Carbon dioxide foam system added with hydrophilic nanoparticles for oil displacement and preparation method for carbon dioxide foam system

A technology of nano-particles and carbon dioxide, applied in chemical instruments and methods, drilling compositions, etc., can solve the problems of high cost of hydrophobic nanoparticles, difficult dispersion, poor dispersion stability of foaming agent solution, etc., to achieve the preparation method And the on-site construction process is simple, the cost is low, and the effect of easy popularization and application

Active Publication Date: 2015-11-11
CHINA UNIV OF PETROLEUM (EAST CHINA)
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the cost of hydrophobic nanoparticles is high, and due to the strong degree of hydrophobicity, it is difficult to disperse in water, and the dispe

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0034] A carbon dioxide foam system added with hydrophilic nanoparticles, comprising the following components by mass of raw materials:

[0035] Lauryl alcohol polyoxyethylene polyoxypropylene ether (C 12 E. 9 P 3 ) 0.15g, hydrophilic silica nanoparticles (average particle diameter 16nm, surface silanol density 1.5 / nm 2 , the contact angle with water is 38.8°) 1.5g, sodium chloride (NaCl) 0.2g, carbon dioxide 0.5g, distilled water 100g.

[0036] The preparation method is as follows:

[0037] (1) Add hydrophilic silica nanoparticles into distilled water and stir evenly, then add lauryl alcohol polyoxyethylene polyoxypropylene ether (C 12 E. 9 P 3 ) and sodium chloride (NaCl), use an ultrasonic disperser to ultrasonically disperse the mixed system for 3 minutes;

[0038] (2) Use the WaringBlender method to generate foam: continuously inject carbon dioxide into the system obtained in step (1) for 3 minutes, and then stir the system at a speed of 8000 r / min for 3 minutes to...

Embodiment 2

[0041]A carbon dioxide foam system added with hydrophilic nanoparticles, comprising the following components by mass of raw materials:

[0042] Lauryl alcohol polyoxyethylene polyoxypropylene ether (C 12 E. 9 P 3 ) 0.1g, hydrophilic silica nanoparticles (average particle diameter 20nm, surface silanol density 1 / nm 2 , the contact angle with water is 50.4°) 1.5g, sodium chloride (NaCl) 0.2g, carbon dioxide 0.5g, distilled water 100g.

[0043] The preparation method is as follows:

[0044] (1) Add hydrophilic silica nanoparticles into distilled water and stir evenly, then add lauryl alcohol polyoxyethylene polyoxypropylene ether (C 12 E. 9 P 3 ) and sodium chloride (NaCl), use an ultrasonic disperser to ultrasonically disperse the mixed system for 3 minutes;

[0045] (2) Foam generation by using the WaringBlender method: Continuously inject carbon dioxide into the system obtained in step (1) for 3 minutes, and then stir the system at a speed of 8000 r / min for 3 minutes to...

Embodiment 3

[0048] A carbon dioxide foam system added with hydrophilic nanoparticles, comprising the following components by mass of raw materials:

[0049] Lauryl alcohol polyoxyethylene polyoxypropylene ether (C 12 E. 9 P 3 ) 0.1g, hydrophilic silica nanoparticles (average particle diameter 20nm, surface silanol density 1 / nm 2 , the contact angle with water is 50.4°) 1.5g, sodium chloride (NaCl) 0.2g, carbon dioxide 0.5g, distilled water 100g.

[0050] The preparation method is as follows:

[0051] (1) Add hydrophilic silica nanoparticles into distilled water and stir evenly, then add lauryl alcohol polyoxyethylene polyoxypropylene ether (C 12 E. 9 P 3 ) and sodium chloride (NaCl), use an ultrasonic disperser to ultrasonically disperse the mixed system for 3 minutes;

[0052] (2) Place the mixed system in an incubator at 80°C and keep the temperature constant for 3 hours;

[0053] (3) Use the WaringBlender method to generate foam: continuously feed carbon dioxide into the system...

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Abstract

The invention relates to a carbon dioxide foam system added with hydrophilic nanoparticles for oil displacement and a preparation method for the carbon dioxide foam system. The carbon dioxide foam system is prepared from the following components in parts by mass: 0.1-0.3 part of a nonionic surfactant, 1-2 parts of hydrophilic nanoparticles, 0.01-0.2 part of inorganic salt, 0.2-0.8 part of carbon dioxide and 100 parts of water. The preparation method comprises: after preparing a foaming agent in proportion, uniformly dispersing the foaming agent by using an ultrasonic wave dispersing instrument; and introducing carbon dioxide into a stirring cup and stirring the mixture by virtue of a Waring Blender method to obtain the carbon dioxide foam system. Compared to carbon dioxide foam generated by a common surfactant, the carbon dioxide foam added with hydrophilic nanoparticles is better in temperature resistance and salt resistance, and compared to a foaming agent added with hydrophobic nanoparticles, the carbon dioxide foam system is low in cost and good in dispersing stability and is more liable to be popularized and applied in a field site.

Description

technical field [0001] The invention relates to a carbon dioxide foam system added with hydrophilic nanoparticles and a preparation method thereof, belonging to the technical field of oil and gas field development engineering. Background technique [0002] The combustion of fossil fuels will produce a large amount of carbon dioxide gas, and the random emission of carbon dioxide will lead to the greenhouse effect and endanger the climate security of mankind. As people's requirements for carbon dioxide emission reduction are increasing day by day, more and more attention has been paid to the storage and utilization technology of carbon dioxide. [0003] Carbon dioxide and crude oil in the formation can interact to reduce the viscosity of crude oil and increase the elastic energy of crude oil. Compared with nitrogen, air and methane gas, the miscibility pressure of carbon dioxide and crude oil is low, which is a kind of oilfield development field. Ideal oil displacing agent. ...

Claims

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Application Information

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IPC IPC(8): C09K8/594
CPCC09K8/594
Inventor 李松岩李兆敏王继乾王鹏李宾飞孙乾
Owner CHINA UNIV OF PETROLEUM (EAST CHINA)
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