A kind of nucleating agent polypropylene high-performance composite additive and preparation method thereof

A technology for compounding additives and nucleating agents, applied in the field of plastic additives, can solve the problems of insufficient rigidity, increase production costs, reduce labor efficiency, etc., and achieve the effects of reducing interface free energy, improving production efficiency, and shortening molding cycle.

Active Publication Date: 2016-08-17
南京淳达科技发展有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, the usual PP additives also have the following main problems: (1) The modification effect is general
There is a difficult technical problem: if the rigidity of PP is increased, the toughness will decrease, and if the toughness is increased, the rigidity will be insufficient. In addition, it is difficult to improve the main technical indicators such as heat resistance and low temperature impact strength simultaneously.
(2) Single function
To change the performance of PP in many ways, it is often necessary to open multiple feeding holes at the same time to add a variety of modifiers with different functions, which not only increases the difficulty of the process, but also increases the hidden dangers of equipment failure, but also increases the production cost and reduces labor efficiency.
(3) More powder
At present, some modifier products are still in powder form. During the production process, they are easy to hang on the wall when storing materials, easy to raise dust when feeding materials, easy to block (bridge) when feeding materials, and large material loss, which not only causes pollution, but also affects the health of workers. , also make the measurement inaccurate, directly affect the product quality

Method used

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  • A kind of nucleating agent polypropylene high-performance composite additive and preparation method thereof
  • A kind of nucleating agent polypropylene high-performance composite additive and preparation method thereof
  • A kind of nucleating agent polypropylene high-performance composite additive and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032]

[0033] (1) Put all the components into the cantilever double-helix cone mixer according to the above weight ratio for premixing and coarse dispersion;

[0034] Cantilever double-helix cone mixer, model: DSH-1.5CD, made of stainless steel, the process operation speed is 40-50 rpm, and the mixing time is 40 minutes. The flow rate output is controlled within the range of 0.2-0.3 tons / hour.

[0035] (2) After premixing and coarse dispersion, put the obtained mixture into a horizontal ball mill for grinding and fine dispersion. Horizontal ball mill model: QM-500, made of stainless steel, the process control speed is 75-85 rpm, the temperature is controlled at 70°C, and the time is 60 minutes.

[0036](3) After refining and dispersing, put the obtained mixture into twin-screw granulation to extrude granulation to further strengthen the dispersion. Granulator model: TE-65, the temperature inside the machine is controlled within the range of 75-85°C, the discharge temper...

Embodiment 2

[0043] formula:

[0044]

[0045] The preparation steps of Example 2 are the same as Example 1, except that the stirring time of Step 1 is increased to 60 minutes, and other control indicators are the same as Example 1.

[0046] Table 3 Contrast table between the main index of the auxiliary agent in Example 2 of the present invention and the inspection achievement index

[0047]

[0048]

[0049] Table 4 The main inspection indicators achieved by the application of the auxiliary agent in Example 2 of the present invention to M30RH resin

[0050]

Embodiment 3

[0052] formula:

[0053]

[0054] The preparation steps of Example 3 are the same as those of Example 1, except that the stirring time of Step 1 is increased to 80 minutes, and other control indicators are the same as those of Example 1.

[0055] Table 5 Contrast table between the main index of the auxiliary agent in Example 3 of the present invention and the inspection achievement index

[0056]

[0057] Table 6 The main inspection indicators achieved by applying the auxiliary agent of Example 3 of the present invention to M30RH resin

[0058]

[0059] .

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PUM

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Abstract

The invention discloses a nucleating agent polypropylene high-performance compound additive which comprises the following components in percentage: 45-55% of nano nucleating agent, 5-10% of fluorine-containing polymer, 20-30% of antioxidant, 2-6% of antibacterial agent, 5-10% of dispersing agent and 3-10% of calcium stearate. The nucleating agent polypropylene high-performance compound additive has the characteristics of multiple functions, safety, environmental-friendliness and high specificity, and a plastic product with the additive has multiple excellent properties.

Description

technical field [0001] The invention belongs to the technical field of plastic additives, and in particular relates to a nucleating agent polypropylene high-performance compound additive and a preparation method thereof. Background technique [0002] There are many defects in the existing plastics. Take the domestic M30RH and K9927 as examples. Although they are strong in rigidity, their toughness is poor, and they are easily damaged when used as the inner tub of a washing machine under high-speed impact; the temperature resistance is not strong, especially under low temperature conditions. The texture is brittle, and it is easy to crack when used as a refrigerator liner; it has no anti-mildew and antibacterial function, and it is easy to infect skin, gastrointestinal and other diseases; it also has high haze and low light transmission rate, which affects the use effect; it is not easy to release the mold during processing, which is serious It will directly damage the proces...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L23/12C08L83/04C08L27/12C08K5/098C08K5/42
CPCC08L23/12C08L2205/03C08L2205/24C08L83/04C08L27/12C08K5/098C08K5/42C08K3/015
Inventor 李英杰彭令才孙秀平徐宝成刘铁民
Owner 南京淳达科技发展有限公司
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