A kind of purification method of ATP sulfurylase
A purification method and sulfurylase technology, applied in the biological field, can solve the problems of low product purity, inability to meet genome sequencing, affecting the accuracy of sequencing reaction, etc., and achieve the effects of high purity, high activity and increased stability.
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Embodiment 1
[0027] (1) Adjust the pH value: adjust the pH value of the crude enzyme solution to 7.6;
[0028] (2) Take 1L of crude luciferase enzyme solution and add 10mmol of magnesium chloride, 15mmol of magnesium sulfate and 16mmol of calcium chloride;
[0029] (3) Add 6g of soybean polysaccharide and 3g of dimercaptothreitol;
[0030] (4) Organic solvent precipitation: slowly add 15ml acetone and 20ml acetonitrile, stir, let stand for 10 minutes, centrifuge at 13000rpm, discard the supernatant, add 10ml Tris-HCl buffer, stir, centrifuge at 13000rpm, and collect the supernatant;
[0031] (5) Use 0.22μm filter membrane for sterile filtration;
[0032] (6) Purify on nickel column, use pH 8.0 Tris-HCl buffer for column equilibration and elution, and use 20-500 mM imidazole for gradient elution;
[0033] (7) Use Tris-HCl buffer for protein dialysis;
[0034] (8) Use GE molecular exclusion prepacked column superdex200 for molecular exclusion, and use pH 8.0 Tris-HCl buffer for column equilibration and ...
Embodiment 2
[0038] (1) Adjust the pH value: adjust the pH value of the crude enzyme solution to 8.0;
[0039] (2) Take 1L of crude luciferase enzyme solution, add 20mmol magnesium nitrate, 12mmol calcium sulfate, and 8mmol calcium chloride;
[0040] (3) Add 5g of glycerin;
[0041] (4) Organic solvent precipitation: slowly add 20ml methanol and 12ml acetonitrile, stir, let stand for 10 minutes, centrifuge at 13000rpm, discard the supernatant, add 10ml Tris-HCl buffer, stir, centrifuge at 13000rpm, and collect the supernatant;
[0042] (5) Use 0.22μm filter membrane for sterile filtration;
[0043] (6) Purify on nickel column, use pH8.0 Tris-HCl buffer for column equilibration and elution, and use 20-500mM imidazole for gradient elution during elution;
[0044] (7) Use Tris-HCl buffer for protein dialysis;
[0045] (8) Use GE molecular exclusion prepacked column superdex200 for molecular exclusion, and use pH 8.0 Tris-HCl buffer for column equilibration and elution to obtain 100 ml of enzyme solution;...
Embodiment 3
[0049] (1) Adjust the pH value: adjust the pH value of the crude enzyme solution to 7.5;
[0050] (2) Take 1L of crude luciferase enzyme solution and add 30mmol of magnesium chloride, 2mmol of calcium sulfate, 4mmol of calcium chloride and 4mmol of calcium nitrate;
[0051] (3) Add 8g of glycerin, 2g of ethylene glycol and 5g of soybean polysaccharide;
[0052] (4) Organic solvent precipitation: slowly add 30ml acetonitrile, stir, let stand for 10 minutes, centrifuge at 13000rpm, discard the supernatant, add 10ml Tris-HCl buffer, stir, centrifuge at 13000rpm, and collect the supernatant;
[0053] (5) Use 0.22μm filter membrane for aseptic filtration;
[0054] (6) Purify on nickel column, use pH8.0 Tris-HCl buffer for column equilibration and elution, and use 20-500mM imidazole for gradient elution during elution;
[0055] (7) Use Tris-HCl buffer for protein dialysis;
[0056] (8) Use GE molecular exclusion prepacked column superdex200 for molecular exclusion, and use pH 8.0 Tris-HCl buffe...
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