The invention provides an amphoteric metaanion
chlorine-free
rosin size
raw material composition which comprises the following raw materials in parts by weight: 100-200 parts of
rosin, 5-20 parts of a modifier, 5-8 parts of an anionic
starch emulsifier, 5-8 parts of an amphoteric emulsifier and / or a proper amount of a functional aid, and the anionic
starch emulsifier is an esterification cross-linked product of 1, 2, 3, 4-butanetetracarboxylic acid and
starch. The preparation method of the amphoteric metaanion
chlorine-free
rosin size from the
raw material composition comprises the following steps: heating and melting rosin, adding a modifier, reacting to obtain modified rosin, heating an anionic starch emulsifier and an amphoteric emulsifier to 60-90 DEG C, sequentially dropwise adding the materials into the modified rosin in a
molten state, pre-emulsifying, and cooling to
room temperature to obtain the amphoteric metaanion
chlorine-free rosin size. And adding hot water into the pre-emulsified rosin liquid for
phase inversion, cooling, and adding a functional auxiliary agent. The main raw materials of the amphoteric partial anion chlorine-free rosin size are natural renewable substances, the
particle size distribution is narrow, the stability is good, the foam is less,
fiber flocculation is not caused, and when the amphoteric partial anion chlorine-free rosin size is applied to
papermaking sizing, acidic to neutral
sizing can be achieved.