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Aerosil opacifier gradient doping structure

A silicon dioxide and gradient doping technology, which is applied in the field of nano-insulation materials, can solve the problems of high radiation thermal conductivity and solid-phase thermal conductivity, and achieve low thermal conductivity, lower thermal conductivity, and large application range. Effect

Active Publication Date: 2015-02-04
CHANGSHA RONGLAN MACHINERY
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Problems solved by technology

However, due to the low absorption characteristics of aerogels with silica as the main material to high-temperature near-infrared wavelengths, pure silica airgel materials have extremely high radiation thermal conductivity, so it is difficult to make pure silica airgel The material is directly applied for high-temperature thermal protection, so opacifier doping is required to effectively suppress radiative heat transfer
The shading effect and temperature tolerance of different shading materials are different. The optimal doping particle size of the shading agent is closely related to the temperature, and the doping of the shading agent will lead to an increase in the solid-phase thermal conductivity. Therefore, it is urgent to propose a new Silica Airgel Opacifier Doped Structure

Method used

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Embodiment

[0029] The application conditions of thermal insulation materials are: the high temperature end is 1300K, the low temperature end is 300K, and the density of silica aerogel is 100kg / m 3 .

[0030] The silica aerogel is divided into four doped layers, and the average temperature of each layer is 500, 700, 900 and 1100K from low to high. Therefore, two doping materials are used in the direction of temperature increase: carbon black and silicon carbide. The low temperature layer is made of carbon black, and the two middle layers and the high temperature layer are made of silicon carbide. The optimum particle diameter of the doped carbon black at 500K is 2.8μm, and the optimum mass fraction is 43.23%. The optimal particle diameters of doped silicon carbide at 700, 900 and 1200K were 3.4, 2.8 and 2.6 μm, and the optimal mass fractions were 76.49%, 81.24% and 84.73%, respectively.

[0031] figure 2 The doping methods of three silica aerogels were compared. The optimal particle ...

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Abstract

The invention provides an aerosil opacifier gradient doping structure, and is characterized in that a silicon carbide opacifier material with advantages of high density, small particle size, low density and high temperature resistance can be employed at a high temperature segment of the aerogel material; and the carbon black material opacifier with advantages of low concentration and large particle size can be employed at a low temperature segment. Under condition of doping the opacifier, solid phase thermal conductivity of the material is considered, radiation thermal conductivity of the material is greatly reduced, solid phase thermal conductivity of the aerogel material can be increased, the chemical stability of the doped aerogel material can be ensured, effective thermal conductivity of the material can be effectively reached, heat insulation effect of the material can be increased, application requirements of aviation spaceflight, military material and industrial high temperature thermal protection can be satisfied, and the gradient doping structure has strong practicality.

Description

technical field [0001] The invention belongs to the technical field of nano-insulation materials, and in particular relates to a gradient doping structure of a silica aerogel sunscreen. Background technique [0002] With the development of aerospace technology, the speed of the aircraft continues to increase, the flight time also continues to increase, and the requirements for thermal insulation materials are becoming more and more stringent. At this time, radiation heat transfer is dominant, so the use of nanotechnology to design and develop aerogel composites with high temperature resistance and low radiation thermal conductivity has become the focus of high temperature thermal protection in aerospace. Silica aerogel is a super insulating material with nanoporous structure. Silica aerogel has extremely low density and extremely high porosity. Its staggered nanoporous network structure can effectively inhibit thermal conduction and thermal convection. It has a thermal cond...

Claims

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Application Information

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IPC IPC(8): C04B30/00
Inventor 唐桂华杜慕赵越
Owner CHANGSHA RONGLAN MACHINERY
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