Antistatic toughened, enhanced and stiffened polybutylece terephthalate (PBT) composite material

A composite material and antistatic technology, applied in the field of PBT composite materials, can solve problems such as unsatisfactory, and achieve the effects of convenient operation, excellent electrical performance, and high flame retardant energy efficiency.

Inactive Publication Date: 2014-05-21
QINGDAO XINZHAN PLASTIC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

PBT modification mainly starts from two aspects. One is to adopt chemical modification methods, that is, to make it have better performance and new functions through chemical methods such as copolymerization, grafting, block, cross-linking or degradation; The physical modification method is used to improve and improve the overall performance of PBT by filling and reinforcing with inorganic materials, blending with other resins, and adding various additives. There are many imperfections

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] A PBT composite material with antistatic toughening, strengthening and rigidity, whose components are proportioned by mass percentage: 60% of PBT, 10% of TPU, 10% of micron calcium carbonate, 4% of HBS-510 antistatic agent, poly 2, 6-dibromophenylene ether 10%, antimony trioxide 5%, stearic acid 0.3%, antioxidant 1076 and antioxidant JC-242 compound 0.2%, polysiloxane 0.5%, of which , The intrinsic viscosity of PBT is 0.85~1.25dl / g, TPU is a thermoplastic polyurethane polymer elastomer, and the average particle size of micron calcium carbonate is between 0.5μm and 10μm.

[0024] Preparation method: (1) Dry PBT at 130°C-140°C for 3-5 hours, control the moisture content below 0.03%, and wait for use; (2) Weigh the micron calcium carbonate and stearic acid according to the weight ratio , put it into an ultrasonic vibration generator or a high-speed mixer with a speed of no less than 3000 rpm, and stir at a temperature of 80°C to 100°C for 20 to 100 minutes, so that the ste...

Embodiment 2

[0026] A PBT composite material with antistatic toughening, strengthening and rigidity, whose components are proportioned by mass percentage: PBT 50%, TPU 15%, micron calcium carbonate 15%, HDC-102 antistatic agent 5%, poly 2, 6-dibromophenylene ether 8%, aluminum hydroxide 4%, calcium stearate 0.5%, antioxidant 1076 and antioxidant JC-242 compound 1%, ethylene bisstearamide 1.5% Among them, the intrinsic viscosity of PBT is 0.85-1.25dl / g, TPU is thermoplastic polyurethane polymer elastomer, and the average particle size of micron calcium carbonate is between 0.5 μm and 10 μm.

[0027] Preparation method: (1) Dry PBT at 130°C-140°C for 3-5 hours, control the moisture content below 0.03%, and wait for use; (2) Weigh the micron calcium carbonate and calcium stearate according to the weight ratio Finally, add it to an ultrasonic oscillator or a high-speed mixer with a speed of not less than 3000 rpm, and stir at a temperature of 80°C to 100°C for 20 to 100 minutes, so that the ca...

Embodiment 3

[0029] A PBT composite material with antistatic toughening, strengthening and rigidity, whose components are proportioned by mass percentage: PBT 70%, TPU 5%, micron calcium carbonate 5%, HBS-510 antistatic agent 4%, poly 2, 10% of 6-dibromophenylene ether, 5% of magnesium hydroxide, 0.1% of silane, 0.3% of the compound of antioxidant 1076 and antioxidant JC-242, 0.6% of TAS-2A, among them, the characteristics of PBT The viscosity is 0.85~1.25dl / g, TPU is thermoplastic polyurethane polymer elastomer, and the average particle size of micron calcium carbonate is between 0.5μm~10μm.

[0030] Preparation method: (1) Dry PBT at 130°C-140°C for 3-5 hours, control the moisture content below 0.03%, and wait for use; (2) Weigh the micron calcium carbonate and silane according to the weight ratio, add In an ultrasonic vibration generator or a high-speed mixer of not less than 3000 rpm, stir at a temperature of 80°C to 100°C for 20 to 100 minutes, so that silane is uniformly coated with ...

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Abstract

The invention discloses an antistatic toughened, enhanced and stiffened polybutylece terephthalate (PBT) composite material, comprising the following components by mass percent: 50-70% of PBT, 5-15% of thermoplastic polyurethane (TPU), 5-15% of micron calcium carbonate, 3-5% of antistatic agent, 8-15% of aggregate-type fire retardant, 3-8% of flame retardant, 0.1-0.5% of surface treating agent, 0.1-1% of antioxidant and 0.2-1.5% of lubricating agent. The antistatic toughened, enhanced and stiffened PBT composite material has the beneficial effects that compared with the prior art, the prepared PBT composite material has the advantages that good tensile strength is kept when the gap impact toughness, the rigidity and the heat resistance can be greatly improved, the PBT composite material has significant toughening, enhancing and stiffening effects, is high in flame retardant efficiency, good in antistatic property, excellent in electric property, low in cost, simple in preparation method, convenient to operate, and easy to achieve industrialization, and can be widely applied to the fields such as electronic electricity, automobile industries, mechanical accessories, architectural structures and the like.

Description

technical field [0001] The invention relates to a polymer material, in particular to a PBT composite material which is antistatic, toughened, reinforced and stiffened. Background technique [0002] Polybutylene terephthalate (PBT) has been widely used in electronic appliances, home appliances, automobile industry, mechanical equipment and other industries due to its excellent heat resistance, fatigue resistance, weather resistance, low friction coefficient and other properties. However, the use of PBT alone has disadvantages such as low heat distortion temperature, easy combustion, shrinkage and warping of parts, poor mechanical properties, especially notched impact strength of products, etc. Therefore, PBT is rarely used alone, and most of them need to be modified before they can be applied. PBT modification mainly starts from two aspects. One is to adopt chemical modification methods, that is, to make it have better performance and new functions through chemical methods s...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L67/02C08L75/04C08L71/12C08K13/06C08K9/06C08K9/04C08K3/26C08K3/22
Inventor 不公告发明人
Owner QINGDAO XINZHAN PLASTIC
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