold sulfide ore used in this embodiment, the gold content is 3.0 g / t, sulfur 6.20%, arsenic 0.5%, and carbon 1.40%. First, the ore sample is crushed to -200 mesh 100%, and then direct cyanidation gold leaching and gold extraction are carried out by the method of the present invention respectively.

[0035] Direct cyanidation gold leaching of primary sulfide ores: Slurry with water, add lime milk to adjust the pH value and stabilize it at pH ~ 11.0, add sodium cyanide for leaching, the initial concentration of sodium cyanide is 4.0 g / L, and the leaching solid-liquid ratio is 1:3. The leaching rate of gold was only 1.40% by using roller bottle technology for leaching for 24 hours. The results of the leaching test show that the ore sample is very difficult to leach, mainly due to the wrapping of the gold particles by the sulfide and the "gold-robbing" nature of the carbonaceous material.

[0036] ...

Embodiment 3

[0039]In the primary ore sample of the fine-grained carbonaceous arsenic-containing gold sulfide ore used in this embodiment, it contains 3.0 g / t of gold, 6.0% of sulfur, 0.5% of arsenic, and 1.40% of carbon. First, the ore sample is crushed to -200 mesh 100%, and then direct cyanidation gold leaching and gold extraction are carried out by the method of the present invention respectively.

[0040] Direct cyanidation gold leaching of primary sulfide ores: Slurry with water, add lime milk to adjust the pH value and stabilize it at pH ~ 11.0, add sodium cyanide for leaching, the initial concentration of sodium cyanide is 4.0 g / L, and the leaching solid-liquid ratio is 1:3.0. The leaching rate of gold was only 1.40% by using roller bottle technology for leaching for 24 hours. The results of the leaching test show that the ore sample is very difficult to leach, mainly due to the wrapping of the gold particles by the sulfide and the "gold-robbing" nature of the carbonaceous materia...

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Abstract

The invention discloses a technology for extracting gold from a superfine carbonaceous gold ore containing arsenic sulfide. The gold extracting method is provided in a way of combining a complex technology. The technology is characterized in that gold losses caused by difficult dressing are avoided through the direct treatment of a primary ore; the primary ore is pretreated by an oxygen pressure technology, the sulfide is oxidized to release gold particles, and convenient carbonitriding leaching is realized; in the process of oxygen pressure oxidation pretreatment, reaction is carried out in a liquid phase, no sulfur dioxide or arsenic oxide escapes, and arsenic elements are trapped in leaching residues, so that environment problems are solved; meanwhile, the gold robbing activity of carbonaceous substances is partially or completely passivated; during carbonitriding gold leaching, the problems that difficult solid-liquid separation is caused by high clay and the like are avoided through the adoption of a CIL (Carbon-in-Leach) technology so as to increase the recovery rate of the gold and overcome environment pollution caused by emission in the gold extracting process.

Description

technical field [0001] The invention belongs to the field of hydrometallurgy, and relates to a process for extracting gold from fine-grained carbon-containing, arsenic-containing, high-clay sulfide gold ores. Background technique [0002] Gold is one of the important precious metals and the first metal discovered and used by human beings. Due to its special physical and chemical properties, gold has long been used as precious jewelry and financial reserves. In modern history, with the development of modern science and technology, gold has also been widely used in electronics, computers, precision instruments, aviation, aerospace and other fields. [0003] With the depletion of easily leachable oxidized gold deposits on the surface, most of the primary gold deposits discovered in recent decades are complex and refractory sulfide deposits. There are many such gold resources in my country, and they are more complex. For example, the fine-grained carbonaceous arsenic-containin...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22B1/00C22B3/24C22B11/00
CPCY02P10/20
Inventor 李尽善周卫宁吕智
Owner CHINA NONFERROUS METAL (GUILIN) GEOLOGY & MINING CO LTD
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