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Nano inorganic material and alkyl glycoside compounded radionuclide decontaminant as well as use method thereof

A nano-inorganic material, radionuclide technology, applied in the directions of radioactive purification, detergent compounding agent, organic washing composition, etc. problems, to achieve good ecological safety and compatibility, rapid and thorough degradation, and easy handling.

Active Publication Date: 2015-03-11
SOUTHWEAT UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the decontamination efficiency of existing foam detergents is low, and the foam after decontamination is difficult to defoam, which has a certain impact on the treatment of nuclides in the subsequent solution, such as evaporation and filtration.
In addition, acid solution can be used to defoam the foam, but the acid solution has a certain corrosive effect on the equipment, and the waste liquid is difficult to handle after decontamination, and the radionuclides in the waste liquid are difficult to separate and enrich

Method used

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  • Nano inorganic material and alkyl glycoside compounded radionuclide decontaminant as well as use method thereof
  • Nano inorganic material and alkyl glycoside compounded radionuclide decontaminant as well as use method thereof
  • Nano inorganic material and alkyl glycoside compounded radionuclide decontaminant as well as use method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0049] Take 0.5 parts by weight of alkyl glycosides with 10 carbon atoms and 0.5 parts by weight of nano-TiO 2 , 5 parts by weight sodium citrate, 1 part by weight sodium carbonate, 5 parts by weight urea, 0.2 parts by weight sodium carboxymethyl cellulose, 0.2 parts by weight sodium dodecylbenzene sulfonate, 0.1 parts by weight sodium polycarboxylate, 1 Parts by weight of NaCl, 0.1 parts by weight of phenol, 0.5 parts by weight of purified konjac glucomannan, and 85.9 parts by weight of water are mixed uniformly to obtain a foam detergent solution.

[0050] Stir the resulting solution at 3000 r / min to obtain a stable foam, spray the foam on the surface of the contaminated paint, let it stand for 5 minutes, and blow the foam into the waste liquid bucket with a blast blowing device for subsequent treatment.

[0051] Put the foam in the waste liquid bucket under the light condition for 2h, the foam disappears, the waste liquid is stirred at 3000r / min without foam generation, and the w...

Embodiment 2

[0053] Take 1 part by weight of alkyl glycoside with 10 carbon atoms and 0.5 part by weight of nano Fe 2 O 3 , 5 parts by weight sodium citrate, 1 part by weight sodium carbonate, 5 parts by weight urea, 0.3 parts by weight sodium carboxymethyl cellulose, 0.2 parts by weight sodium dodecylbenzene sulfonate, 0.4 parts by weight sodium polycarboxylate, 1 Parts by weight of NaCl, 0.1 parts by weight of phenol, 0.5 parts by weight of purified konjac glucomannan, and 85 parts by weight of water are mixed uniformly to obtain a foam detergent solution.

[0054] Stir the resulting solution at 3000 r / min to obtain a stable foam, spray the foam on the surface of the contaminated paint, let it stand for 8 minutes, and blow the foam into the waste liquid bucket with a blast blowing device for subsequent treatment.

[0055] Place the foam in the waste liquid bucket under light conditions for 3 hours, the foam disappears, the waste liquid is stirred at 3000r / min without foam generation, and the w...

Embodiment 3

[0057] Take 1.5 parts by weight of alkyl glycosides with 10 alkyl carbon atoms, 1 part by weight of nano-ZnO, 5 parts by weight of disodium edetate, 3 parts by weight of sodium carbonate, 5 parts by weight of urea, 0.4 parts by weight of carboxymethyl Sodium cellulose, 0.2 parts by weight of sodium dodecylbenzene sulfonate, 0.1 parts by weight of sodium polycarboxylate, 1 part by weight of NH 4 Cl, 0.1 parts by weight of paraben, 0.5 parts by weight of purified konjac glucomannan, and 84.2 parts by weight of water are mixed uniformly to obtain a foam detergent solution.

[0058] Stir the resulting solution at 3000 r / min to obtain a stable foam, spray the foam on the surface of the contaminated paint, let it stand for 5 minutes, and blow the foam into the waste liquid bucket with a blast blowing device for subsequent treatment.

[0059] Put the foam in the waste liquid bucket under the light condition for 5 hours, the foam disappears, the waste liquid is stirred at 3000r / min without ...

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Abstract

The invention discloses a nano inorganic material and alkyl glycoside compounded radionuclide decontaminant as well as a use method thereof. The decontaminant comprises the following components in parts by weight: 0.5-2 parts of an alkyl glycoside surfactant, 0.1-2 parts of a nano inorganic material additive, 1-5 parts of a chelating agent, 1-5 parts of a corrosion inhibitor, 1-5 parts of a solubilizer, 0.1-1 part of a foam stabilizer and 71-94.4 parts of water and further comprises 0.2-1 part of an anionic surfactant, 0.1-0.5 part of a dispersant, 1-5 parts of an inorganic salt electrolyte, 0.1-0.5 part of a preservative and 0.5-2 parts of a thickener. The use method comprises the step of stirring the mixed components in parts by weight at a high speed to obtain the foam decontaminant. By adopting environment-friendly alkyl glycoside as a foaming agent and simultaneously adding the nano inorganic material which is relatively strong in adsorption capacity and flocculating ability, the nano inorganic material is simple in preparation process, good in radionuclide decontamination effect, free of corrosion on solid surfaces, easily degradable under illumination and less in secondary pollution. The nano inorganic material can be used for defoaming and is convenient to defoam.

Description

Technical field [0001] The invention relates to a radionuclide detergent, in particular to a radionuclide detergent obtained by compounding a nano inorganic material and an alkyl glycoside surfactant. Background technique [0002] Nuclear facility decontamination technologies mainly include chemical decontamination, mechanical decontamination, electrochemical decontamination and biological decontamination. The chemical decontamination waste liquid has a large amount, damages the surface of the object, and takes a long time. The mechanical decontamination requires that the surface of the contaminated workpiece can be touched, and it is easy to produce airborne dust. The electrochemical decontamination effect is better than the chemical decontamination method. The corrosion is large, and the biological decontamination speed is slow. [0003] The foam decontamination method has less secondary waste output, and can clean blind holes, crevices and places that are generally difficult to...

Claims

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Application Information

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IPC IPC(8): C11D1/66C11D1/83C11D3/60C11D3/37C11D3/34C11D3/26G21F9/30
Inventor 林晓艳周星保朱高龙罗学刚
Owner SOUTHWEAT UNIV OF SCI & TECH
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