Waterproof acrylic acid adhesive tape and preparation method thereof

Abstract

The invention discloses a waterproof acrylic acid adhesive tape and a preparation method thereof. The waterproof acrylic acid adhesive tape comprises a substrate layer, waterproof acrylic acid adhesive is applied to the substrate layer to form an adhesive layer, and the other surface of the adhesive layer is adhered to a release material layer. The waterproof acrylic acid adhesive tape is prepared from components A in parts by weight, and the components A comprises paraffin, a silane coupling agent, methyl ethyl ketone, isocyanate, methyl methacrylate, ethyl acrylate and dimethyldiethoxylsilane. Due to the formation of a network structure, the distance among latex particles can be shortened greatly, the gaps among latex particles can be narrowed, water molecules can be hereby prevented from entering the acrylic acid adhesive, and the purposes of improving the cohesion and the water resistance of an adhesive film can be achieved. In addition, because paraffin is mixed into a solution by stirring, and paraffin molecules fill in the gaps among latex particles, water molecules can be prevented from entering the acrylic acid adhesive. Moreover, paraffin can form a waterproof protective film on the surface, thus water is prevented from entering the acrylic acid adhesive.

Description

technical field

[0001] The invention relates to the technical field of acrylic tapes, in particular to a waterproof acrylic tape and a manufacturing process thereof. Background technique

[0002] Acrylates are widely used as adhesives because of the strong hydrogen bonding of the ester group, and its types include cyanoacrylate adhesives and reactive acrylic adhesives. Adhesives that use polyacrylate as a single-component or main component are thermoplastic and thermosetting. The single-component adhesive has no solvent, can be cured at room temperature, and has certain transparency. There are mainly a-cyanoacrylate adhesives and acrylic adhesives. Acrylic adhesives are used to stick one object to another. People pay more attention to the visual requirements of various furniture or electronic products such as styles and colors, so the appearance of electronic products is particularly important. This requires higher and higher requirements for adhesive tapes, which often re...

Examples

Embodiment 1

[0038] The waterproof acrylic adhesive tape of the present invention comprises a substrate layer, on which a waterproof acrylic adhesive is coated to form an adhesive layer, and a release material layer is pasted on the other side of the adhesive layer, and the waterproof The acrylic adhesive consists of the following components by weight:

[0039] A component:

[0040] 3 parts paraffin,

[0041] 2 parts of silane coupling agent,

[0042] Butanone 11 parts,

[0043] 2 parts isocyanate,

[0044] 45 parts of methyl methacrylate,

[0045] 40 parts of ethyl acrylate,

[0046] 11 parts of dimethyldiethoxysilane;

[0047] 200 parts of toluene,

[0048] 3 parts resin,

[0049] 2 parts of azo compound,

[0050] Butyl acrylate 20 parts

[0051] Acrylonitrile 11 parts

[0052] Acrylic 9 parts

[0053] Sodium dodecyl sulfonate 2 parts

[0054] Potassium sulfate 2 parts

[0055] 2 parts dodecyl mercaptan

[0056] Ammonia 20 parts

[0057] 20 parts of water

[0058] B comp...

Embodiment 2

[0062] The waterproof acrylic adhesive tape of the present invention comprises a substrate layer, on which a waterproof acrylic adhesive is coated to form an adhesive layer, and a release material layer is pasted on the other side of the adhesive layer, and the waterproof The acrylic adhesive consists of the following components by weight:

[0063] A component:

[0064] 4 parts paraffin,

[0065] 3 parts of silane coupling agent,

[0066] Butanone 12 parts,

[0067] 2.5 parts of isocyanate,

[0068] 47 parts of methyl methacrylate,

[0069] 45 parts of ethyl acrylate,

[0070] 13 parts of dimethyldiethoxysilane;

[0071] 25 parts of toluene,

[0072] 4 parts resin,

[0073] 4 parts of azo compound,

[0074] Butyl acrylate 25 parts

[0075] Acrylonitrile 16 parts

[0076] Acrylic acid 9.5 parts

[0077] Sodium dodecyl sulfate 2.5 parts

[0078] Potassium sulfate 2.5 parts

[0079] 4 parts dodecyl mercaptan

[0080] Ammonia 25 parts

[0081] 30 parts of water

...

Embodiment 3

[0086]The waterproof acrylic adhesive tape of the present invention comprises a substrate layer, on which a waterproof acrylic adhesive is coated to form an adhesive layer, and a release material layer is pasted on the other side of the adhesive layer, and the waterproof The acrylic adhesive consists of the following components by weight:

[0087] A component:

[0088] 6 parts paraffin,

[0089] 5 parts of silane coupling agent,

[0090] Butanone 13 parts,

[0091] 3 parts isocyanate,

[0092] 60 parts of methyl methacrylate,

[0093] 49 parts of ethyl acrylate,

[0094] 15 parts of dimethyldiethoxysilane;

[0095] 30 parts of toluene,

[0096] 5 parts resin,

[0097] 5 parts of azo compounds,

[0098] 30 parts of butyl acrylate

[0099] Acrylonitrile 20 parts

[0100] Acrylic 10 parts

[0101] Sodium dodecyl sulfate 3 parts

[0102] Potassium sulfate 3 parts

[0103] Dodecyl Mercaptan 5 parts

[0104] Ammonia 30 parts

[0105] 40 parts of water

[0106] B com...

technical field

[0001] The invention relates to the technical field of acrylic tapes, in particular to a waterproof acrylic tape and a manufacturing process thereof. Background technique

[0002] Acrylates are widely used as adhesives because of the strong hydrogen bonding of the ester group, and its types include cyanoacrylate adhesives and reactive acrylic adhesives. Adhesives that use polyacrylate as a single-component or main component are thermoplastic and thermosetting. The single-component adhesive has no solvent, can be cured at room temperature, and has certain transparency. There are mainly a-cyanoacrylate adhesives and acrylic adhesives. Acrylic adhesives are used to stick one object to another. People pay more attention to the visual requirements of various furniture or electronic products such as styles and colors, so the appearance of electronic products is particularly important. This requires higher and higher requirements for adhesive tapes, which often re...

Examples

Embodiment 1

[0038] The waterproof acrylic adhesive tape of the present invention comprises a substrate layer, on which a waterproof acrylic adhesive is coated to form an adhesive layer, and a release material layer is pasted on the other side of the adhesive layer, and the waterproof The acrylic adhesive consists of the following components by weight:

[0039] A component:

[0040] 3 parts paraffin,

[0041] 2 parts of silane coupling agent,

[0042] Butanone 11 parts,

[0043] 2 parts isocyanate,

[0044] 45 parts of methyl methacrylate,

[0045] 40 parts of ethyl acrylate,

[0046] 11 parts of dimethyldiethoxysilane;

[0047] 200 parts of toluene,

[0048] 3 parts resin,

[0049] 2 parts of azo compound,

[0050] Butyl acrylate 20 parts

[0051] Acrylonitrile 11 parts

[0052] Acrylic 9 parts

[0053] Sodium dodecyl sulfonate 2 parts

[0054] Potassium sulfate 2 parts

[0055] 2 parts dodecyl mercaptan

[0056] Ammonia 20 parts

[0057] 20 parts of water

[0058] B comp...

Embodiment 2

[0062] The waterproof acrylic adhesive tape of the present invention comprises a substrate layer, on which a waterproof acrylic adhesive is coated to form an adhesive layer, and a release material layer is pasted on the other side of the adhesive layer, and the waterproof The acrylic adhesive consists of the following components by weight:

[0063] A component:

[0064] 4 parts paraffin,

[0065] 3 parts of silane coupling agent,

[0066] Butanone 12 parts,

[0067] 2.5 parts of isocyanate,

[0068] 47 parts of methyl methacrylate,

[0069] 45 parts of ethyl acrylate,

[0070] 13 parts of dimethyldiethoxysilane;

[0071] 25 parts of toluene,

[0072] 4 parts resin,

[0073] 4 parts of azo compound,

[0074] Butyl acrylate 25 parts

[0075] Acrylonitrile 16 parts

[0076] Acrylic acid 9.5 parts

[0077] Sodium dodecyl sulfate 2.5 parts

[0078] Potassium sulfate 2.5 parts

[0079] 4 parts dodecyl mercaptan

[0080] Ammonia 25 parts

[0081] 30 parts of water

...

Embodiment 3

[0086]The waterproof acrylic adhesive tape of the present invention comprises a substrate layer, on which a waterproof acrylic adhesive is coated to form an adhesive layer, and a release material layer is pasted on the other side of the adhesive layer, and the waterproof The acrylic adhesive consists of the following components by weight:

[0087] A component:

[0088] 6 parts paraffin,

[0089] 5 parts of silane coupling agent,

[0090] Butanone 13 parts,

[0091] 3 parts isocyanate,

[0092] 60 parts of methyl methacrylate,

[0093] 49 parts of ethyl acrylate,

[0094] 15 parts of dimethyldiethoxysilane;

[0095] 30 parts of toluene,

[0096] 5 parts resin,

[0097] 5 parts of azo compounds,

[0098] 30 parts of butyl acrylate

[0099] Acrylonitrile 20 parts

[0100] Acrylic 10 parts

[0101] Sodium dodecyl sulfate 3 parts

[0102] Potassium sulfate 3 parts

[0103] Dodecyl Mercaptan 5 parts

[0104] Ammonia 30 parts

[0105] 40 parts of water

[0106] B com...

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