Ultraviolet-proof exterior wall coating and preparation method therefor
A technology for exterior wall coating and UV protection, applied in coatings and other directions, can solve the problem of unsolved compatibility between nano-titanium dioxide and polymers, and achieve environmental protection and construction safety, excellent stability, and enhanced hardness. Effect
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Embodiment 1
[0055] In terms of parts by mass, the formula of the anti-ultraviolet exterior wall paint consists of:
[0056]
[0057] Prepare UV-resistant exterior paints as follows:
[0058] (1) Preparation of Nano Titanium Dioxide / Acrylic Ester Polymer Composite Emulsion
[0059] 1) Preparation of modified nano titanium dioxide
[0060] In terms of parts by mass, mix 5 parts of nano-titanium dioxide with 200 parts of ethanol, 800W ultrasonic dispersion for 35 minutes, add 5 parts of vinyltriethoxysilane, react at 80°C for 6 hours, centrifuge, wash with absolute ethanol, centrifuge and wash Repeat 3 times, and bake at 100° C. for 12 hours to obtain modified nano-titanium dioxide.
[0061] 2) Preparation of nano-titanium dioxide / acrylate polymer composite emulsion
[0062] In terms of parts by mass, 5 parts of modified nano-titanium dioxide were dispersed in a mixed solution of 25 parts of acrylamide, 25 parts of butyl acrylate and 2 parts of cetyl alcohol, ultrasonically dispersed a...
Embodiment 2
[0069] In terms of parts by mass, the formula of the anti-ultraviolet exterior wall paint consists of:
[0070]
[0071] Prepare UV-resistant exterior paints as follows:
[0072] (1) Preparation of Nano Titanium Dioxide / Acrylic Ester Polymer Composite Emulsion
[0073] 1) Preparation of modified nano titanium dioxide
[0074] In terms of parts by mass, mix 3.2 parts of nano-titanium dioxide with 150 parts of isopropanol, disperse with 400W ultrasonic for 20 minutes, add 1.2 parts of vinyltrimethoxysilane, react at 70°C for 3.5h, centrifuge, wash with absolute ethanol, and centrifuge 1. Washing was repeated 3 times, and the modified nano titanium dioxide was obtained after drying at 50° C. for 24 hours.
[0075] 2) Preparation of nano-titanium dioxide / acrylate polymer composite emulsion
[0076] In terms of parts by mass, 3.2 parts of modified nano-titanium dioxide were dispersed in a mixed solution of 40 parts of methyl methacrylate and 1.8 parts of hexadecane, 500W ultr...
Embodiment 3
[0083] In terms of parts by mass, the formula of the anti-ultraviolet exterior wall paint consists of:
[0084]
[0085]
[0086] Prepare UV-resistant exterior paints as follows:
[0087] (1) Preparation of Nano Titanium Dioxide / Acrylic Ester Polymer Composite Emulsion
[0088] 1) Preparation of modified nano titanium dioxide
[0089] In terms of parts by mass, mix 2.25 parts of nano-titanium dioxide with 110 parts of methanol, 600W ultrasonic dispersion for 10 minutes, add 2.25 parts of γ-methacryloxypropyltrimethoxysilane, react at 60°C for 3.5h, centrifuge, and use Washing with absolute ethanol, centrifugation and washing were repeated 3 times, and drying at 75° C. for 18 hours to obtain modified nano titanium dioxide.
[0090] 2) Preparation of nano-titanium dioxide / acrylate polymer composite emulsion
[0091] In terms of parts by mass, 2.25 parts of modified nano-titanium dioxide were dispersed in a mixed solution of 20 parts of acrylate, 14.1 parts of tert-butyl...
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