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PID (Potential Induced Degradation) resisting solar cell module packaging coating and preparation method thereof

A solar cell and encapsulation adhesive film technology, which is applied in the direction of electrical components, circuits, adhesives, etc., can solve the problems of invisible component appearance, component power attenuation, etc., and achieve low component PID phenomenon, good hydrolysis resistance and insulation. Effect

Inactive Publication Date: 2015-06-10
南京红宝丽新材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In the past few decades, the power of components has been greatly attenuated due to system bias, and some attenuation even exceeds 50%, but no defects can be seen from the appearance of components

Method used

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  • PID (Potential Induced Degradation) resisting solar cell module packaging coating and preparation method thereof
  • PID (Potential Induced Degradation) resisting solar cell module packaging coating and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] In terms of parts by mass, 20 parts of EVA resin with a vinyl acetate content of 28% (produced by DuPont, USA, trade name: PV1300z), 0.25 parts of β-(4-hydroxyphenyl-3,5-di-tert-butyl Phenyl) n-octadecanyl propionate, 0.3 parts of maleic anhydride modified low molecular weight 1,2-polybutadiene (produced by Sartomer, USA, trade name: RICON130 (number average molecular weight 2500)) in Density Mix in the mixer, place the mixed material in a twin-screw extruder, control the temperature at 120-140°C, melt and extrude at a speed of 300-350rpm, and the extruded product is pelletized and air-dried to obtain particles; The particles obtained by smelting and granulation are mixed with 80 parts of EVA resin with a vinyl acetate content of 28%, 1.0 part of tert-butyl peroxycarbonate-2-ethylhexyl, and 0.6 part of vinyltriethoxysilane to form a mixed Material; the mixed material is melted through an extruder, extruded from a die into a film, embossed by a pressure roller, cooled an...

Embodiment 2

[0029] In terms of parts by mass, 8 parts of EVA resin with a vinyl acetate content of 28% (produced by DuPont, USA, trade name: PV1300z), 0.1 part of tris(2,4-di-tert-butylphenyl) phosphite, 0.2 parts of maleic anhydride-modified low-molecular-weight 1,2-polybutadiene (produced by Sartomer, USA, trade name: RICON130 (number-average molecular weight 2500)) were mixed in an internal mixer, and the mixed materials were placed in Twin-screw extruder, the temperature is controlled at 120-140°C, melted and extruded at 300-350rpm, the extruded product is pelletized and air-dried to obtain granules; the granules obtained by mixing and granulating are mixed with 92 parts of vinyl acetate EVA resin with a content of 28%, 1.25 parts of 1,1-(diperoxytert-butyl)-3,3,5-trimethylcyclohexane, and 0.4 parts of vinyltriacetoxysilane are mixed to make a mixture Material; the mixed material is melted through an extruder, extruded from a die into a film, embossed by a pressure roller, cooled and ...

Embodiment 3

[0031] In terms of parts by mass, 30 parts of EVA resin with a vinyl acetate content of 28% (produced by DuPont, USA, trade name: PV1300z), 0.1 part of tetrakis[β-(3,5-di-tert-butyl-4-hydroxy Phenyl) propionic acid] pentaerythritol ester, 0.2 parts of polyisoprene (produced by Puyang Linshi New Chemical Materials Co., Ltd., trade name: IR-550 (number average molecular weight 4700)) are mixed in an internal mixer, and the mixed The good material is placed in a twin-screw extruder, the temperature is controlled at 120-140°C, and it is melted and extruded at a speed of 300-350rpm. The extruded product is pelletized and air-dried to obtain particles; 70 parts of EVA resin with a vinyl acetate content of 28%, 1.1 parts of tert-butyl peroxycarbonate-2-ethylhexyl, and 0.6 parts of vinyl triethoxysilane are mixed to make a mixture; the mixture is passed through extrusion It is melted out of the machine, extruded into a film form from the die, embossed by pressing rollers, cooled and s...

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Abstract

The invention provides a PID (Potential Induced Degradation) resisting solar cell module packaging coating and a preparation method thereof. The PID resisting solar cell module packaging coating comprise the following components in parts by weight: 100 parts of vinyl-vinyl acetate resin, 0.4-2.0 parts of a peroxide crosslinking agent, 0.1-1.5 parts of a tackifier, and 0.01-1.0 part of an antioxidant and 0.05-1.0 part of a modifier, wherein vinyl acetate accounts for 20-40% of vinyl-vinyl acetate resin. The solar cell module packaging coating provided by the invention has good hydrolysis resistance and insulativity, and the PID phenomena of the module can be effectively reduced, so that the solar cell module packaging coating fully satisfies the demand of the solar cell module packaging material.

Description

technical field [0001] The invention relates to an anti-PID solar battery component encapsulation adhesive film and a preparation method thereof. Background technique [0002] As a kind of renewable green energy, solar energy has gradually developed rapidly all over the world. Solar photovoltaic power generation is a technology that uses the photovoltaic effect of the semiconductor interface to directly convert light energy into electrical energy. After the solar cells are connected in series, they are protected by glass, packaging materials and backplanes. Encapsulate to form a large-area photovoltaic module. [0003] PID (Potential induced degradation) was first discovered by Sunpower in 2005. The long-term high voltage of the component causes leakage current between the glass and the packaging material, and a large amount of charge accumulates on the surface of the cell, which deteriorates the passivation effect of the cell surface, resulting in the fill factor FF, shor...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09J7/00C09J123/08C09J11/08H01L31/049
CPCY02E10/50
Inventor 祝丽娟周徐李平张蒙蒙
Owner 南京红宝丽新材料有限公司