Anti-dazzle coating and anti-dazzle hardening film

A hardened film and coating technology, applied in polyurea/polyurethane coatings, coatings, instruments, etc., can solve the problems of poor clarity and flash point of the anti-glare hardened film, heavy flash point, and inability to meet the requirements of high-definition display devices. , to achieve excellent leveling, reduce the effect of flash point

Active Publication Date: 2015-08-05
ZHANGJIAGANG KANGDE XIN OPTRONICS MATERIAL
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Patent CN102124048A discloses a method for preparing an anti-glare hardened film, by dissolving at least two mutually incompatible resins in at least one solvent, the particles migrate to the air-liquid interface of the coating, so that it is centrifugally Positioned on the surface of the coating to prepare an anti-glare hardened film; however, the prepared anti-glare hardened film has poor clarity and flash point
Patent CN101679825A discloses a composition for anti-glare cured film and the anti-glare cured film prepared by using the composition. By adding a certain amount of organic particles with a particle size of 1-10um to the binder resin, the coating surface Form a concave-convex height of 0.01-2μm to achieve the anti-glare effect, but the disadvantage is that the flash point is heavy and the clarity is not enough
[0004] At present, most anti-glare hardened film products have heavy flash points, poor clarity, and blurred images, which can no longer meet the requirements of high-definition display devices.

Method used

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  • Anti-dazzle coating and anti-dazzle hardening film

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preparation example Construction

[0046] In the present invention, the preparation method of the antiglare coating preferably comprises the following steps:

[0047] Mix urethane acrylate polymer with 6-functionality and above, acrylate monomer with 3-functionality and above, photoinitiator and organic solvent, stir to obtain the mixture, and then continue to add anti-glare particles with a particle size of ≤500nm, particle size The anti-glare particles of 1-3 μm, the silicone leveling agent and the acrylic leveling agent are fully stirred evenly to obtain the anti-glare coating.

[0048] In the present invention, the urethane acrylate polymer with a hexafunctionality and above, the acrylate monomer with a trifunctionality and above, the antiglare particles with a particle diameter of ≤500 nm, the antiglare particles with a particle diameter of 1 to 3 μm, The types, dosages and sources of photoinitiators, silicone-based leveling agents, acrylic leveling agents and organic solvents are the same as those of poly...

Embodiment 1

[0074] The components of the anti-glare coating include by weight:

[0075]

[0076]In 60 parts of urethane acrylate polymer CN9006NS (manufactured by Sartomer) and 40 parts of 3-functionality acrylate monomer DPHA (manufactured by Guojing Chemical), add 4 parts of 1-hydroxycyclohexyl phenyl ketone (Tianjin Manufactured by Tianjiao Chemical Co., Ltd.); obtain the mixture after being diluted with 60 parts of mixed solvents comprising butyl acetate and ethyl acetate with a relative weight ratio of 1:1, then add 33 parts of MP9130X solution (solid content is 30%, The particle diameter is 120nm, and the dispersion liquid is acetic acid-1-methoxy-2-propyl ester, manufactured by Evonik), 50 parts of antiglare particles 2356 solution (solid content is 10%, particle diameter is 2~3μm, dispersed Liquid is a mixture of cyclohexanone, toluene, xylene and ethylbenzene, manufactured by Gifu, Japan) and 0.1 part of silicone leveling agent 333, 0.5 part of acrylic leveling agent 354 (both...

Embodiment 2

[0080] The components of the anti-glare coating include by weight:

[0081]

[0082] To 80 parts of 6195-100 oligomer (manufactured by Changxing Chemical Industry Co., Ltd.) and 20 parts of PETA (manufactured by Changxing Chemical Industry Co., Ltd.), add 4 parts of photoinitiator 184 and 2 parts of 2,4,6 (Trimethylbenzoyl) diphenylphosphine oxide (TPO) (both manufactured by Tianjin Tianjiao Chemical Co., Ltd.); obtain the mixture after diluting 30 parts of propylene glycol methyl ether and 10 parts of ethyl acetate, and then add 75 Parts of antiglare particle AB-S10 solution (solid content is 20%, particle diameter is 200nm, dispersion liquid is methyl isobutyl ketone, produced by Shanghai Nagase Trading Company), 100 parts of antiglare particle TR-7 solution (solid content 10%, the particle size is 2 ~ 3μm, the dispersion liquid is a mixture of cyclohexanone, toluene, xylene and ethylbenzene, made in Gifu, Japan) and 1 part of silicone leveling agent 377, 1 part of acryli...

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Abstract

The invention provides an anti-dazzle coating and an anti-dazzle hardening film. The anti-dazzle coating comprises the following components in parts by weight: 60-80 parts of polyurethane acrylate polymer with six degrees of functionality or above, 20-40 parts of acrylate monomer with six degrees of functionality or above, 10-15 parts of anti-dazzle particles with particle size of less than or equal to 500nm, 5-10 parts of anti-dazzle particles with particle size of 1-3mu m, 4-8 parts of a photoinitiator, 0.1-1 part of an organosilicone levelling agent, 0.5-1 part of an acrylic acid levelling agent and 40-80 parts of an organic solvent. The anti-dazzle coating provided by the invention is used for preparing an anti-dazzle hard coating film; two types of anti-dazzle particles different in particle size are used together so that the prepared anti-dazzle hard coating film has excellent properties of low flash point and high definition; in addition, the anti-dazzle hard coating film further has excellent levelling property so that the flash point of the anti-dazzle hardening film can be lowered further.

Description

technical field [0001] The invention relates to the technical field of anti-glare hardened films, in particular to an anti-glare coating and an anti-glare hardened film. Background technique [0002] When mobile phones, laptops, PADs and other displays are exposed to external light such as natural light, the glare pollution caused by the reflected light on the surface often makes people's eyes tired and affects the clarity of the picture. Therefore, there are more and more anti-glare hardened film products on the market to reduce the interference of reflected light on people's sight. [0003] Patent CN102124048A discloses a method for preparing an anti-glare hardened film, by dissolving at least two mutually incompatible resins in at least one solvent, the particles migrate to the air-liquid interface of the coating, so that it is centrifugally Positioned on the surface of the coating to prepare an anti-glare hardened film; but the prepared anti-glare hardened film has poor...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D175/14C09D7/12G02B1/11
CPCC08K3/00C08K3/22C08K3/26C08K3/36C08K2003/2227C08K2003/2241C08K2003/265C08K2003/267C08K2201/014C09D7/47C09D7/61C09D7/69C09D175/14G02B1/111
Inventor 鞠久妹李冠毅丁清华
Owner ZHANGJIAGANG KANGDE XIN OPTRONICS MATERIAL
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