Active impregnation solution and preparation method thereof
An impregnating solution and active technology, which is applied in the field of active impregnating solution and its preparation, can solve the problems of general supplementary effect, etc., and achieve the effect of high activity recovery rate and good supplementary effect
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[0049] The present invention also provides a kind of preparation method of active dipping solution, comprises the following steps:
[0050]a) mixing a penetration enhancer, an emulsifier, a surfactant and deionized water to obtain a solution A;
[0051] b) Ammonium metavanadate, ammonium paratungstate, ammonium heptamolybdate, and a cosolvent are mixed with the solution A to obtain a solution B; the cosolvent is acetamide;
[0052] c) mixing the solution B with an acid and aging to obtain an active impregnating solution.
[0053] The present invention mixes penetration enhancer, emulsifier, surfactant and deionized water to obtain solution A. In the present invention, the penetration enhancer preferably includes one or more of JFC type fatty alcohol polyoxyethylene ether, JFC-1 type fatty alcohol polyoxyethylene ether and JFC-2 type fatty alcohol polyoxyethylene ether, More preferred is JFC-1 fatty alcohol polyoxyethylene ether. The present invention has no special limitati...
Embodiment 1
[0072] Add 1wt‰ JFC-1 type fatty alcohol polyoxyethylene ether, 1wt‰ TX-10 type alkylphenol polyoxyethylene ether and 0.2wt% AEO type fatty alcohol polyoxyethylene ether into deionized water, stir for 5min until uniform to obtain solution A; add 1wt% ammonium metavanadate, 2wt% ammonium paratungstate, 1.5wt% ammonium heptamolybdate and 1wt% acetamide to solution A, stir for 35 minutes until uniform, and obtain solution B; Add nitric acid to solution B, adjust the pH value to 5, continue to stir for 5 minutes until uniform, and age for 2 hours to obtain an active impregnating solution.
[0073] The present invention carries out the SCR denitrification catalyst regeneration experiment on the obtained active impregnating solution, first takes the honeycomb SCR denitrification catalyst detection block whose denitrification efficiency has dropped from 86% to 30%, uses oil-free compressed air to purge, and then purifies the SCR denitrification catalyst The denitrification catalyst w...
Embodiment 2
[0078] Add 2wt‰ JFC-1 type fatty alcohol polyoxyethylene ether, 2wt‰ TX-10 type alkylphenol polyoxyethylene ether and 0.4wt% AEO type fatty alcohol polyoxyethylene ether into deionized water, stir for 5min Until uniform, solution A is obtained; 2wt% ammonium metavanadate, 4wt% ammonium paratungstate, 3wt% ammonium heptamolybdate and 2wt% acetamide are added to solution A, stirred for 35min until uniform, solution B is obtained; Add nitric acid to solution B, adjust the pH value to 5.5, continue to stir for 8 minutes until uniform, and age for 2 hours to obtain an active impregnation solution.
[0079] The present invention carries out the SCR denitrification catalyst regeneration experiment on the obtained active impregnating solution, first takes the honeycomb SCR denitrification catalyst detection block whose denitrification efficiency has dropped from 86% to 30%, uses oil-free compressed air to purge, and then purifies the SCR denitrification catalyst The denitrification ca...
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