A method for preparing cadmium oxide from zinc smelting cadmium-containing fumes
A cadmium oxide and zinc smelting technology, applied in chemical instruments and methods, cadmium compounds, inorganic chemistry, etc., can solve problems such as difficult separation and complicated process, and achieve the effect of simple equipment, simple process and strong implementability
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Embodiment 1
[0013] Weigh 1 kg of zinc smelting dust, whose composition is shown in Table 1, add sulfuric acid solution with a concentration of 90g / L for leaching, and leaching at 60°C for 1 hour at a liquid-solid ratio of 6:1, the leaching rate of cadmium is 99.6%.
[0014] Table 1 Chemical composition of zinc smelting dust (wt%)
[0015] element Na K Fe Cu Zn As CD Pb content 0.08 0.99 0.02 0.09 0.20 0.05 18.32 42.45
[0016] Add FeCl to the leaching solution 3 , wherein the ratio of the amount of Fe and As is 3:1, then add 5 times the theoretical amount of hydrogen peroxide, adjust the pH to 5 with NaOH, and filter. Add the P204 extraction agent that the mass concentration is 20% in the filtrate, O / A=1, extraction time 15min, separate and obtain raffinate after static stratification, adopt primary extraction, zinc removal rate reaches 96.8%, raffinate Medium Zn 2+ The concentration is 0.5mg / L, Cd 2+ The concentration is 23.83g / L.
[0017] D...
Embodiment 2
[0021] Take 10kg of cadmium-containing fumes, the composition of which is shown in Table 3, add sulfuric acid solution with a concentration of 110g / L for leaching, and leaching at 50°C for 2 hours at a liquid-solid ratio of 5:1, the leaching rate of cadmium is 99.2%.
[0022] Table 3 Main chemical composition of zinc smelting dust (wt%)
[0023] element Na K Fe Cu Zn As CD Pb content 0.07 0.1 0.04 0.09 0.15 0.1 20.35 40.8
[0024] Add FeCl to the leaching solution 3 , wherein the ratio of the amount of Fe and As is 5:1, then add 10 times the theoretical amount of hydrogen peroxide, adjust the pH to 4.5 with NaOH, and filter. Add P204 extractant with a mass concentration of 30% to the filtrate, O / A=1, extraction time 10min, after static layering, separate to obtain a raffinate, the zinc removal rate reaches 96.8%. Dilute the raffinate with water to a cadmium ion concentration of 0.25mol / L, add urea at a concentration of 0.5mol / L, the ...
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