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Organic-inorganic composite water-based paint and preparation method thereof

A composite water-based and water-based paint technology, applied in the direction of coating, etc., can solve the problem of poor adhesion of nano-composite high-temperature fire-resistant coatings

Active Publication Date: 2018-07-13
HEBEI CHENYANG INDAL & TRADE GROUP CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the adhesion of the nanocomposite high temperature fireproof coating is poor, and the high temperature performance needs to be further improved

Method used

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  • Organic-inorganic composite water-based paint and preparation method thereof
  • Organic-inorganic composite water-based paint and preparation method thereof

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preparation example Construction

[0021] Correspondingly, the present invention also provides a preparation method of an organic-inorganic composite water-based paint, comprising the following steps: mixing iron powder, 1,3,5-trimesic acid, hydrofluoric acid, nitric acid and N,N-dimethyl Formamide is polymerized under hydrothermal conditions to obtain a metal-organic framework material; nano-titanium dioxide dispersion and talcum powder are added to the sodium silicate solution, and the metal-organic framework material and silica sol are added after the first stirring, Dispersant, leveling agent, defoamer, nonionic emulsion, styrene-acrylic emulsion, sodium acetate and water are stirred for the second time to obtain an organic-inorganic composite water-based paint.

[0022] As a preferred solution, in the step of obtaining the metal organic framework material, the temperature of the polymerization reaction is preferably 140-160° C., and the time of the polymerization reaction is preferably 8-20 hours. The conc...

Embodiment 1

[0039] Follow the steps below to prepare water-based paint:

[0040] 1. Contains the following components by weight: 32% of water (the first part of water: 12%, the second part of water 10%, the third part of water 10%), iron powder 3%, 1,3,5-benzenetri Acid 5%, hydrofluoric acid (35%) 0.1%, nitric acid (65%) 0.1%, N,N-dimethylformamide 0.5%, water-soluble sodium silicate 30%, silica sol 6%, non 0.3% ionic emulsion, 3% styrene-acrylic emulsion, nano TiO 2 Dispersion 5%, sodium acetate 0.15%, defoamer (organosiloxane) 0.3%, leveling agent (acetobutylcellulose) 0.15%, dispersant (polyacrylamide) 1.5%, talc 12%.

[0041] 2. Add iron powder, 1,3,5-trimesic acid, hydrofluoric acid (35%), nitric acid (65%), N,N-dimethylformamide and the first part of water into the reactor and mix well , put the lid on and move to the stainless steel reaction kettle to seal it, and place it in an electric blast drying oven at 150°C for 12 hours.

[0042] 3. Put the water-soluble sodium silicate s...

Embodiment 2

[0045] Follow the steps below to prepare water-based paint:

[0046] 1. Contains the following components by weight fraction: water 35% (the first part of water: 15%, the second part of water 10%, the third part of water 10%), iron powder 2%, 1,3,5-trimesic acid 4%, hydrofluoric acid (35%) 0.1%, nitric acid (65%) 0.1%, N,N-dimethylformamide 0.5%, water-soluble sodium silicate 35%, silica sol 8%, non-ionic Emulsion 0.3%, styrene-acrylic emulsion 5%, nano TiO 2 Dispersion 5%, sodium acetate 0.2%, defoamer (organosiloxane) 0.3%, leveling agent (acetobutylcellulose) 0.15%, dispersant (polyacrylamide) 1.5%, talc 12%.

[0047] 2. Add iron powder, 1,3,5-trimesic acid, hydrofluoric acid (35%), nitric acid (65%), N,N-dimethylformamide and the first part of water into the reactor and mix well , put the lid on and move to the stainless steel reaction kettle to seal it, and place it in an electric blast drying oven at 150°C for 12 hours.

[0048] 3. Put the water-soluble sodium silicat...

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Abstract

The invention provides organic-inorganic compound water based paint and a preparation method thereof. The organic-inorganic compound water based paint is prepared from the following raw materials: water, iron powder, benzene 1,3,5-tricarboxylic acid, hydrofluoric acid, nitric acid, N,N-dimethyl formamide, sodium silicate, non-ionic emulsion, styrene-acrylic emulsion, silica sol, nano-titanium dioxide dispersoid, sodium acetate, a defoaming agent, a flatting agent, a dispersing agent and talcum powder. Compared with the prior art, the organic-inorganic compound water based paint has the advantages that water soluble sodium silicate is taken as an inorganic film forming matter and then is compounded with a metal organic frame (MOF) material, thus obtaining the organic-inorganic compound water based paint; and the MOF material has the unique characteristics that thermal stability is good, an open-framework structure is ordered and functional group modification can be carried out in pores and on the surfaces, so that the water based paint has good stability, high temperature resistance and adhesion.

Description

technical field [0001] The invention relates to the technical field of coatings, in particular to an organic-inorganic composite water-based paint and a preparation method thereof. Background technique [0002] With the development of industrial technology, high-temperature-resistant thermal insulation coatings have emerged, and water-based paints have attracted much attention because of their many excellent properties, and their use in high-temperature-resistant fields has a considerable development trend. At present, water-based paint can be applied to high-temperature surfaces, such as high-temperature metal parts such as barbecue ovens, induction cookers, and heat exchangers, but its adhesion and high-temperature resistance still need to be further improved. [0003] Generally speaking, high temperature resistant coatings are mainly divided into organic high temperature resistant coatings, inorganic high temperature resistant coatings and organic-inorganic composite high...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D125/14C09D7/61
CPCC08K2201/011C09D1/00C09D7/61C09D7/63C09D7/65
Inventor 胡中源郑毅刘洪亮李青春楚会来魏君
Owner HEBEI CHENYANG INDAL & TRADE GROUP CO LTD