Method for producing tobermorite and aluminum oxide by using coal ash alkaline leaching sintering hydrothermal method

Abstract

The invention discloses a method for producing tobermorite and aluminum oxide by using a coal ash alkaline leaching sintering hydrothermal method. The method comprises the following steps: (1) performing chemical ore separation; (2) producing aluminum oxide through alkaline leaching; (3) preparing raw material slurry; (4) sintering to prepare clinker; (5) dissolving, separating and washing the clinker; (6) preparing tobermorite precursor raw material slurry; (7) performing hydro-thermal synthesis to prepare a tobermorite precursor; (8) performing hydro-thermal synthesis to prepare tobermorite slurry. By adopting the method, the problems and the defects that in the prior art a great deal of limestone is consumed, the energy consumption is large and a great deal of slag is generated are effectively solved, both tobermorite and aluminum oxide can be produced, a silicon mineral resource is saved, a monohydrallite resource is replaced, sources such as soil are also saved, and large-scale economic production is achieved.

Description

technical field [0001] The invention relates to a comprehensive utilization method of fly ash, in particular to a method for producing tobermorite and alumina by a hydrothermal method of alkali leaching and sintering of fly ash. Background technique [0002] Some coal fields in central and western Inner Mongolia and northern Shanxi are rich in high-alumina coal resources, with prospective reserves of nearly 100 billion tons, equivalent to about 15 billion tons of high-alumina fly ash, which is equivalent to the current reserves of bauxite in my country More than 8 times of that, and the alumina content in some fly ash can reach 40~50%. This kind of fly ash is generally called high aluminum fly ash. Fly ash is the main solid waste from the perspective of power generation in power plants, but the alumina content in the high-alumina fly ash produced by the combustion of high-alumina coal can reach 35-45%, some even as high as 50%, and the silicon content is generally 35%. %abov...

AI Technical Summary

Problems solved by technology

However, my country's bauxite resources are quite scarce, and bauxite reserves only account for about 5% of the world's total reserves, and most of them are low-grade diaspore-type bauxite that is difficult to handle. Purchasing restriction policy, bauxite resource problem has become the biggest bottleneck for the sustainable development of my country's alumina and aluminum industry

[0005] Tobermorite and its products are produced by traditional techniques, and its siliceous raw materials are generally produced by using diatomite or quartz sand and alkali under melting conditions to generate industrial water glass. In the preparation process of raw materials, it is necessary to use a large amount of high-quality silicon ore such as quartz sand and diatomaceous earth to co-melt with soda ash or sodium sulfate in a melting kiln, and then cool, pulverize and dissolve to make it; this makes the selection of silicon raw materials require mining and A large amount of non-renewable silicon mineral resources such as quartz and diatomaceous earth are consumed; at the same time, in addition to calcium carbide slag, limestone generally needs to be burned separately with high-quality fuels such as coke or white coal to burn lime and refined lime milk. The production energy consumption and High cost, great impact on resources and environment

Existing various processes for producing aluminum hydroxide or aluminum oxide with high alumina fly ash produce a large amount of silicon-calcium slag or silicon slag, and the large-scale and rational utilization of a large amount of silicon-calcium slag or silicon slag has become a huge bottleneck for various processes

Images