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Macromolecular polymerized phenol modified polydicyclopentadiene material and preparation method thereof

A technology for polydicyclopentadiene and dicyclopentadiene is applied in the field of preparation of macromolecular polymerized phenol modified polydicyclopentadiene materials, which can solve problems such as inability to meet the requirements of use, and achieve high production efficiency and convenient operation. , the effect of good compatibility

Active Publication Date: 2015-01-21
长春三友智造科技发展有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Some application fields require polydicyclopentadiene not only to have high impact strength, but also to have good aging resistance. However, the existing polydicyclopentadiene materials cannot meet the requirements of use.

Method used

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  • Macromolecular polymerized phenol modified polydicyclopentadiene material and preparation method thereof
  • Macromolecular polymerized phenol modified polydicyclopentadiene material and preparation method thereof
  • Macromolecular polymerized phenol modified polydicyclopentadiene material and preparation method thereof

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Experimental program
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Embodiment 1

[0024] The macromolecule polymerized phenol modified polydicyclopentadiene material in this embodiment is made of dicyclopentadiene monomer, tungsten phenol complex, monochlorodiethylaluminum and macromolecular polymerized phenol, and is molded by reaction injection process; wherein, the structural formula of the tungsten phenol complex is W(OPhR) 3 Cl 3 , wherein OPhR is a nonylphenoxy group; the molar ratio of the dicyclopentadiene monomer, tungsten phenol complex, and diethylaluminum chloride is 1000:1:15, and the addition amount of the macromolecular polymerized phenol It is 1% of the mass of dicyclopentadiene monomer.

[0025] The macromolecular polymerized phenol is a linear condensation polymer of dicyclopentadiene monomer and p-methylphenol, and its structural formula is:

[0026]

[0027] Described macromolecule polyphenol is prepared by following method:

[0028] In a three-neck flask with stirring, reflux condenser, and thermometer, add toluene (solvent), p-cr...

Embodiment 2

[0032] The macromolecule polymerized phenol-modified polydicyclopentadiene material in this embodiment uses dicyclopentadiene monomer, molybdenum phenol complex, monochlorodiethylaluminum and macromolecular polymerized phenol as raw materials, and is molded by reaction injection Process is made; Wherein, the structural formula of described molybdenum phenol complex is Mo(OPhR) 3 Cl 2 , wherein OPhR is a nonylphenoxy group; the molar ratio of the dicyclopentadiene monomer, molybdenum phenol complex, and diethylaluminum chloride is 1500:1:20, and the addition amount of the macromolecular polymeric phenol It is 4% of the mass of dicyclopentadiene monomer.

[0033] The macromolecular polymerized phenol is a linear condensation polymer of dicyclopentadiene monomer and p-isopropylphenol, and its structural formula is:

[0034]

[0035] Described macromolecule polyphenol is prepared by following method:

[0036] In a three-neck flask with stirring, reflux condenser, and thermom...

Embodiment 3

[0040] The macromolecular polymerized phenol modified polydicyclopentadiene material in this embodiment is made of dicyclopentadiene monomer, tungsten phenol complex, triethylaluminum and macromolecular polymerized phenol through reaction injection molding process. into; wherein, the structural formula of the tungsten phenol complex is W(OPhR) 3 Cl 3 , wherein OPhR is nonylphenoxy; the molar ratio of the dicyclopentadiene monomer, tungsten phenol complex, and triethylaluminum is 1800:1:25, and the addition amount of the macromolecule polymerized phenol is bicyclic 8% of the mass of pentadiene monomer.

[0041] The macromolecular polymerized phenol is a linear condensation polymer of dicyclopentadiene monomer and hexylphenol, and its structural formula is:

[0042]

[0043] Described macromolecule polyphenol is prepared by following method:

[0044] In a three-neck flask with stirring, reflux condenser, and thermometer, add ethylbenzene (solvent), hexylphenol and BF 3 ·E...

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Abstract

The invention discloses a macromolecular polymerized phenol modified polydicyclopentadiene material and a preparation method thereof. The modified polydicyclopentadiene material is prepared by using dicyclopentadiene monomers, a main catalyst, a co-catalyst and macromolecular polymerized phenol as raw materials and through a reaction injection molding process, wherein a molar ratio of the dicyclopentadiene monomers to the main catalyst to the co-catalyst is 1,000-2,000:1:15-30; and the adding amount of the macromolecular polymerized phenol is 1%-10% by mass of the dicyclopentadiene. In the macromolecular polymerized phenol modified polydicyclopentadiene material, the macromolecular polymerized phenol has an anti-oxidant capacity, can generate a condensation cross-linking reaction under the effects of a dicyclopentadiene metathesis polymerization system and a catalyst, forms an interpenetrating polymer network polymer with polydicyclopentadiene, and achieves the objects of strengthening, toughening and anti-aging, so that the modified polydicyclopentadiene material has relatively high strength, toughness and anti-aging performance.

Description

technical field [0001] The invention belongs to the technical field of polydicyclopentadiene materials, in particular to a macromolecular polymerized phenol modified polydicyclopentadiene material, and also relates to a preparation method of a macromolecular polymerized phenol modified polydicyclopentadiene material. Background technique [0002] Polydicyclopentadiene (PDCPD) is a kind of engineering plastic with good comprehensive performance, which is obtained by ring-opening transposition polymerization of dicyclopentadiene (DCPD) monomer in a two-component catalytic system. Polydicyclopentadiene material has a good balance of strength and toughness, and has good dimensional stability, acid and alkali resistance, excellent coating and electrical insulation properties, so it is widely used in civil engineering, communication, machinery, sports equipment and other fields. [0003] Some application fields require polydicyclopentadiene not only to have high impact strength, ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08F283/00C08F232/08C08G61/02B29C45/00
Inventor 张玉清陈国伟刘翠云陆敏
Owner 长春三友智造科技发展有限公司
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