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Method for preparing high-purity terephthalic acid from alkali-minimization wastewater residues

A technology for terephthalic acid and alkali reduction wastewater, applied in the separation/purification of carboxylic acid compounds, organic chemistry, etc., can solve the problems of difficult removal of soluble impurities, high production costs, complex processes, etc., and achieve good economic benefits and The effects of social benefits, fast production speed and simple process

Inactive Publication Date: 2014-10-15
陆君
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The principle of this method is simple, but the process is more complicated, the production cost is higher, the energy consumption is higher, and it is difficult to remove soluble impurities

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0034] Weigh 1.0kg of alkali reduction waste water residue (moisture content about 50%), add 3.0kg of tap water at 10-15°C, and manually stir the homogenate for 15 minutes to obtain solid content of 10% to 15%, median particle size 0.2mm suspension.

[0035] The obtained suspension was added to a centrifugal filter with a rotating speed of 1000 rpm, and the centrifugation was started for filtration. After 10 minutes, the filtration was completed, and a filter cake with a water content of 70-75% was obtained. Increase the speed of the centrifuge to 5000 rpm and maintain it for 10 minutes to further reduce the moisture content of the filter cake to 65‐70%.

[0036] Weigh 5.0kg of tap water at 10-15°C and pour it into the filter chamber of a centrifugal filter. The initial speed of the centrifuge is set at 2000 rpm, and the filter cake is washed by centrifugal filtration; after the washing water is basically exhausted, , increase the rotating speed to 5000 r / min, keep it for 20...

Embodiment 2

[0041]Weigh 1.0kg of alkali reduction wastewater residue (moisture content about 50%), add about 5.0kg of tap water at 15-20°C, and use a stirring paddle to stir the slurry at a stirring speed of 1500 rpm for 20 minutes to obtain the solid content 5% to 10% suspension with a median particle size of 0.2mm.

[0042] The obtained suspension was added to a centrifugal filter with a rotating speed of 1000 rpm, and the centrifugation was started for filtration. After 10 minutes, the filtration was completed, and a filter cake with a water content of 70-75% was obtained. Increase the speed of the centrifuge to 5000 rpm and maintain it for 10 minutes to further reduce the moisture content of the filter cake to 65‐70%.

[0043] Weigh 5.0kg of tap water at 15-20°C and pour it into the filter cavity of a centrifugal filter. The initial speed of the centrifuge is set at 2000 rpm, and the filter cake is washed by centrifugal filtration; after the washing water is basically exhausted, , i...

Embodiment 3

[0047] Weigh 1.0kg of alkali-reduced wastewater residue (moisture content about 50%), add about 10.0kg of tap water at 20-25°C, and use a stirring paddle to stir the slurry at a stirring speed of 1500 rpm for 25 minutes to obtain the solid content 2.5% to 5% suspension with a median particle size of 0.2 mm.

[0048] The obtained suspension was added to a centrifugal filter with a rotating speed of 1000 rpm, and the centrifugation was started for filtration. After 10 minutes, the filtration was completed, and a filter cake with a water content of 70-75% was obtained. Increase the speed of the centrifuge to 5000 rpm and maintain it for 10 minutes to further reduce the moisture content of the filter cake to 65‐70%.

[0049] Weigh 5.0kg of tap water at 20-25°C and pour it into the filter chamber of a centrifugal filter. The initial speed of the centrifuge is set at 2000 rpm, and the filter cake is washed by centrifugal filtration; after the washing water is basically exhausted, ...

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Abstract

The invention relates to a method for preparing high-purity terephthalic acid from alkali-minimization wastewater residues, and belongs to the technical filed of waste use in the chemical fiber industry. The alkali-minimization wastewater residues dispersed in water again is subjected to solid-liquid separation by a centrifugal filter or a filter press, and an obtained filter cake is washed by an appropriate amount of washing water; the process is repeated, and a terephthalic acid filter cake with remarkably reduced impurity content is finally obtained; and the obtained solid is dried and smashed to obtain the high-purity terephthalic acid product. According to the method, impurities excluding terephthalic acid in the alkali-minimization wastewater residues can be effectively removed, the recovery rate of terephthalic acid is high, the production speed is high, the process is simple, small sewage is produced, energy consumption is small, and the alkali-minimization wastewater residues are economically and effectively recycled.

Description

technical field [0001] The invention relates to a method for preparing high-purity terephthalic acid from alkali-reduction waste water residue, and belongs to the technical field of waste utilization in the chemical fiber industry. Background technique [0002] Terephthalic acid is the organic acid with the largest annual output in the world. It is the raw material of polyester (polyethylene terephthalate) and is widely used in the textile and garment industry. In today's technology, the main source of terephthalic acid is the catalytic oxidation of petrochemical product PX, which consumes a large amount of petrochemical raw materials, and is limited by resources and environmental protection due to the hidden danger of environmental pollution of the PX project. [0003] In the textile printing and dyeing process, the alkaline reduction method wastewater contains a large amount of terephthalic acid. The waste water residue obtained by the acidification precipitation method i...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C07C51/42C07C63/26
CPCC07C51/42C07C63/26
Inventor 陆君陆月来
Owner 陆君