Metal base polyquaternary ammonium salt silica gel coating antibacterial finishing technology

A technology of antibacterial finishing and quaternary ammonium salt, applied in coating, manufacturing tools, fiber treatment, etc., can solve the problems of destroying the main structure of bacteria, difficulty in obtaining durable effects, affecting fabric color and light, etc., and achieves good chemical stability and antibacterial effect Safe and non-toxic, wide-ranging effects

Active Publication Date: 2014-04-23
安徽创宇新材料科技有限公司
View PDF4 Cites 18 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] At present, although the inorganic antibacterial agents widely used in the market have good heat resistance, it is difficult to obtain durable effects when used in textile finishing, and most of them have heavy metal toxicity hazards. At the same time, most of the heavy metals in the metal ions contain bactericidal effects. It is...

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] 1) Take 40% double-capped vinyl silicone oil, 25% dimethyl silicone oil, 15% hydrogen-containing silicone oil, EP-DC57008%, PETA 10%, and nano-silver 2% by weight, and mix them at room temperature with high-efficiency shearing to prepare Obtain antibacterial coated silica gel with a viscosity in the range of 10000cp;

[0025] 2) Scrape the antibacterial coated silica gel prepared in step 1) on the substrate with a coating knife. The speed of the front and rear drive rollers of the coating machine is 5m / min, adjust the angle of the coating knife to 100°, and the coating amount of the coating glue is 10g / min. m 2 ;

[0026] 3) Put the base material coated with antibacterial coating silica gel in step 2) on the transmission beam rack of the 200KeV low-energy electron accelerator through the transmission rollers before and after the coating machine for radiation curing, and the transmission speed of the electron accelerator is 5m / min. Vacuumize the front and rear isolatio...

Embodiment 2

[0028] 1) Take 50% double-capped vinyl silicone oil, 15% dimethyl silicone oil, 15% hydrogen-containing silicone oil, EP-DC57006%, PETA 10%, and nano-silver 4% by weight, and mix them at room temperature with high-efficiency shearing to prepare Obtain antibacterial coated silica gel with viscosity in the range of 20000cp;

[0029] 2) Scrape the antibacterial coated silica gel prepared in step 1) on the substrate with a coating knife. The speed of the front and rear drive rollers of the coating machine is 10m / min, the angle of the coating knife is adjusted to 110°, and the coating amount of the coating glue is 20g / min. m 2 ;

[0030] 3) Put the substrate coated with antibacterial coating silica gel in step 2) on the transmission beam frame of the 200KeV low-energy electron accelerator for radiation curing through the transmission rollers before and after the coating machine, and the transmission speed of the electron accelerator is 10m / min. Vacuumize the front and rear isolat...

Embodiment 3

[0032] 1) Preparation of antibacterial coated silica gel: the weight ratio of each component: double-capped vinyl silicone oil 60%, dimethyl silicone oil 15%, hydrogen silicone oil 10%, EP-DC57008%, PETA 5%, nano silver 2% , high-efficiency shear mixing at room temperature to prepare antibacterial coated silica gel with a viscosity in the range of 30000cp;

[0033] 2) Scrape the antibacterial coated silica gel prepared in step 1) on the substrate with a coating knife. The speed of the front and rear drive rollers of the coating machine is 20m / min, the angle of the coating knife is adjusted to 120°, and the coating amount of the coating glue is 30g / min. m 2 ;

[0034] 3) Put the substrate coated with antibacterial coating silica gel in step 2) on the transmission beam frame of the 200KeV low-energy electron accelerator through the transmission rollers before and after the coating machine for radiation curing, and the transmission speed of the electron accelerator is 20m / min. ...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
Viscosityaaaaaaaaaa
Viscosityaaaaaaaaaa
Viscosityaaaaaaaaaa
Login to view more

Abstract

The invention relates to a metal base polyquaternary ammonium salt silica gel coating antibacterial finishing technology. The technology comprises the following steps: high-efficiently shearing and mixing double terminated vinyl silicone oil, dimethyl silicone oil, silicone oil containing hydrogen, EP-DC5700, PETA, and nano silver at room temperature so as to obtain an antibacterial coating silica gel; painting the prepared antibacterial coating silica gel on a basic material by using a painting knife, wherein the coating amount of the coating layer gel is 10 to 50 g/cm<2>; fixing the basic material coated by the antibacterial coating silica gel on transmission rollers arranged on the front side and rear side of a coating machine, and then placing the basic material in a conveying belt frame of a 200 KeV low-energy electronic accelerator to carry out a radiation curing treatment. An electronic beam radiation curing technology is adopted, and the technology has the advantages of high efficiency, short technological process, and long-lasting effect; the polyquaternary ammonium salt silica gel is well combined with fiber molecules under the radiation; the modified fiber has a long-lasting bacterium killing effect, will not penetrate into the skin and cause adverse effects such as secondary infection, has a good safety property, can effectively inhibits the growth of bacteria, and has good properties of thermal stability, weatherability, ultraviolet resistance, hygroscopicity and softness. The coating material can also be applied to various textures, can be used as a surface coating, and has the advantages of long lasting effect, no toxicity, and no pollution.

Description

technical field [0001] The invention belongs to the technical field of textile post-finishing, and in particular relates to an antibacterial finishing process for metal-based polyquaternium silica gel coating. Background technique [0002] At present, although the inorganic antibacterial agents widely used in the market have good heat resistance, it is difficult to obtain durable effects when used in textile finishing, and most of them have heavy metal toxicity hazards. At the same time, most of the heavy metals in the metal ions contain bactericidal effects. It is Ag>Co>Ni>Al>Zn>Cu=Fe>Mn>Sn>Ba>Mg>Ca. At present, nano-silver ions are widely used as bactericides, which can destroy the main structure of bacteria and inactivate the enzymes for bacterial reproduction; Although some natural antibacterial agents have good safety, they have defects such as narrow application range and affecting the shade of fabrics. [0003] One of the production meth...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
IPC IPC(8): D06M15/643D06M11/83D06M13/513D06M13/224B27K3/52D21H21/36C09D183/07C09D183/04C09D5/14
Inventor 吴海燕张翔夏智贤吴慧周宏烨
Owner 安徽创宇新材料科技有限公司
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products