Ultraviolet light polymerized low polymer synthesized by utilizing rosin derivatives and preparation method of polymer

A technology of rosin derivatives and light-curing inks, which is applied in rosin coatings, applications, household appliances, etc., can solve problems such as adhesion, poor emulsification, high production costs, and poor light-curing performance, and achieve broad market prospects and save money. The effect of production costs

Inactive Publication Date: 2014-09-03
HUZHOU YIBANG CHEM PROD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0008] The purpose of the present invention is to solve a kind of rosin derivative material suitable for light-curable ink and coating that exists in the prior art and also has poor light-curing performance, unsatisfactory compatibility with g

Method used

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  • Ultraviolet light polymerized low polymer synthesized by utilizing rosin derivatives and preparation method of polymer

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Embodiment 1

[0048] Adopt split flow uniform distribution feeding reactor of the present invention, wherein stainless steel reactor volume is 1m 3 , the distance between the stirring paddle and the inner wall of the reactor is 20mm, the diameter of the distributor is DN40, and the length of the distributor is 1000mm; the inner diameter of the short tube with the lower opening is DN8, and the length of the short tube is 10mm. In the reactor, add 85 parts of abietic acid, 15 parts of diethylene glycol, add 0.3 parts of catalyst, protect it with nitrogen, heat to 120-125 °C to melt all the abietic acid, keep the pressure at 0.1MPa, and keep warm for 2-2 After 4 hours, cool down to 80-100°C, add 10 parts of acrylic acid dropwise, finish dropping in 30 minutes, keep warm for 3-4hrs; evacuate to -0.07-0.098MPa, cool down to 50°C and discharge.

Embodiment 2

[0050] Adopt split flow uniform distribution feeding reactor of the present invention, wherein stainless steel reactor volume is 1.5m 3 , the distance between the stirring paddle and the inner wall of the reactor is 25mm, the diameter of the distributor is DN50, and the length of the distributor is 1300mm; the inner diameter of the short tube with the lower opening is DN10, and the length of the short tube is 10mm. In the reactor, add 75 parts of abietic acid, 25 parts of dipropylene glycol, add 0.5 parts of catalyst, pass nitrogen protection, heat to 130-140 °C to melt all the abietic acid, keep the pressure at 0.1MPa, keep warm for 2-4hrs, After cooling down to 80-100°C, add 20 parts of acrylic acid dropwise for 30 minutes, keep warm for 3-4 hours; vacuumize to -0.07-0.098MPa, cool down to 50°C and discharge.

Embodiment 3

[0052] Adopt split flow uniform distribution feeding reactor of the present invention, wherein stainless steel reactor volume is 2.5m 3 , the distance between the stirring paddle and the inner wall of the reactor is 35mm, the diameter of the distributor is DN65, and the length of the distributor is 1500mm; the inner diameter of the short tube with the lower opening is DN12, and the length of the short tube is 12mm. In the reactor, add 85 parts of hydrogenated abietic acid, 25 parts of tripropylene glycol, add 0.5 part of catalyst, pass nitrogen protection, heat to 150°C to melt all the abietic acid, keep the pressure at 0.1MPa, keep it warm for 2 to 4 hours, and then Cool down to 80-100°C, add 20 parts of acrylic acid dropwise, finish dropping in 30 minutes, keep warm for 3-4 hours; vacuumize to -0.07-0.098MPa, cool down to 50°C and discharge.

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Abstract

The invention provides a rosin derivative material suitable for photo-cured printing ink and paints and a preparation method of the rosin derivative material. The rosin derivative material contains an esterification chain segment which is prepared by performing esterification on abietic acid resins and polyol in a reactor and an olefine acid ester chain segment which is prepared by continuously performing reaction on a rosin composition having the esterification chain segment and an organic solvent solution of an acrylic acid compound in a reactor. According to the preparation method of the rosin derivative resin, the production cost is reduced, and the final cured film performance test shows that the pencil hardness, the adhesion, the shock resistance and the weather resistance of a coating meet the basic application requirement, so that the rosin derivative resin has wide market prospect in the fields of photo-cured printing ink and paints.

Description

technical field [0001] The invention relates to a rosin acid derivative chemical, in particular to a rosin esterification chemical, and further relates to a UV curable oligomer synthesized by using a rosin derivative and a preparation method thereof. The invention belongs to light-curing materials, and is a rosin derivative resin suitable for light-curing inks and coatings. Background technique [0002] Rosin is a natural product with excellent properties such as insulation, adhesion, emulsification and thickening. It is also a renewable natural resin. It is known as "petroleum growing on trees" and can be widely used in paints, inks, rubber, It is an important industrial raw material in the fields of paper making, food additives and biological products. As human beings are concerned about the depletion of petroleum-based macromolecular monomer raw materials, the modification of resource-rich rosin into free radical polymerizable rosin macromonomer has become a current and ...

Claims

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Application Information

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IPC IPC(8): C09F1/04C09D193/04C09D11/08
Inventor 李玉江冯根荣
Owner HUZHOU YIBANG CHEM PROD
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