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A kind of preparation method of primer for addition type silicone potting glue

A technology of silicone potting glue and primer, applied in adhesives, coatings and other directions, can solve the problems of unsuitable porous surface, affecting reliability, reducing sealing and caulking effect, etc., to achieve excellent chemical stability, easy to use. Industrial production, excellent viscosity increasing effect

Inactive Publication Date: 2017-01-11
GAINIA SHANGHAI PATENT TECH LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] In the past, LEDs still had the problems of poor heat dissipation and low light output rate, because heat dissipation directly affects the reliability of LEDs, and then affects their life and applications, and the low light output rate directly limits the development of LEDs. Existing technologies exist The light extraction efficiency is low, generally only up to 92%, even better than 95%, and the light cannot be refracted from the potting material on the surface of the device, so that the light loss during refraction is too large, more than 8%
[0005] The purpose of using potting glue is to have the function of sealing and caulking, but often when the potting glue is used for caulking, the surface energy of the potting glue is low due to the curing reaction, and the adhesion to the substrate is very poor, and Often the resin will shrink after curing. When the adhesion between the potting compound and the substrate is improved by adding a tackifier, it will lead to poor sealing and caulking effects, or insufficient strength to make a slight touch Touching the seal will cause it to fall off; or with long-term exposure to the external environment, dust will accumulate and penetrate into the potting compound, resulting in reduced sealing and caulking effects; moreover, prolonged exposure to moisture Under the environment or light irradiation, the potting compound will turn yellow and the effect of sealing and caulking will be reduced.
[0006] In addition, there are many restrictions on the use of general potting adhesives, for example: usually no additional treatment, such as painting to maintain the appearance of the exterior, is not suitable for long-term immersion in water or underground applications, when curing reaction Requires moisture to cure, not suitable for applications where abrasion and physical damage would damage the sealant, or for substrates with porous surfaces

Method used

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  • A kind of preparation method of primer for addition type silicone potting glue
  • A kind of preparation method of primer for addition type silicone potting glue
  • A kind of preparation method of primer for addition type silicone potting glue

Examples

Experimental program
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Effect test

Embodiment 1

[0061] Embodiment 1: This embodiment provides a primer for addition-type silicone potting adhesive, and its production method includes the following steps:

[0062] (1) Preparation of primer:

[0063] The primer can be mainly composed of four components, including the first to fourth components. Preferably, the first component is methylvinyl dichlorosilane (dichloro(methyl)(vinyl)silane), and the second component is The second component is methylphenyldichlorosilane, the third component is phenyltrichlorosilane, and the fourth component is hydrogen-rich containing siloxane. The production method is as follows :

[0064] Mix 17g of methylvinyldichlorosilane, 0.3094g of methylphenyldichlorosilane, 51.67g of phenyltrichlorosilane and 69g of xylene evenly. Then, 100 g of water and 150 g of xylene were added into a 250 ml four-necked flask, and the temperature was raised to 50° C. The mixed solution of the monomers was added dropwise to the four-neck flask at a uniform speed, an...

Embodiment 2

[0072] Embodiment 2: This embodiment provides a primer for addition-type silicone potting glue, and its production method includes the following steps:

[0073] (1) Preparation of primer:

[0074] In this example, except that the hydrogen content of the added high hydrogen-containing silicone oil is different from that of Example 1, the steps and conditions of the production method for preparing the primer are the same. The difference is that 3.51g of high hydrogen-containing silicone oil (hydrogen content 0.5-0.9%, viscosity 20-200mPa.s) is added in this example, wherein the ratio of silicon hydrogen group to silicon vinyl group content is 0.4-0.72.

[0075] The prepared primer is transparent, has a refractive index of 1.46-1.50, and a light transmittance of 96-99%.

[0076] (2) Preparation of silicone potting compound:

[0077] The steps and conditions of the production method for preparing the encapsulant in this example are the same as those in Example 1.

[0078] (3) A...

Embodiment 3

[0081] Embodiment 3: the present embodiment provides a kind of primer for addition type silicone potting glue, and its production method comprises the following steps:

[0082] (1) Preparation of primer:

[0083] In this example, except that the hydrogen content of the added high hydrogen-containing silicone oil is different from that of Example 1, the steps and conditions of the production method for preparing the primer are the same. The difference is that 3.51g of high hydrogen-containing silicone oil (hydrogen content 0.1-0.4%, viscosity 20-200mPa.s) is added in this embodiment, wherein the ratio of silicon hydrogen group to silicon vinyl group content is 0.08-0.32.

[0084] The prepared primer is transparent, has a refractive index of 1.46-1.50, and a light transmittance of 96-99%.

[0085] (2) Preparation of silicone potting compound:

[0086] The steps and conditions of the production method for preparing the encapsulant in this example are the same as those in Exampl...

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Abstract

The invention discloses a preparation method of a primer for an addition type organosilicone potting adhesive, which is implemented by coating the primer on the surface of a base material; potting the organosilicone potting adhesive on the base material; reacting hydrosilicofluoric groups in the structure of the primer with silicon vinyl in the addition type liquid silicone rubber so as to form a 'bridge' which closely adheres the organosilicone potting adhesive to the surface of the base material, thereby obtaining an excellent bonding performance.

Description

technical field [0001] The invention belongs to the field of chemical materials, and relates to a filling material for encapsulation, in particular to a primer for addition-type silicone potting glue, a preparation method and application thereof. Background technique [0002] The noun of potting or sealant has played an indispensable role in modern life, and is often seen in, for example: window frames, door frames, wainscoting, trim, skylights, gutters, ventilation holes, bridge filling repairs, In the application of building structure curtain wall and caulking, caulking and sealing of pipes, general potting adhesives usually need to be exposed to air and different temperature environments for a long time, so they need to have functions such as weather resistance, waterproof and water vapor barrier. In the environment of long-term exposure to ultraviolet radiation, additives are added to make it anti-ultraviolet. [0003] Potting adhesives can also be used in LED applicati...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D183/07C09D183/05C09J183/07C09J183/05
Inventor 熊二青
Owner GAINIA SHANGHAI PATENT TECH LTD
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