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A kind of nickel-molybdenum-aluminum rare earth coating and preparation method thereof

A nickel-molybdenum-aluminum and rare-earth technology, applied in the field of nickel-molybdenum-aluminum rare-earth coating and its preparation, can solve the problems of weak oxidation resistance and corrosion resistance, and achieve the effect of strong oxidation resistance and corrosion resistance.

Inactive Publication Date: 2017-01-18
SHANGHAI INST OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, thermal barrier coatings use nickel coating, nickel molybdenum coating, nickel molybdenum rare earth coating, nickel molybdenum-molybdenum disilicide coating, nickel molybdenum rare earth-molybdenum disilicide coating as the bonding layer, but the above-mentioned bonding layer materials all have oxidation resistance. Corrosion performance is not very strong and other technical problems

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] A nickel-molybdenum-aluminum rare earth coating is composed of four elements: nickel, molybdenum, aluminum and rare earth. Calculated by mass percentage, nickel: molybdenum: aluminum: rare earth is 53.90%: 33.68%: 9.00%: 3.42%.

[0024] The above-mentioned preparation method of a nickel-molybdenum-aluminum rare earth coating specifically comprises the following steps:

[0025] (1) Add 2.9g of nickel salt, 1.4g of molybdenum compound, 342g of aluminum salt, and 0.0978g of rare earth salt into 191g of ionic liquid, stir to dissolve, and obtain nickel salt-molybdenum compound-aluminum salt-rare earth salt-ionic liquid plating solution That is, nickel nitrate-molybdenum pentachloride-aluminum sulfate-cerium nitrate-1-ethyl-3-methyl-imidazolium bromide electroplating solution;

[0026] Wherein the ionic liquid is 1-ethyl-3-methyl-imidazolium bromide;

[0027] Wherein the nickel salt is nickel nitrate;

[0028] The molybdenum compound is molybdenum pentachloride;

[0029] ...

Embodiment 2

[0036] A nickel-molybdenum-aluminum rare earth coating is composed of four elements: nickel, molybdenum, aluminum and rare earth. Calculated by mass percentage, nickel: molybdenum: aluminum: rare earth is 19.47%: 42.83%: 18.50%: 19.20%.

[0037] The above-mentioned preparation method of a nickel-molybdenum-aluminum rare earth coating specifically comprises the following steps:

[0038] (1) Add 78g of nickel salt, 17.6g of molybdenum compound, 160g of aluminum salt, and 2.45g of rare earth salt into 198g of ionic liquid, stir and dissolve to obtain nickel salt-molybdenum compound-aluminum salt-rare earth salt-ionic liquid electroplating solution namely chlorine Nickel-nickel sulfate-ammonium molybdate-aluminum trichloride-lanthanum chloride-1-ethyl-3-methyl-imidazole tetrafluoroboric acid plating solution;

[0039] Wherein the ionic liquid is 1-ethyl-3-methyl-imidazolium tetrafluoroboric acid;

[0040] Wherein nickel salt is the mixture that nickel chloride and nickel sulfate ...

Embodiment 3

[0049] A nickel-molybdenum-aluminum rare earth coating is composed of four elements: nickel, molybdenum, aluminum and rare earth. Calculated by mass percentage, nickel: molybdenum: aluminum: rare earth is 33.86%: 35.12%: 14.5%: 16.52%.

[0050] The above-mentioned preparation method of a nickel-molybdenum-aluminum rare earth coating specifically comprises the following steps:

[0051] (1), 32.4g nickel salt, 10.89g molybdenum compound, 147g aluminum salt, 1.28g rare earth salt in 147g ionic liquid, stir and dissolve to obtain nickel salt-molybdenum compound-aluminum salt-rare earth salt-ionic liquid electroplating solution namely chlorine Nickel-sodium molybdate-aluminum trichloride-samarium chloride-1-ethyl-3-methyl-imidazolium chloride electroplating solution;

[0052] Wherein the ionic liquid is 1-ethyl-3-methyl-imidazolium chloride;

[0053] Wherein the nickel salt is nickel chloride;

[0054] The molybdenum compound is sodium molybdate;

[0055] Aluminum salt is aluminum...

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PUM

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Abstract

The invention discloses Ni-Mo-Al-rare earth coating and a preparation method thereof. The Ni-Mo-Al-rear earth coating comprises four elements including Ni, Mo, Al and rare earth and particularly comprises the following four elements in percentage by mass: 53.90-19.47% of Ni, 33.68-42.83% of Mo, 9.00-18.50% of Al and 3.42-19.20% of rare earth. The preparation method comprises the following steps: firstly adding a nickel salt, a molybdenum compound, an aluminum salt and a rare earth salt into an ionic liquid, and stirring for dissolving to obtain a nickel salt-molybdenum compound-aluminum salt-rare earth salt-ionic liquid electroplating liquid; then, adding a to-be-plated part serving as a negative pole and Ni serving as a positive pole into the electroplating liquid and electroplating at 30-60 DEG C for 10-60min under the conditions that the current density is 10-25A / dm<2> and the rotating speed is 100-600rpm; washing the electroplated part by the end of the electroplating; and drying to finally obtain Ni-Mo-Al-rare earth coating with good oxidation corrosion resistance on the surface of the electroplated part.

Description

technical field [0001] The invention relates to a nickel-molybdenum-aluminum rare earth coating and a preparation method thereof. Background technique [0002] With the development of aero-engines toward high thrust-to-weight ratios, the design inlet temperature of aero-engines continues to increase, and the use of high-temperature structural materials alone cannot meet the urgent requirements of the rapid development of advanced aero-engines. At present, the practical way to greatly increase the operating temperature of aero-engines is to use thermal barrier coating technology. Most of the thermal barrier coatings that have been applied in practice have a double-layer structure, and the ceramic layer is used as the surface layer of the thermal barrier coating because of its heat insulation, corrosion resistance, erosion and erosion properties. Due to the thermal expansion coefficient mismatch between ceramics and high-temperature structural materials, a metal bonding layer...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C25D3/56
CPCC25D3/56C25D5/00
Inventor 刘小珍张骋陈捷
Owner SHANGHAI INST OF TECH