Producing method for preparing ammonium dihydrogen phosphate byproduct as special fertilizer for white gourd
A technology of ammonium dihydrogen phosphate and production method, applied in the directions of phosphate, phosphorus oxyacid, application, etc., can solve the problems of low purity of ammonium dihydrogen phosphate and unavailability of effective components, and achieve the effect of increasing element content
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Embodiment 1
[0060] This embodiment provides a kind of production method for preparing ammonium dihydrogen phosphate by-product wax gourd special fertilizer, it is characterized in that comprising the following steps:
[0061] (1) Phosphoric acid and carbonamide prepared by wet-process phosphoric acid are mixed according to the molar ratio of 1.6:1, and the temperature is raised from 90°C to 160°C at a heating rate of 8°C / min, stirred for 4 hours, and the intermediate is separated;
[0062] (2) Then dissolve the intermediate in the phosphoric acid solution, the concentration of the phosphoric acid solution is 17%, adjust the pH of the solution at 3.5, feed ammonia gas into the solution, the ammonia gas and the intermediate are in a molar ratio of 1.1:1, stir React for 3 hours. After the reaction is over, the obtained slurry is placed in a cooling crystallizer to cool down to 25 ° C, and crystallization and filtration are carried out. The filtrate is circulated and crystallized in the coolin...
Embodiment 2
[0068] This embodiment provides a kind of production method for preparing ammonium dihydrogen phosphate by-product wax gourd special fertilizer, it is characterized in that comprising the following steps:
[0069] (1) Phosphoric acid and carbonamide prepared by wet-process phosphoric acid were mixed according to the molar ratio of 1.1:1, and the temperature was raised from 90°C to 160°C at a heating rate of 5°C / min, stirred and reacted for 5 hours, and the intermediate was isolated;
[0070] (2) Then dissolve the intermediate in the phosphoric acid solution, the concentration of the phosphoric acid solution is 20%, adjust the pH of the solution at 3, feed ammonia gas into the solution, the ammonia gas and the intermediate are in a molar ratio of 1.4:1, stir React for 2 hours. After the reaction is over, the obtained slurry is placed in a cooling crystallizer to cool down to 30°C, and crystallization and filtration are carried out. The filtrate is circulated and crystallized in ...
Embodiment 3
[0076] This embodiment provides a kind of production method for preparing ammonium dihydrogen phosphate by-product wax gourd special fertilizer, it is characterized in that comprising the following steps:
[0077] (1) Phosphoric acid and carbonamide prepared by wet-process phosphoric acid are mixed according to the molar ratio of 1.4:1, and the temperature is raised from 90°C to 160°C at a heating rate of 6°C / min, stirred and reacted for 4.5h, and the intermediate is separated;
[0078] (2) Then dissolve the intermediate in the phosphoric acid solution, the concentration of the phosphoric acid solution is 18%, adjust the pH of the solution at 3.2, feed ammonia gas into the solution, the ammonia gas and the intermediate are in a molar ratio of 1.3:1, stir React for 2.5 hours. After the reaction is over, obtain the slurry, and place the slurry in a cooling crystallizer to cool down to 27°C, perform crystallization and filtration treatment, and circulate the filtrate in the cooli...
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