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Sump oil dehydration technology and device

A kind of sewage oil and process technology, which is applied in the fields of grease/oily substance/float removal device, heating water/sewage treatment, water/sewage multi-stage treatment, etc. and other problems, to achieve the effect of considerable economic benefits, broad application prospects, and prevention of excessive attenuation.

Active Publication Date: 2015-04-29
CHINA PETROLEUM & CHEM CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The disadvantages of this method are: due to the different sources of waste oil and complex components, a large amount of emulsified waste oil cannot be effectively dehydrated, and the limited storage tanks are occupied.
[0006] Disadvantages of equipment waste oil dehydration technology: single equipment has small processing capacity, low efficiency, poor separation effect and is easy to damage. There are only patents in this area at home and abroad, and there are few cases in actual treatment of waste oil
Its disadvantages are: the tank with vertical structure is small in volume and low in processing capacity
[0008] The centrifuge dehydration technology introduced in patent CN201320420, because the density of waste oil and water is relatively close, and the oil sludge is mixed, only relying on the principle of different centrifugal force in the rotation of density, only free water can be separated, and emulsified water in waste oil is difficult to separate
Secondly, after separation, the waste oil has a large water content and cannot be reprocessed
The extracted water contains a lot of oil and cannot be effectively biochemically treated

Method used

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  • Sump oil dehydration technology and device
  • Sump oil dehydration technology and device
  • Sump oil dehydration technology and device

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0045] Such as figure 1 As shown, the sewage tank 1, the centrifugal pump 22 and the upper side of the cyclone 2 are connected sequentially through the pipeline, the top of the cyclone 2 is connected to the bottom of the expansion pipe 3, and the middle side of the expansion pipe 3 is connected to the metering pump 21 , the top of the expansion pipe 3 is connected to the mixing tank 4, and the bottom of the mixing tank 4 is vertically provided with a distribution pipe 5, and the bottom of the distribution pipe 5 is directly connected with the sewage oil inlet pipe 20 at one end of the settling tank 19, and the sewage oil inlet pipe inside the settling tank 19 The top of the 20 is provided with a dirty oil outlet pipe 6, and the other end of the settling tank 19 is sequentially arranged with a dirty oil outlet 8, an oil-water interface layer outlet 16 and a water layer outlet 15, and the dirty oil outlet pipe 6 is connected with the dirty oil outlet 8, and the oil-water The out...

Embodiment 2

[0049] Set side pipe 7 on dirty oil inlet pipe 20 and dirty oil outlet pipe 6, settling tank 19 outer shape is rectangle, groove width 5.9m, depth 4.9m, and the bottom is inclined slope. As shown in FIG. 2 , the ultrasonic generator 17 emitter is a shuttle-shaped emitter, and the others are the same as in Embodiment 1.

[0050] From the sewage oil tank 1, the water-containing sewage oil is transported through the centrifugal pump 22 into the cyclone separator 2, and the cyclone separator 2 separates the free water in the sewage oil by relying on the difference in specific gravity of oil and water. The waste oil is further processed, mixed with the demulsifier from the metering pump 21 into the expansion pipe 3 for preliminary mixing, and then enters the mixing tank 4. In the mixing tank 4, the oil agent is further mixed through the slow stirring of the stirring paddle, and the waste oil is discharged from the mixing tank 4 The bottom enters the sewage oil inlet pipe 20 through...

Embodiment 3

[0053] The device is the same as in Example 2.

[0054] Process: Put the dirty oil with a water content of 48% into the cyclone separator, after part of the free water is removed, add 200mg / L demulsifier, stir and mix in the mixing tank, put it into the settling tank through the dirty oil discharge pipe, and heat And keep the dirty oil temperature at 90°C, the frequency of ultrasonic wave is 20kHz, and the sound energy density is 0.3kW / m 3 Continuous effect, after 48 hours, the oil and water are separated, and the upper part of the dirty oil is taken for analysis. The water content is 9.7%, and the upper part of the dirty oil can be sent to the device for re-refining. Higher emulsification is still serious, enter the oil-water separation tower, heat it at 100°C to boil and evaporate the water, and the remaining dirty oil has a water content of 6%, which is sent to coking and blending.

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Abstract

The invention belongs to the field of chemical engineering and particularly relates to a sump oil dehydration technology and device. Hydrocyclone separation is adopted to separate dissociative water from sump oil, a demulsifier is added, and ultrasonic treatment is performed for dehydration, so that layering is formed, the upper layer contains sump oil with low water content, and the sump oil on the oil-water interface layer of the middle part and the lower part is subjected to heating, distillation and dehydration; therefore, the problems in the prior art that the sump oil dehydration technology is defective, the sump oil emulsification is serious, and the sump oil contains high water content and more impurities are solved; with adoption of the comprehensive measures, the total moisture content of the sump oil is less than 10%, and the mixing and refining recycling requirements are met. According to the invention, the technological process is simple, the application prospect is broad, and the economic benefit is remarkable on days when the crude oil price increasingly rises. The invention further provides the sump oil dehydration device which is high in handling capacity and efficiency as well as practicability, and reasonable in design.

Description

technical field [0001] The invention belongs to the field of chemical industry, and in particular relates to a waste oil dehydration process and device. Background technique [0002] In the process of oil production, gathering and transportation in the oil field, some dirty oil will be produced, which is difficult to recycle due to its high water content. In the process of petroleum refining, due to the nature of crude oil and the limitation of processing technology, a large amount of dirty oil will also be produced. An oil refinery with a refining capacity of 10Mt / a produces about 15kt of dirty oil every year, and as crude oil becomes heavier and worse, the amount of dirty oil will increase. [0003] Sludge oil in refineries generally comes from crude oil desalination and dehydration units in atmospheric and vacuum, and grease trap units in sewage treatment plants. A small amount of dirty oil is also produced in the cleaning of crude oil tanks or refined oil tanks, equipm...

Claims

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Application Information

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IPC IPC(8): C02F9/10
CPCC02F1/04C02F1/36C02F1/38C02F1/40C02F9/00C02F2301/08
Inventor 常文之苟社全张红宇张传明许金山刘爱华周玉新莫群
Owner CHINA PETROLEUM & CHEM CORP