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Preparation method of high-density polyethylene IBC inner container blow molding material

A high-density polyethylene and polyethylene technology, which is applied in the field of preparation of high-density polyethylene IBC liner blow molding materials, can solve the problems of difficult to meet market demand, poor anti-aging properties of products, etc., and achieve outstanding anti-oxidation ability, anti-aging Excellent environmental stress cracking performance and photostability, and good product quality

Inactive Publication Date: 2016-01-20
CHINA PETROLEUM & CHEM CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, domestic enterprises have not formed a scale in the special material for IBC barrels, and the prepared products have poor anti-aging performance and various other quality reasons, which cannot meet the production needs of manufacturers.
Therefore, the special materials used in the manufacture of IBC barrels in China are mainly imported materials, which is difficult to meet market demand.

Method used

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  • Preparation method of high-density polyethylene IBC inner container blow molding material
  • Preparation method of high-density polyethylene IBC inner container blow molding material
  • Preparation method of high-density polyethylene IBC inner container blow molding material

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0039] The preparation method of ethylene-hexene copolymerized polyethylene resin:

[0040] The diluent isobutane is always in a circulating state, inject ethylene and hexene into the loop reactor respectively, strictly control the feed ratio of ethylene and hexene, and add a pre-activated catalyst to control the reaction temperature in the reactor to 92.0±2.0 ℃, ethylene feed rate 37.5t / h, hexene-1 / ethylene ratio 17.6kg / t, catalyst 963T feed rate 193kg / h, so that the melt flow rate is 5.95g / 10min and the density is 0.9448kg / m 3 , a weight average molecular weight of 280,000, a molecular weight distribution of 16.4, and an ethylene-hexene copolymerized polyethylene resin with a hexene monomer content of 0.34%.

[0041] Raw materials (parts by weight) of IBC liner blow molding material:

[0042] Ethylene Hexene Copolymerized Polyethylene Resin 100

[0043] Antioxidant 0.09

[0044] Auxiliary antioxidant 0.07

[0045] Light stabilizer 0.18

[0046] Among them, the antioxida...

Embodiment 2

[0050] The preparation method of ethylene-hexene copolymerized polyethylene resin:

[0051] The diluent isobutane is always in a circulating state, inject ethylene and hexene into the loop reactor respectively, strictly control the feed ratio of ethylene and hexene, and add a pre-activated catalyst to control the reaction temperature in the reactor to 92.0±2.0 ℃, ethylene feed rate 36.3t / h, hexene-1 / ethylene ratio 18.4kg / t, catalyst 963T feed rate 185kg / h, so that the melt flow rate is 5.84g / 10min and the density is 0.9452kg / m 3 , a weight average molecular weight of 286,000, a molecular weight distribution of 17.7, and an ethylene-hexene copolymerized polyethylene resin with a hexene monomer content of 0.41%.

[0052] Raw materials (parts by weight) of IBC liner blow molding material:

[0053] Ethylene Hexene Copolymerized Polyethylene Resin 100

[0054] Antioxidant 0.09

[0055] Auxiliary antioxidant 0.07

[0056] Light stabilizer 0.18

[0057] Among them, the antioxida...

Embodiment 3

[0061] The preparation method of ethylene-hexene copolymerized polyethylene resin:

[0062] The diluent isobutane is always in a circulating state, inject ethylene and hexene into the loop reactor respectively, strictly control the feed ratio of ethylene and hexene, and add a pre-activated catalyst to control the reaction temperature in the reactor to 92.0±2.0 ℃, the ethylene feed rate is 38.1t / h, the hexene-1 / ethylene ratio is 18.8kg / t, and the catalyst 963T feed rate is 204kg / h, so that the melt flow rate is 6.10g / 10min and the density is 0.9455kg / m 3 , a weight average molecular weight of 272,000, a molecular weight distribution of 15.3, and an ethylene-hexene copolymerized polyethylene resin with a hexene monomer content of 0.42%.

[0063] Raw materials (parts by weight) of IBC liner blow molding material:

[0064] Ethylene Hexene Copolymerized Polyethylene Resin 100

[0065] Antioxidant 0.09

[0066] Auxiliary antioxidant 0.07

[0067] Light stabilizer 0.18

[0068] ...

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Abstract

The invention discloses a preparation method of a high-density polyethylene IBC inner container blow molding material. The method comprises the following steps that 1, in the single-loop slurry process polythene production technology, on the condition that diluents are always in a circulating state, ethylene and hexene-1 are placed in a reaction container, a polymerization reaction is performed on the condition that a catalyst exists to generate ethylene-hexene-copolymerization polyethylene resin with the melt flow rate of 5.60-7.0 g / 10 min, the density of 0.943-0.947 kg / m<3>, the weight-average molecular weight of 250-290 thousands, the molecular weight distribution of 13-18 and the hexene-1content of 0.3%-0.6%, and the reaction temperature in the reaction container is set at 92.0+ / -2.0 DEG C; 2, the ethylene-hexene-copolymerization polyethylene resin, antioxidants, antioxidant aids and light stabilizers are taken to be mixed evenly, and then extruding and pelleting are performed to obtain the granular high-density polyethylene IBC inner container blow molding material. According to the IBC inner container blow molding material prepared through the method, molecular weight distribution is wide, the comonomer hexene content is high, the processing property and the moldability are good, and a blow-molded IBC inner container product has the outstanding rigid-tough balance capacity, antioxidant capacity and anti-corrosion and environmental stress cracking resistance properties and the good rebound resilience.

Description

technical field [0001] The invention relates to a preparation method of a blow molding material, in particular to a preparation method of a high density polyethylene IBC liner blow molding material. Background technique [0002] IBC (Intermediate Bulk Container) refers to a composite bulk container with a rigid plastic inner container for shipping liquids. It is mainly composed of high-density polyethylene plastic liner, plastic corner accessories, high-precision ball valve, steel tray base and guardrail steel Composed of racks and other parts, it is a new type of packaging container that can fill Class II and III dangerous goods liquids. [0003] IBC barrel liner is a packaging container developed in the chemical liquid packaging industry with the research and development of polymer and ultra-high polymer resin materials. It is made of high-density polyethylene (HDPE) with an average molecular weight of about 250,000. , which is blown by a large-scale extrusion blow moldin...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/08C08K5/134C08K5/526C08K5/357C08F210/16C08F210/14
CPCC08F210/16C08F2800/20C08K5/1345C08K5/357C08K5/526C08L2201/08C08L2207/062C08F210/14C08F2500/04C08F2500/07C08L23/0815
Inventor 张玮钟向宏林国易志勤骆新平李伟陈仕兵
Owner CHINA PETROLEUM & CHEM CORP
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