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A kind of redispersing powder AKD sizing agent and its preparation method and application

A re-dispersion and sizing agent technology, which is applied in the direction of water-repellent addition, inorganic compound addition, paper, etc., can solve the problem of difficult dispersion of powder, and achieve the effects of protecting emulsion particles, convenient transportation and storage, and good water dispersibility

Active Publication Date: 2017-10-20
SOUTH CHINA UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, if the emulsion is dried directly, the resulting powder is often difficult to disperse in water

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] Heat 38 parts by mass of deionized water to 70°C with a water bath, gradually add 3.5 parts by mass of cationic starch into the deionized water while stirring continuously, and add 1.5 parts by mass of sodium lignosulfonate at the same time, and stir at 10000r / min for 10min , to obtain starch gelatinization solution, the temperature is kept at 70°C, and it is set aside;

[0033] Weigh 15 parts by mass of industrial AKD wax powder and heat it in an emulsifier to a molten state; add the molten AKD to the starch gelatinization liquid prepared above, stir at a speed of about 2500r / min for 1min, and then adjust the speed to 15000r / min, stirring and emulsifying for 8min to obtain the emulsion;

[0034] The obtained emulsion was added to 39 parts by mass of ice deionized water, and 3 parts by mass of aluminum sulfate solution with a mass fraction of 40% were added at the same time, the rotating speed was adjusted to 3500r / min, and stirred to room temperature to obtain an AKD ...

Embodiment 2

[0040] Heat 38 parts by mass of deionized water to 70°C with a water bath, gradually add 2.5 parts by mass of cationic starch into the deionized water under constant stirring, and stir for 10 minutes at 10,000 r / min to obtain starch gelatinization solution, and keep the temperature at 70°C ,spare;

[0041] Weigh 13 parts by mass of industrial AKD wax powder and heat it to a molten state in an emulsifier; add the molten AKD to the starch gelatinization liquid prepared above, stir at a speed of about 2000r / min for 1min, and then adjust the speed to 18000r / min, stirring and emulsifying for 8min to obtain the emulsion;

[0042] The obtained emulsion was added to 42.5 parts by mass of ice-deionized water, and 4 parts by mass of aluminum sulfate solution with a mass fraction of 40% were added at the same time, the rotating speed was adjusted to 4000r / min, and stirred to room temperature to obtain an AKD emulsion with an AKD content of 13%. (Aggregation will occur between some AKD dr...

Embodiment 3

[0048] Heat 38 parts by mass of deionized water to 70°C with a water bath, gradually add 5 parts by mass of cationic starch into the deionized water under constant stirring, and stir at 10,000r / min for 10min to obtain starch gelatinization solution, and keep the temperature at 70°C ,spare;

[0049] Weigh 15 parts by mass of industrial AKD wax powder and heat it to a molten state in an emulsifier; add the molten AKD to the starch gelatinization liquid prepared above, stir at a speed of about 2500r / min for 1min, and then adjust the speed to 18000r / min, stirring and emulsifying for 8min to obtain the emulsion;

[0050] Gained emulsion is added to 42 mass parts of ice deionized water, the rotating speed is adjusted to 4000r / min, stirred to room temperature, the AKD emulsion that obtains the AKD content is 15% (aggregation will occur between some AKD droplets, and the emulsion gradually loses its Fluidity, become a paste, but the paste can still be dispersed in water), standby; ...

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Abstract

The invention belongs to the technical field of papermaking sizing agents, and discloses a redispersed powder AKD sizing agent, a preparation method and application thereof. The redispersed powder AKD sizing agent is prepared by mixing and drying 100 parts by mass of AKD emulsion, 2-8 parts by mass of water-soluble high polymer and 2-10 parts by mass of inorganic powder. The product of the invention can be used in the sizing process of papermaking, can obviously improve the water resistance of paper, and has good redispersibility, stability and sizing performance. In addition, the product of the present invention is in powder form, and has the advantages of convenient transportation, storage and use.

Description

technical field [0001] The invention belongs to the technical field of papermaking sizing agents, and in particular relates to a redispersed powder AKD sizing agent and its preparation method and application. Background technique [0002] Neutral sizing represents the trend and direction of today's paper sizing technology development. Among the numerous medium-alkaline paper sizing agents, the most favored by paper manufacturers are alkyl ketene dimer (AKD) and alkenyl succinic anhydride (ASA), which are called cellulose-reactive sizing agents. Because the sizing efficiency of AKD is higher than that of ASA, no on-site emulsification is required, and the hydrolysis tendency is not as obvious as ASA, the wet end of the paper machine is cleaner, and there are fewer problems of sticking rolls and fouling. AKD is more commonly used than ASA. AKD is a light yellow waxy solid with a low melting point (generally between 43°C and 65°C). It is insoluble in water. Usually, it is melt...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D21H21/16D21H17/17D21H17/67D21H17/68D21H17/35D21H17/36D21H17/24
Inventor 赵丽红梁明露何北海
Owner SOUTH CHINA UNIV OF TECH