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A chlorine-free mercerizing method for wool carpets based on the combined action of protease and mechanical force

A combined action, protease technology, used in textiles and papermaking, biochemical fiber treatment, dry cleaning fiber products, etc., can solve the problems of uneven wool weight reduction, difficult protease hydrolysis, and difficult to control the processing process, so as to achieve a soft feel to the carpet. Smooth, more tactile carpet, soft gloss effect

Active Publication Date: 2016-04-20
BINZHOU COC CARPET
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The hydrolysis of the fiber by enzyme molecules first starts through the intercellular adhesion in the cell membrane complex (CMC) that runs through the entire fiber and extends to the surface, and then gradually diffuses and acts along the CMC to the inside of the fiber, thus causing the protease The weight reduction effect on wool is uneven and mainly occurs inside the wool fiber, rather than from the outside to the inside as expected, so relying solely on the hydrolysis of proteases may lead to severe degradation of the inside of the wool fiber, while the wool scales are still quite As a result, it is difficult to control the process of protease treatment on wool, and technical problems such as internal fiber damage and serious decline in strength are prone to occur, which also limits the application of protease reduction treatment in wool mercerizing process
At the same time, the inhomogeneity in the process of protease reduction treatment of wool and the difficulty in controlling the degree of protease hydrolysis are also an unresolved technical problem in the industrial application of protease reduction treatment in wool carpet treatment.

Method used

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  • A chlorine-free mercerizing method for wool carpets based on the combined action of protease and mechanical force
  • A chlorine-free mercerizing method for wool carpets based on the combined action of protease and mechanical force
  • A chlorine-free mercerizing method for wool carpets based on the combined action of protease and mechanical force

Examples

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Comparison scheme
Effect test

Embodiment 1

[0022] Example 1: Chlorine-free mercerizing finishing of wool carpets combined with protease and external mechanical force

[0023] 1. Chlorine-free mercerizing finishing of wool carpets combined with protease and mechanical force

[0024] Fabric Type: Pure Wool Rug

[0025] (1) Cleaning of fabrics: The net wool energy is 3% (o.w.f), at a bath ratio of 1:30, at a temperature of 35°C, soak the fabric for 1 hour, then rinse with clean water once, and dehydrate for use.

[0026] (2) Protease treatment under alkaline conditions: use 2% (o.w.f) Savinase16L protease in an aqueous solution at a temperature of 55°C, pH 8.0, and a bath ratio of 1:30 for 30 minutes.

[0027] (3) Protease treatment under neutral conditions: immerse 2% (o.w.f) papain in an aqueous solution at a temperature of 55°C, pH 7.0, and a bath ratio of 1:30 for 30 minutes.

[0028] (4) Physical peeling of scales by scraper: After the wool carpet is treated with protease, it is still in the protease treatment solu...

Embodiment 2

[0049] Embodiment 2 has the wool carpet mercerizing finishing of the protease of pretreatment and the combined effect of external mechanical force

[0050] Fabric type: pure wool carpet

[0051] (1) Cleaning of fabrics: Maonengjing A is 3% (o.w.f), at a bath ratio of 1:30, at a temperature of 35°C, soak the fabric for 1 hour, rinse with clean water once, and dehydrate for later use.

[0052] (2) Oxidative pretreatment of hydrogen peroxide: the wool sample was pre-soaked in hot water at 90°C, and then mixed with 30%H of 3g / L under the conditions of pH 8.0, temperature 50°C, and bath ratio 1:30. 2 o 2 The solution was treated for 1 hour.

[0053] (3) Reduction pretreatment of sodium bisulfite: soak the fabric in a solution containing 15% (o.w.f) NaHSO at a bath ratio of 1:30 and a temperature of 40°C 3 and 3% (o.w.f) Na 2 CO 3 In aqueous solution, the treatment time is 40min, and then dehydration.

[0054] (4) Protease treatment: Under the conditions of temperature 50°C, p...

Embodiment 3

[0069] Embodiment 3 The mercerizing finishing of wool carpets combined with protease and mechanical external force

[0070] Fabric type: pure wool carpet

[0071] (1) Washing of fabrics: Maonengjing A is 5% (o.w.f), at a bath ratio of 1:30, at a temperature of 50°C, soak the fabric for 1 hour, rinse with clean water once, and dehydrate for use.

[0072] (2) Oxidative pretreatment of hydrogen peroxide: Under the conditions of pH 8.5, temperature 60°C, and liquor ratio 1:50, the fabric was soaked in 30% H2O containing 5g / L 2 o 2 and 1.5g / L Na 2 SiO 3 9H 2 O aqueous solution, treatment 45min.

[0073] (3) Mixed protease treatment: Treat the fabric with an aqueous solution containing 1% (o.w.f) Savinase 16L protease and 1% (o.w.f) Esperase 8.0L protease at a temperature of 55°C, pH 8.0, and bath ratio 1:50 for 30 minutes.

[0074] (4) The mechanical force of the scraper: After the wool carpet is treated with protease, it is still in the protease treatment solution to scrape ...

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Abstract

The invention relates to a chloride-free mercerizing method for wool carpets based on the joint action of biological enzymes and mechanical forces, which is characterized by comprising the processes of cleaning a wool carpet, carrying out protease treatment on the wool carpet, mechanically stripping scales, and carrying out protease inactivation and water washing; for improving the efficiency of hydrolyzing wool fibers by protease, an oxidation or reduction pretreatment process can be added before the process of protease treatment; and for endowing a finished wool carpet with a soft and smooth handfeel, a soft finish process is added after the process of carrying out protease inactivation and water washing on the wool carpet. The mercerizing method is based on the joint action of the reduction treatment of protease and external mechanical forces, through moderately stripping wool scales, a purpose of carrying out mercerized finish on wool fabrics is achieved, and excessive damages on wools just caused by the chemical action of protease and other chemicals and the pollution to the environment caused by a chlorination process are reduced.

Description

technical field [0001] The invention relates to the technical field of wool carpet mercerizing, in particular to a chlorine-free mercerizing method for wool carpets based on the joint action of protease and mechanical force. Background technique [0002] Compared with carpets made of other fibers, wool carpets have a luxurious appearance, fluffy texture, warm and elastic touch, and are a class of high-end indoor textile products. However, the structure of wool fiber is special, and there is a scale layer on the surface, which leads to the common disadvantages of wool textile products such as washing shrinkage, itching when wearing, and difficulty in dyeing. For wool carpets, if the wool fiber scales can be properly removed, the morphological stability of the carpet will increase during use due to the decrease in the fineness of the wool fibers and the decrease in the surface friction coefficient of the fibers, and the carpet will feel softer and smoother. , the luster is so...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D06M16/00D06M15/53D06M15/643D06M11/50D06M11/79D06M11/54D06L1/12D06M101/12
Inventor 朱若英韩洪亮崔旗王书东董卫国刘以海崔鹏翔李祥林王召民张秀娟张立平
Owner BINZHOU COC CARPET