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Active impregnation solution and preparation method thereof

An impregnating solution and active technology, which is applied in the field of active impregnating solution and its preparation, can solve the problems of general supplementary effect, etc., and achieve the effect of high activity recovery rate and good supplementary effect

Inactive Publication Date: 2015-01-28
TIANHE BAODING ENVIRONMENTAL ENG
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] However, the existing active impregnation solution has a general supplementary effect on the active components of the SCR denitration catalyst. For example, the Chinese patent with the publication number CN102059156A discloses a denitration catalyst regeneration solution and a regeneration method thereof. The activity recovery rate of the catalyst after regeneration is 95%- 99%; Another example is that the Chinese patent with publication number CN103816946A discloses a cleaning solution for regenerated SCR denitration catalyst and a method for regenerating SCR denitration catalyst. The denitration efficiency of the catalyst after regeneration is only 63% to 72%.

Method used

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preparation example Construction

[0049] The present invention also provides a kind of preparation method of active dipping solution, comprises the following steps:

[0050]a) mixing a penetration enhancer, an emulsifier, a surfactant and deionized water to obtain a solution A;

[0051] b) Ammonium metavanadate, ammonium paratungstate, ammonium heptamolybdate, and a cosolvent are mixed with the solution A to obtain a solution B; the cosolvent is acetamide;

[0052] c) mixing the solution B with an acid and aging to obtain an active impregnating solution.

[0053] The present invention mixes penetration enhancer, emulsifier, surfactant and deionized water to obtain solution A. In the present invention, the penetration enhancer preferably includes one or more of JFC type fatty alcohol polyoxyethylene ether, JFC-1 type fatty alcohol polyoxyethylene ether and JFC-2 type fatty alcohol polyoxyethylene ether, More preferred is JFC-1 fatty alcohol polyoxyethylene ether. The present invention has no special limitati...

Embodiment 1

[0072] Add 1wt‰ JFC-1 type fatty alcohol polyoxyethylene ether, 1wt‰ TX-10 type alkylphenol polyoxyethylene ether and 0.2wt% AEO type fatty alcohol polyoxyethylene ether into deionized water, stir for 5min until uniform to obtain solution A; add 1wt% ammonium metavanadate, 2wt% ammonium paratungstate, 1.5wt% ammonium heptamolybdate and 1wt% acetamide to solution A, stir for 35 minutes until uniform, and obtain solution B; Add nitric acid to solution B, adjust the pH value to 5, continue to stir for 5 minutes until uniform, and age for 2 hours to obtain an active impregnating solution.

[0073] The present invention carries out the SCR denitrification catalyst regeneration experiment on the obtained active impregnating solution, first takes the honeycomb SCR denitrification catalyst detection block whose denitrification efficiency has dropped from 86% to 30%, uses oil-free compressed air to purge, and then purifies the SCR denitrification catalyst The denitrification catalyst w...

Embodiment 2

[0078] Add 2wt‰ JFC-1 type fatty alcohol polyoxyethylene ether, 2wt‰ TX-10 type alkylphenol polyoxyethylene ether and 0.4wt% AEO type fatty alcohol polyoxyethylene ether into deionized water, stir for 5min Until uniform, solution A is obtained; 2wt% ammonium metavanadate, 4wt% ammonium paratungstate, 3wt% ammonium heptamolybdate and 2wt% acetamide are added to solution A, stirred for 35min until uniform, solution B is obtained; Add nitric acid to solution B, adjust the pH value to 5.5, continue to stir for 8 minutes until uniform, and age for 2 hours to obtain an active impregnation solution.

[0079] The present invention carries out the SCR denitrification catalyst regeneration experiment on the obtained active impregnating solution, first takes the honeycomb SCR denitrification catalyst detection block whose denitrification efficiency has dropped from 86% to 30%, uses oil-free compressed air to purge, and then purifies the SCR denitrification catalyst The denitrification ca...

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Abstract

The invention provides an active impregnation solution and a preparation method thereof. The active impregnation solution is prepared from the following components: 0.1wt%-0.5wt% of a penetration enhancer, 0.1wt%-0.5wt% of an emulsifier, 0.02wt%-0.1wt% of a surfactant, 1wt%-10wt% of a cosolvent, 1wt%-10wt% of ammonium metavanadate, 1wt%-10wt% of ammonium paratungstate, 1wt%-10wt% of ammonium heptamolybdate, and the balance of de-ionized water and acid, wherein the cosolvent is acetamide. The active impregnation solution provided by the invention has a good supplementation effect on active components of an SCR (Selective Catalytic Reduction) denitration catalyst and the activity recovery rate of the supplemented SCR denitration catalyst is high.

Description

technical field [0001] The invention relates to the technical field of catalyst regeneration, and more specifically relates to an active impregnating solution and a preparation method thereof. Background technique [0002] Coal is one of the main energy sources in the world. It accounts for about 70% of China's primary energy consumption, of which 85% is used through combustion. The flue gas produced by coal combustion contains a large amount of nitrogen oxides, which is extremely harmful to the environment. Therefore, my country has strictly controlled the emission standards of nitrogen oxides. [0003] At present, coal-fired power plants generally adopt Selective Catalytic Reduction (hereinafter referred to as SCR) denitrification technology to control the emission of nitrogen oxides. Among them, the catalyst is the core of SCR denitrification technology, and the cost accounts for 30% of the total investment of the denitrification project. 50%, and its performance directly...

Claims

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Application Information

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IPC IPC(8): B01J37/02B01J38/60B01J38/48B01J23/30
Inventor 於承志莫士净闫坤鹏毛昂崔飞飞刘海军李毅王丽娜贾彦奇李庆丰
Owner TIANHE BAODING ENVIRONMENTAL ENG