Composite transfer adhesive for high-brightness reflective fabric and preparation method thereof

A composite adhesive and reflective fabric technology, applied in the direction of adhesives, grafted polymer adhesives, adhesive types, etc., can solve the problems of different properties and troubles of blends, and achieve improved stickiness and good washing resistance , to avoid the impact of product performance

Active Publication Date: 2014-06-25
中节能(达州)新材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This method of physical blending is cumbersome to operate. First, polyacrylate resins with different Tgs must be synthesized. During blending, the performance of the blend may be different due to the inconsistent conversion rate of different batches of monomers.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] A transfer composite adhesive for high-gloss reflective cloth, which is prepared from raw materials comprising the following components, and the weight ratio of each component is:

[0030] Acrylic soft monomer: 60,

[0031] Acrylic hard monomer: 32,

[0032] Acrylic functional monomer: 8,

[0033] Initiator: 1,

[0034] Solvent: 186,

[0035] The acrylate soft monomer is: butyl acrylate, 2-ethylhexyl acrylate and ethyl acrylate, and the weight ratio of the above components can be any value, and the weight ratio used in this implementation is: acrylic acid Butyl: 20, 2-ethylhexyl acrylate: 35, ethyl acrylate: 5,

[0036] The acrylate hard monomer is: methyl methacrylate and vinyl acetate, and the weight ratio of the above components can be any value, and the weight ratio used in this implementation is: methyl methacrylate: 20, Vinyl acetate: 12,

[0037] The acrylate functional monomer is acrylic acid,

[0038] Described initiator is azobisisobutyronitrile,

[00...

Embodiment 2

[0047] A transfer composite adhesive for high-gloss reflective cloth, which is prepared from raw materials comprising the following components, and the weight ratio of each component is:

[0048] Acrylic soft monomer: 70,

[0049] Acrylic hard monomer: 10,

[0050] Acrylic functional monomer: 12,

[0051] Initiator: 0.5,

[0052] Solvent: 190,

[0053] The acrylate soft monomer is: butyl acrylate, 2-ethylhexyl acrylate and ethyl acrylate, and the weight ratio of the above components can be any value, and the weight ratio used in this implementation is: acrylic acid Butyl: 25, 2-ethylhexyl acrylate: 35, ethyl acrylate: 10,

[0054] The acrylate hard monomer is: methyl acrylate,

[0055] Described acrylate functional monomer is hydroxyethyl acrylate, hydroxypropyl acrylate, 2-hydroxyethyl methacrylate, 2-hydroxypropyl methacrylate and maleic acid, and the weight of the above components The ratio can be any value, and the weight ratio adopted in this implementation is: hydr...

Embodiment 3

[0065] A transfer composite adhesive for high-gloss reflective cloth, which is prepared from raw materials comprising the following components, and the weight ratio of each component is:

[0066] Acrylic soft monomer: 50,

[0067] Acrylic hard monomer: 40,

[0068] Acrylic functional monomer: 3,

[0069] Initiator: 0.2,

[0070] Solvent: 180,

[0071] The acrylate soft monomer is: butyl acrylate,

[0072] The acrylate hard monomer is: ethyl methacrylate, n-butyl methacrylate and styrene, and the weight ratio of the above components can be any value, and the weight ratio used in this implementation is: methyl Ethyl acrylate: 20, n-butyl methacrylate: 10, styrene: 10,

[0073] The acrylate functional monomers are acrylic acid, hydroxyethyl acrylate and hydroxypropyl acrylate, and the weight ratio of the above components can be any value, and the weight ratio used in this implementation is: acrylic acid: 1, hydroxyethyl acrylate Esters: 1 and Hydroxypropyl Acrylate: 1.

[...

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PUM

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Abstract

The invention discloses a composite transfer adhesive for a high-brightness reflective fabric. The composite transfer adhesive is prepared from raw materials comprising the following components in parts by weight: 50-70 parts of acrylate soft monomer, 10-40 parts of acrylate hard monomer, 3-12 parts of acrylate functional monomer, 0.2-1 part of initiator and 180-190 parts of solvent. The invention also discloses a preparation method of the composite transfer adhesive. The composite transfer adhesive has the beneficial effects that only low-toxicity ethyl acetate is adopted to serve as a solvent; the composite transfer adhesive for the high-brightness reflective fabric is synthesized by adopting a graft copolymerization method, so that high initial stickness is kept, and the holding power is greatly improved; the rubbing resistance and washing resistance applied to the high-brightness reflective fabric are far higher than those of random copolymer. A method for adding the initiators in batches is adopted, and the influence on the product performance in a traditional dripping mode due to the inconsistent dripping speed is avoided.

Description

technical field [0001] The invention relates to a transfer composite adhesive for high brightness reflective cloth and a preparation method thereof. Background technique [0002] High-gloss reflective fabrics can be widely used in public security, fire protection, transportation, railways, sanitation, coal mines, and personal safety and protective equipment. They are usually composed of three parts: high refractive index glass beads, adhesives, and substrates. Among them, the adhesive is the key basic raw material of the reflective material, and is the adhesive between the glass beads and the substrate, and requires good film-forming properties, softness, washing resistance and wear resistance. [0003] At present, the reflective fabric market mainly uses two systems of adhesives, one is polyacrylate system adhesives, and the other is polyurethane system adhesives. However, according to the use requirements of high-brightness reflective cloth, acrylic adhesives can fully me...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J151/00C08F265/06C08F220/18
Inventor 韩君
Owner 中节能(达州)新材料有限公司
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