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Preparation method of polyoxymethylene crude fiber for toughening concrete

A technology of polyoxymethylene and polyoxymethylene resin, which is applied in the field of polyoxymethylene fiber preparation, can solve the problems of no fiber preparation and application, single reinforcement method, limited reinforcement effect, etc. Low, reduce indentation processing, increase the effect of roughness

Active Publication Date: 2015-04-08
JIANGSU SOBUTE NEW MATERIALS +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

It can be seen from these patents that adding carbon nanotubes and glass fibers can strengthen POM, but these patents use a single reinforcement method, the reinforcement effect is limited, and there are various components. They are mainly used as engineering plastics and do not involve the preparation of fibers. and applications, not to mention polyoxymethylene crude fibers for concrete toughening

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] Put 1000g of polyoxymethylene resin, 1g of carboxylated carbon nanotubes, 50g of carbon fibers (the length of the fibers is 1-3mm), and 5g of polyvinylpyrrolidone into a high-speed mixer, and raise the temperature of the mixer to 80°C After stirring for 8 minutes, stop stirring, and after the material is cooled, extrude and granulate in the screw extruder to obtain modified POM pellets; melt the modified POM pellets in the twin-screw extruder and extrude them into the Cooling and molding in an ethanol cooling bath at 20°C, the distance between the cooling bath liquid surface and the extrusion die is 2mm, the cooled filaments are introduced into a 95°C water bath for washing to remove water-soluble polymers, and at the same time stretch 3 times, and the washing time is 4s, after being dried in a hot oven at 120°C for 20s, enter a hot oven at 140°C for secondary stretching, with a stretching ratio of 1.5 times, and then heat-set in a hot oven at 158°C for 50s, and finally ...

Embodiment 2

[0030] Put 1000g of polyoxymethylene resin, 15g of carboxylated nanocellulose whiskers, 200g of poly-p-phenylene benzobisoxazole fiber (the length of the fiber is 1-3mm), and 10g of polyethylene oxide into the high-speed In the mixer, heat the mixer to 90°C and stir for 5 minutes, then stop stirring. After the material is cooled, extrude and granulate the modified POM pellets in the screw extruder; the modified POM pellets are extruded on the twin-screw After being melted in the machine and extruded through the die, enter the ethylene glycol cooling bath at -60°C to cool and form. The distance between the cooling bath liquid surface and the extrusion die is 5mm, and the cooled silk is introduced into a 95°C water bath for washing to remove water solubility. The polymer is stretched 4 times at the same time, and the washing time is 3.6s. After being dried in a hot oven at 120°C for 40s, it is stretched twice in a hot oven at 160°C. ℃ heat oven for setting for 30s, and finally t...

Embodiment 3

[0032] Put 1000g of polyoxymethylene resin, 10g of carboxylated nanocellulose whiskers, 100g of polyphenylene sulfide fibers (the length of the fibers is 1-3mm), and 30g of polyethylene glycol into a high-speed mixer, Heat the mixer to 100°C and stir for 4 minutes, then stop stirring. After the material is cooled, extrude and granulate the modified POM pellets in a screw extruder; melt the modified POM pellets in a twin-screw extruder After the die is extruded, enter the ethanol and ethylene glycol cooling bath at -30°C (the volume ratio of ethanol and ethylene glycol is 1:1) to cool and form. The distance between the liquid surface of the cooling bath and the extrusion die is 10mm, and the cooling The silk is introduced into a 90°C water bath for water washing to remove the water-soluble polymer, and at the same time, it is stretched twice. The water washing time is 7.2s. After being dried in a 120°C hot oven for 30s, it enters a 160°C hot oven for secondary stretching. Stret...

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Abstract

The invention relates to a preparation method of a polyoxymethylene crude fiber for toughening concrete. The method comprises the following steps: (1) mixing polyoxymethylene resin, a modified nano filler, a water-soluble polymer pore-foaming agent and a high-performance fiber in a high-speed mixer, extruding and pelletizing, so as to obtain modified POM aggregates; and (2) spinning the modified POM aggregates in a twin-screw extruder, directly feeding to a cooling bath to cool and mold, washing in a hot water bath, removing a water-soluble polymer, carrying out hot stretching, carrying out secondary stretching after drying, carrying out heat setting, and finally cutting into staple fibers, so as to prepare polyoxymethylene crude fiber the surface of which has micropores, with the equivalent diameter being 0.1-1mm, the tensile strength being greater than or equal to 600MPa and the tensile modulus being greater than or equal to 6.5GPa. Nanoparticle-enhanced and fiber-enhanced synergistic reinforcing effects are adopted, so that the high-performance polyoxymethylene crude fiber is prepared by virtue of general crude fiber equipment.

Description

technical field [0001] The invention relates to a method for preparing polyoxymethylene fibers, in particular to a method for preparing thick polyoxymethylene fibers for concrete toughening. Background technique [0002] Concrete is one of the most important building materials, and it is currently developing in the direction of high performance, functionality, and high durability. Concrete has disadvantages such as low tensile strength, poor toughness, and easy cracking, which lead to cracking of concrete structures under loads below the limit, reducing the service life and durability of structures. Adding synthetic fibers to cement-based composites can improve its brittleness, inhibit its early plastic cracking, and improve its crack resistance, impermeability, toughness, fatigue resistance and impact resistance. [0003] Synthetic fibers can be divided into reinforcing fibers for concrete according to their diameters, and can be divided into thin fibers with a diameter o...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D01F6/94C08L59/02C08L1/02C08L79/04C08L81/02C08L77/10C08K13/06C08K9/04C08K7/00C08K7/06D01D5/08D01D10/00C04B16/06
Inventor 刘建忠刘加平徐德根阳知乾李林张爱民周涛叶光斗吕进张丽辉
Owner JIANGSU SOBUTE NEW MATERIALS